Karst and Cave RSS news feed Like us on Facebook! follow us on Twitter!
Community news

Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

Speleology in Kazakhstan

Shakalov on 11 Jul, 2012
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That sinkhole pond is (american.) small lake in closed depression in limestone, due to an impervious clay floor or to intersection of depression with the water table [10]. see doline lake.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

What is Karstbase?

Search KARSTBASE:

keyword
author

Browse Speleogenesis Issues:

KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
Engineering challenges in Karst, Stevanović, Zoran; Milanović, Petar
See all featured articles
Featured articles from other Geoscience Journals
Geochemical and mineralogical fingerprints to distinguish the exploited ferruginous mineralisations of Grotta della Monaca (Calabria, Italy), Dimuccio, L.A.; Rodrigues, N.; Larocca, F.; Pratas, J.; Amado, A.M.; Batista de Carvalho, L.A.
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
See all featured articles from other geoscience journals

Search in KarstBase

Your search for groundwater chemistry (Keyword) returned 12 results for the whole karstbase:
The role of tributary mixing in chemical variations at a karst spring, Milandre, Switzerland, , Perrin J. , Jeannin P. Y. , Cornaton F. ,
SummarySolute concentration variations during flood events were investigated in a karst aquifer of the Swiss Jura. Observations were made at the spring, and at the three main subterraneous tributaries feeding the spring. A simple transient flow and transport numerical model was able to reproduce chemographs and hydrographs observed at the spring, as a result of a mixing of the concentration and discharge of the respective tributaries. Sensitivity analysis carried out with the model showed that it is possible to produce chemical variations at the spring even if all tributaries have constant (but different for each of them) solute concentrations. This process is called tributary mixing. The good match between observed and modelled curves indicate that, in the phreatic zone, tributary mixing is probably an important process that shapes spring chemographs. Chemical reactions and other mixing components (e.g. from low permeability volumes) have a limited influence.Dissolution-related (calcium, bicarbonate, specific conductance) and pollution-related parameters (nitrate, chloride, potassium) displayed slightly different behaviours: during moderate flood events, the former showed limited variations compared to the latter. During large flood events, both presented chemographs with significant changes. No significant event water participates in moderate flood events and tributary mixing will be the major process shaping chemographs. Variations are greater for parameters with higher spatial variability (e.g. pollution-related). Whereas for large flood events, the contribution of event water becomes significant and influences the chemographs of all the parameters. As a result, spring water vulnerability to an accidental pollution is low during moderate flood events and under base flow conditions. It strongly increases during large flood events, because event water contributes to the spring discharge

Groundwater chemistry and cation budgets of tropical karst outcrops, Peninsular Malaysia, I. Calcium and magnesium, 1989, Crowther J,
The discharge and chemical properties of 217 autogenic groundwaters were monitored over a 1-yr period in the tower karsts of central Selangor and the Kinta Valley, and in the Setul Boundary Range. Because of differences in soil PCO2, calcium concentrations are significantly higher in the Boundary Range (mean, 82.5 mg l-1) than in the tower karst terrain (44.6 mg l-1). Local differences in both source area PCO2 and amounts of secondary deposition underground cause marked intersite variability, particularly in the tower karst. Dilution occurs during flood peaks in certain conduit and cave stream waters. Generally, however, calcium correlates positively with discharge, since the amount of secondary deposition per unit volume of water decreases at higher flows. Magnesium concentrations and Mg:Ca Mg ratios of groundwaters are strongly influenced by bedrock composition, though bedrock heterogeneity and the kinetics and equilibria of carbonate dissolution reactions preclude extremely low or high Mg:Ca Mg values. Net chemical denudation rates range from 56.6 to 70.9 m3km2yr-1.The results are considered in relation to cation fluxes in surface runoff, soil throughflow and nutrient cycling. Preliminary calcium and magnesium budgets show that (1) dissolutional activity is largely confined to the near-surface zone; and (2) the annual uptake of calcium and magnesium by tropical limestone forests is similar in magnitude to the net solute output in groundwaters

