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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

Speleology in Kazakhstan

Shakalov on 11 Jul, 2012
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That lime sink is see sinkhole.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
See all featured articles from other geoscience journals

175 FIFTH AVE, NEW YORK, NY 10010
Environmental Geology, 1997, Vol 30, Issue 3, p. 46-58
Thermodynamic equilibrium, kinetics, activation barriers, and reaction mechanisms for chemical reactions in Karst Terrains
Abstract:
Chemical reactions pertinent to karst systems divide broadly into (a) speciation reactions within aqueous solutions, (b) dissolution/precipitation and other acid/base reactions between aqueous solutions and solid minerals, and (c) redox reactions involving various carbon and sulfur-bearing species. As a backdrop against which other chemistry can be evaluated, selected phase diagrams and equilibrium speciation diagrams were calculated for the system Ca--Mg--O--H--C--S. The kinetics of reactions within this system span time scales from milliseconds for homogeneous reactions in solution through hundreds of hours for carbonate mineral dissolution reactions, to geologic time scales for reactions such as the aragonite/calcite inversion or the oxidation/reduction of native sulfur. In purely inorganic systems, kinetic barriers, typically on the order of tens of kJ/mole, are set by nucleation processes and by activated complex formation. Biological processes impact the purely inorganic chemistry by the following mechanisms: (a) Secretions and waste products from biological activity or consumption of CO2 by organisms changes the chemistry in the microenvironments of reaction surfaces. Oxidation potentials, pH, and ion activities may be modified, thus shifting equilibria. (b) Reaction rates may be increased due to modification of activated complexes and thus the activation barriers to reaction. (c) Organic compounds or microorganisms may act as substrates, thus lowering nucleation barriers. The preservation of microorganisms in cave deposits does not necessarily prove a cause and effect relationship