Search KARSTBASE:
KarstBase a bibliography database in karst and cave science.
Featured articles from Cave & Karst Science Journals
Characterization of minothems at Libiola (NW Italy): morphological, mineralogical, and geochemical study, Carbone Cristina; Dinelli Enrico; De Waele Jo
Chemistry and Karst, White, William B.
The karst paradigm: changes, trends and perspectives, Klimchouk, Alexander
Long-term erosion rate measurements in gypsum caves of Sorbas (SE Spain) by the Micro-Erosion Meter method, Sanna, Laura; De Waele, Jo; Calaforra, José Maria; Forti, Paolo
The use of damaged speleothems and in situ fault displacement monitoring to characterise active tectonic structures: an example from Zapadni Cave, Czech Republic , Briestensky, Milos; Stemberk, Josef; Rowberry, Matt D.;
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
Aapg Bulletin/AAPG Bulletin, 2006, Vol 90, Issue 11, p. 1719-1738
Evidence against the Dorag (mixing-zone) model for dolomitization along the Wisconsin arch - A case for hydrothermal diagenesis
Luczaj, J. A.
Abstract:
Ordovician carbonates near the Wisconsin arch represent the type locality in ancient rocks for the Dorag, or mixing-zone, model for dolomitization. Field, petrographic, and geochemical evidence suggests a genetic link between the pervasive dolomite, trace Mississippi Valley–type (MVT) minerals, and potassium (K)-silicate minerals in these rocks, which preserve a regional hydrothermal signature. Constraints were placed on the conditions of water-rock interaction using fluid-inclusion methods, cathodoluminescence and plane-light petrography, stable isotopic analyses, and organic maturity data. Homogenization temperatures of two-phase aqueous fluid inclusions in dolomite, sphalerite, and quartz range between 65 and 120°C. Freezing data suggest a Na-Ca-Mg-Cl-H2O fluid with salinities between 13 and 28 wt.% NaCl equivalent. The pervasive dolomitization of Paleozoic rocks on and adjacent to the Wisconsin arch was the result of water-rock interaction with dense brines at elevated temperatures, and it was coeval with regional trace MVT mineralization and K-silicate diagenesis. A reevaluation of the Dorag (mixing-zone) model for dolomitization, in conjunction with convincing new petrographic and geochemical evidence, has ruled out the Dorag model as the process responsible for pervasive dolomitization along the Wisconsin arch and adds to the abundant body of literature that casts serious doubt about the viability of the Dorag model in general.
John Luczaj is an assistant professor of earth science in the Department of Natural and Applied Sciences at the University of Wisconsin–Green Bay. He earned his B. S. degree in geology from the University of Wisconsin–Oshkosh. This was followed by an M.S. degree in geology from the University of Kansas. He holds a Ph.D. in geology from Johns Hopkins University in Baltimore, Maryland. His recent interests include the investigation of water-rock interaction in Paleozoic sedimentary rocks in the Michigan Basin and eastern Wisconsin. Previous research activities involve mapping subsurface uranium distributions, reflux dolomitization, and U-Pb dating of Permian Chase Group carbonates in southwestern Kansas.
Ordovician carbonates near the Wisconsin arch represent the type locality in ancient rocks for the Dorag, or mixing-zone, model for dolomitization. Field, petrographic, and geochemical evidence suggests a genetic link between the pervasive dolomite, trace Mississippi Valley–type (MVT) minerals, and potassium (K)-silicate minerals in these rocks, which preserve a regional hydrothermal signature. Constraints were placed on the conditions of water-rock interaction using fluid-inclusion methods, cathodoluminescence and plane-light petrography, stable isotopic analyses, and organic maturity data. Homogenization temperatures of two-phase aqueous fluid inclusions in dolomite, sphalerite, and quartz range between 65 and 120°C. Freezing data suggest a Na-Ca-Mg-Cl-H2O fluid with salinities between 13 and 28 wt.% NaCl equivalent. The pervasive dolomitization of Paleozoic rocks on and adjacent to the Wisconsin arch was the result of water-rock interaction with dense brines at elevated temperatures, and it was coeval with regional trace MVT mineralization and K-silicate diagenesis. A reevaluation of the Dorag (mixing-zone) model for dolomitization, in conjunction with convincing new petrographic and geochemical evidence, has ruled out the Dorag model as the process responsible for pervasive dolomitization along the Wisconsin arch and adds to the abundant body of literature that casts serious doubt about the viability of the Dorag model in general.
John Luczaj is an assistant professor of earth science in the Department of Natural and Applied Sciences at the University of Wisconsin–Green Bay. He earned his B. S. degree in geology from the University of Wisconsin–Oshkosh. This was followed by an M.S. degree in geology from the University of Kansas. He holds a Ph.D. in geology from Johns Hopkins University in Baltimore, Maryland. His recent interests include the investigation of water-rock interaction in Paleozoic sedimentary rocks in the Michigan Basin and eastern Wisconsin. Previous research activities involve mapping subsurface uranium distributions, reflux dolomitization, and U-Pb dating of Permian Chase Group carbonates in southwestern Kansas.
Keywords: hypogene karst