High-resolution temporal record of Holocene ground-water chemistry; tracing links between climate and hydrology, 1996, Banner Jl, Musgrove M, Asmerom Y, Edwards Rl, Hoff Ja,
Strontium isotope analysis of precisely dated calcite growth layers in Holocene speleothems from Barbados, West Indies, reveals high-resolution temporal variations in ground-water composition and may provide a new approach to documenting the links between climate variability and fluctuations in the hydrologic cycle such as recharge rates and flow paths. The speleothems grew in a cave that developed in a fresh-water aquifer in uplifted Pleistocene reef limestones. Three periods of ground-water Sr isotope evolution are observed: 87 Sr/ 86 Sr values decreased from 6 to 4 ka, increased from 4 to 1 ka, and decreased again after 1 ka. The Sr isotope oscillations appear to record periodic variations in the relative Sr fluxes to ground water from exchangeable soil sites vs. carbonate mineral reactions, as reflected in 87 Sr/ 86 Sr values of modern Barbados ground waters. A hydrologic model that explains changes in ground-water flow routes in karst aquifers as a function of amount of rainfall recharge can account for the speleothem Sr isotope record. Independent Holocene climate records that indicate a major period of aridity at around 1.3-1.1 ka in the American tropics correspond with periodic variations in rainfall on Barbados that are predicted by this hydrologic model

Geochemical modeling of groundwater in karst area and its application at Pingdingshan coalfield, 1998, Wang G. C. , Tao S. , Shen Z. L. , Zhong Z. X. ,
Several approaches including hydrogeochemistry and isotope hydrogeology have been used to investigate the karst groundwater systems at Pingdingshan coalfield in recent years. The results of the modeling and evaluation of groundwater chemistry, as parts of recent research progress at the area, are presented. The characteristics of Cambrian karst groundwater flow was analyzed in terms of tritium distribution of groundwater based on the fact that the Guodishan fault, the largest one within the coalfield, is divided into permeable (southern and northern) and impermeable (middle) sections. The evolution of groundwater chemistry, the suitability of geothermometers and the feature of karst development were deduced and discussed using the speciation modeling and mass balance approach

Spatial and Temporal Variation of Groundwater Chemistry in Pettyjohns Cave, Northwest Georgia, USA, 1999, Mayer, J.
A longitudinal study of water chemistry in Pettyjohns Cave, Georgia, reveals a wide range of major ion water chemistry at different sampling points within the cave, and pronounced seasonal water-chemistry variations at some locations. The cave occurs in the Mississippian Bangor Limestone on the east side of Pigeon Mountain in the Appalachian Plateaus physiographic province of northwest Georgia, USA. Four sampling points within the cave were monitored at approximately 2- to 3-month intervals for 22 months: a major conduit stream; a small conduit tributary; water dripping into the cave through a small fracture; and water dripping from active speleothems. Other waters, including surface water, were sampled as available. Samples were analyzed for temperature, pH, specific conductance, alkalinity, and major ions. Most spatial water chemistry trends within the cave appear to be the result of rock-water interaction along distinct subsurface flowpaths. Temporal variations, most pronounced in conduit streams, result primarily from mixing of distinct waters in varying ratios, although seasonal changes in CO2 partial pressure may account for some variation. Results illustrate the inherent spatial and temporal variability of water chemistry in karst aquifers and point to the need to design sampling programs carefully.

Patterns in groundwater chemistry resulting from groundwater flow, 1999, Pieter J. Stuyfzand,

Types of karst and evolution of hydrogeologic settings, 2000, Klimchouk A. , Ford D.
Karst is treated as a specific kind of fluid circulation system capable to self-development and self-organization. Active karst may evolve at wide range of geological environments, from deep-seated (without any apparent relation to the surface) to sub-surface, and be represented by confined and unconfined circulation systems. Extrinsic factors and intrinsic mechanisms of karst development change regularly and considerably within the general cycle of geological evolution of a soluble rocks or, more specifically, within hydrogeologic cycle. The latter encompasses a period of exposure between major transgressions and is characterized by progressively expanding meteoric groundwater circulation. A broad evolutionary approach is therefore needed to differentiate between karst types, which concurrently represent distinct stages of karst development. This is also a mean to adequately classify speleogenetic settings. Evolutionary typology of karst considers the whole cycle of a formation's life, from deposition (syngenetic karst) through deep burial to exposure and denudation. The group of intrastratal karst types includes deep-seated, subjacent, entrenched and denuded karst, the latter also fall into the group of exposed karst types. Exposed karst includes also open karst which represents the pure line of exposed development, that is karst evolved solely when the soluble rock has been exposed to the surface. Exposed karst development can be interrupted by a subsequent burial (buried karst), with paleokarst formed in result, and rejuvenated by exhumation. The types of karst are marked by characteristic associations of structural prerequisites for groundwater flow and speleogenesis, flow regime, recharge mode and recharge/discharge configurations, groundwater chemistry and a degree of inheritance. Consequently, these associations generate particular types of caves.

Speleogenesis: Evolution of Karst Aquifers., 2000,
The aim of this book is to present advances made in recent decades in our understanding of the formation of dissolutional caves, and to illustrate the role of cave genetic ( speleogenetic ) processes in the development of karst aquifers. From the perspective of hydrogeology, karst ground water flow is a distinct kind of fluid circulation system, one that is capable of self-organization and self-development due to its capacity to dissolve significant amounts of the host rock and transport them out of the system. Fluid circulation in soluble rocks becomes more efficiently organized by creating, enlarging and modifying patterns of cave conduits, the process of speleogenesis. We can assert that karst ground water flow is a function of speleogenesis and vice versa . The advances in cave science are poorly appreciated in what may be termed ?mainstream hydrogeology?, which retains a child-like faith in flow models developed in the sand box. Many karst students also will not be aware of all emerging concepts of cave origin because discussions of them are scattered through journals and books in different disciplines and languages, including publications with small circulation. An understanding of principles of speleogenesis and its most important controls is indispensable for proper comprehension of the evolution of the karst system in general and of karst aquifers in particular. We hope this book will be useful for both karst and cave scientists, and for general hydrogeologists dealing with karst terranes. This book is a pioneer attempt by an international group of cave scientists to summarize modern knowledge about cave origin in various settings, and to examine the variety of approaches that have been adopted. Selected contributions from 44 authors in 15 nations are combined in an integrated volume, prepared between 1994 and 1998 as an initiative of the Commission of Karst Hydrogeology and Speleogenesis, International Speleological Union. Despite a desire to produce an integrated book, rather than a mere collection of papers, the editors' policy has not been directed toward unifying all views. Along with some well-established theories and approaches, the book contains new concepts and ideas emerging in recent years. We hope that this approach will stimulate further development and exchange of ideas in cave studies and karst hydrogeology. Following this Introduction, (Part 1), the book is organized in seven different parts, each with sub-chapters. Part 2 gives a history of speleogenetic studies, tracing the development of the most important ideas from previous centuries (Shaw, Chapter 2.1) through the early modern period in the first half of this century (Lowe, Chapter 2.2) to the threshold of modern times (W.White, Chapter 2.3). The present state of the art is best illustrated by the entire content of this book. Part 3 overviews the principal geologic and hydrogeologic variables that either control or significantly influence the differing styles of cave development that are found. In Chapter 3.1 Klimchouk and Ford introduce an evolutionary approach to the typology of karst settings, which is a taken as a base line for the book. Extrinsic factors and intrinsic mechanisms of cave development change regularly and substantially during the general cycle of geological evolution of a soluble rock and , more specifically, within the hydrogeologic cycle. The evolutionary typology of karst presented in this chapter considers the entire life cycle of a soluble formation, from deposition (syngenetic karst) through deep burial, to exposure and denudation. It helps to differentiate between karst types which may concurrently represent different stages of karst development, and is also a means of adequately classifying speleogenetic settings. The different types of karst are marked by characteristic associations of the structural prerequisites for groundwater flow and speleogenesis, flow regime, recharge mode and recharge/discharge configurations, groundwater chemistry and degree of inheritance from earlier conditions. Consequently, these associations make a convenient basis to view both the factors that control cave genesis and the particular types of caves. Lithological and structural controls of speleogenesis are reviewed in general terms in Chapters 3.2 (Klimchouk and Ford). Lowe in Chapter 3.3 discusses the role of stratigraphic elements and the speleo-inception concept. Palmer in Chapter 3.4 overviews the hydrogeologic controls of cave patterns and demonstrates that hydrogeologic factors, the recharge mode and type of flow in particular, impose the most powerful controls on the formation of the gross geometry of cave systems. Hence, analysis of cave patterns is especially useful in the reconstruction of environments from paleokarst and in the prediction and interpretation of groundwater flow patterns and contaminant migration. Any opportunity to relate cave patterns to the nature of their host aquifers will assist in these applied studies as well. Osborne (Chapter 3.7) examines the significance of paleokarst in speleogenesis. More specific issues are treated by Klimchouk (The nature of epikarst and its role in vadose speleogenesis, Chapter 3.5) and by V.Dublyansky and Y.Dublyansky (The role of condensation processes, Chapter 3.6). Part 4 outlines the fundamental physics and chemistry of the speleogenetic processes (Chapter 4.1) and presents a variety of different approaches to modeling cave conduit development (Chapter 4.2). In Chapter 4.1, the chemical reactions during the dissolution of the common soluble minerals, calcite, gypsum, salt and quartz, are discussed with the basic physical and chemical mechanisms that determine their dissolution rates. As limestone is the most common karst rock and its dissolution is the most complex in many respects, it receives the greatest attention. Dreybrodt (Section 4.1.1) and Dreybrodt and Eisenlohr (Section 4.1.2) provide advanced discussion and report the most recent experimental data, which are used to obtain realistic dissolution rates for a variety of hydrogeologic conditions and as input for modeling the evolution of conduits. Although direct comparisons between theoretical or analytical dissolution rates and those derived from field measurements is difficult, a very useful comparison is provided by W.White (Section 4.1.3). The bulk removal of carbonate rock from karst drainage basins can be evaluated either by direct measurement of rock surface retreat or by mass balance within known drainage basins. All of these approaches make sense and give roughly accurate results that are consistent with theoretical expectations. It is well recognized today that the earliest, incipient, phases of speleogenesis are crucial in building up the pattern of conduits that evolve into explorable cave systems. It is difficult to establish the major controls on these initial stages by purely analytical or intuitive methods, so that modeling becomes particularly important. Various approaches are presented in Chapter 4.2. Ford, Ewers and Lauritzen present the results of systematic study of the propagation of conduits between input and output points in an anisotropic fissure, using a variety of hardware and software models, in series representing the "single input", "multiple inputs in one rank", and "multiple inputs in multiple ranks" cases (Section 4.2.1). The results indicate important details of the competitive development of proto-conduits and help to explain branching cave patterns. In the competition between inputs, some principal tubes in near ranks first link ("breakthrough") to an output boundary. This re-orients the flowfields of failed nearby competitors, which then extend to join the principal via their closest secondaries. The process extends outwards and to the rear, linking up all inputs in a "cascading system". The exploding growth of computer capability during the last two decades has greatly enhanced possibilities for digital modeling of early conduit development. Investigating the growth of a single conduit is a logical first step in understanding the evolution of caves, realized here by Dreybrodt and Gabrov?ek in the form of a simple mathematical model (Section 4.2.2) and by Palmer by numerical finite-difference modeling (Section 4.2.3). The models show that positive feedback loops operate; widening a fracture causes increasing flow through it, therefore dissolution rates increase along it and so on, until finally a dramatic increase of flow rates permits a dramatic enhancement of the widening. This breakthrough event terminates the initial stage of conduit evolution. From then on the water is able to pass through the entire conduit while maintaining sufficient undersaturation to preserve low-order kinetics, so the growth rate is very rapid, at least from a geological standpoint -- usually about 0.001-0.1 cm/yr. The initiation ("breakthrough") time depends critically on the length and the initial width of the fracture and, for the majority of realistic cases, it covers a time range from a few thousand years to ten million years in limestones. The modeling results give a clear explanation of the operation of selectivity in cave genesis. In a typical unconfined karst aquifer there is a great range of enlargement rates along the competing flow routes, and only a few conduits will grow to enterable size. The modeling also provides one starting point (others are discussed in Chapter 5.2) to explain uniform maze patterns, which will be favored by enlargement of all openings at comparable rates where the discharge/length ratio is great enough. Single-conduit modeling has the virtue of revealing how the cave-forming variables relate to each other in the simplest possible way. Although it is more difficult to extend this approach to two dimensions, many have done so (e.g. Groves & Howard, 1994; Howard & Groves, 1995; in this volume ? Ford, Ewers and Lauritzen, Section 4.2.1; Dreybrodt and Siemers, Section 4.2.4, and Sauter and Liedl, Section 4.2.5). The modeling performed by Dreybrodt and Siemers shows that the main principles of breakthrough derived from one-dimensional models remain valid. The evolution of karst aquifers has been modeled for a variety of different geological settings, including also variation in lithology with respect to the dissolution kinetics. Sauter and Liedl simulate the development of conduits at a catchment scale for fissured carbonate rocks with rather large initial openings (about 1 mm). The approach is based upon hydraulic coupling of a pipe network to matrix continuum in order to represent the well-known duality of karst aquifer flow systems. It is also shown how understanding of the genesis of karst aquifers and modeling of their development can assist in characterization of the conduit system, which dominates flow and transport in karst aquifers. An important point that has emerged from cave studies of the last three decades is that no single speleogenetic model applies to all geologic and hydrologic settings. Given that settings may also change systematically during the evolutionary geological cycles outlined above (Chapter 3.1), an evolutionary approach is called for. This is attempted in Part 5, which is organized to give extended accounts of speleogenesis in the three most important settings that we recognize: coastal and oceanic (Chapter 5.1), deep-seated and confined (Chapter 5.2) and unconfined (Chapter 5.3). Each Chapter begins with a review of modern ideas on cave development in the setting, followed by representative case studies. The latter include new accounts of some "classic" caves as well as descriptions of other, little-known cave systems and areas. Readers may determine for themselves how well the real field examples fit the general models presented in the introductory sections. Mylroie and Carew in Chapter 5.1 summarize specific features of cave and karst development in young rocks in coastal and island settings that result from the chemical interactions between fresh and salt waters, and the effects of fluctuating sea level during the Quaternary. The case studies include a review of syngenetic karst in coastal dune limestones, Australia (S.White, 5.1.1) and an example of speleogenesis on tectonically active carbonate islands (Gunn and Lowe, 5.1.2). Klimchouk in Chapter 5.2 reviews conditions and mechanisms of speleogenesis in deep-seated and confined settings, one of the most controversial but exciting topics in modern cave research. Conventional karst/speleogenetic theories are concerned chiefly with shallow, unconfined geologic settings, supposing that the karstification found there is intimately related to surface conditions of input and output, with the dissolution being driven by downward meteoric water recharge. The possibility of hypogenic karstification in deeper environments has been neglected for a long time, and the quite numerous instances of karst features found at significant depths have usually been interpreted as buried paleokarst. However, the last decade has seen a growing recognition of the variety and importance of hypogene dissolution processes and of speleogenesis under confined settings which often precedes unconfined development (Hill, 1987, 1995; Klimchouk, 1994, 1996, 1997; Lowe, 1992; Lowe & Gunn, 1995; Mazzullo & Harris, 1991, 1992; Palmer, 1991, 1995; Smart & Whitaker, 1991; Worthington, 1991, 1994; Worthington & Ford, 1995). Confined (artesian) settings were commonly ignored as sites for cave origin because the classic concept of artesian flow implies long lateral travel distances for groundwater within a soluble unit, resulting in a low capacity to generate caves in the confined area. However, the recognition of non-classical features in artesian flow, namely the occurrence of cross-formation hydraulic communication within artesian basins, the concepts of transverse speleogenesis and of the inversion of hydrogeologic function of beds in a sequence, allows for a revision of the theory of artesian speleogenesis and of views on the origin of many caves. It is proposed that artesian speleogenesis is immensely important to speleo-inception and also accounts for the development of some of the largest known caves in the world. Typical conditions of recharge, the flow pattern through the soluble rocks, and groundwater aggressiveness favor uniform, rather than competing, development of conduits, resulting in maze caves where the structural prerequisites exist. Cross-formational flow favors a variety of dissolution mechanisms that commonly involve mixing. Hydrogeochemical mechanisms of speleogenesis are particularly diverse and potent where carbonate and sulfate beds alternate and within or adjacent to hydrocarbon-bearing sedimentary basins. Hypogene speleogenesis occurs in rocks of varied lithology and can involve a variety of dissolution mechanisms that operate under different physical constraints but create similar cave features. Case studies include the great gypsum mazes of the Western Ukraine (Klimchouk, Section 5.2.1), great maze caves in limestones in Black Hills, South Dakota (Palmer, Section 5.2.2) and Siberia (Filippov, Section 5.2.3), karstification in the Redwall aquifer, Arizona (Huntoon, Section 5.2.4), hydrothermal caves in Hungary (Y.Dublyansky, Section 5.2.6), and sulfuric acid speleogenesis (Lowe, Bottrell and Gunn, Section 5.2.7, and Hill, Section 5.2.8). Y.Dublyansky summarizes the peculiar features of hydrothermal speleogenesis (Section 5.2.5), and V.Dublyansky describes an outstanding example of a hydrothermal cavity, in fact the largest ever recorded by volume, in the Rhodope Mountains (Section 5.2.9). Recognition of the scale and importance of deep-seated speleogenesis and of the hydraulic continuity and cross-formational communications between aquifers in artesian basins is indispensable for the correct interpretation of evolution of karst aquifers, speleogenetic processes and associated phenomena, regional karst water-resource evaluations, and the genesis of certain karst-related mineral deposits. These and other theoretical and practical implications still have to be developed and evaluated, which offers a wide field for further research efforts. Ford in Chapter 5.3 reviews theory of speleogenesis that occurs where normal meteoric waters sink underground through the epikarst or dolines and stream sinks, etc. and circulate in the limestone or other soluble rocks without any major artesian confinement. These are termed common caves (Ford & Williams, 1989) because they probably account for 90% or more of the explored and mapped dissolutional caves that are longer than a few hundred meters. This estimate reflects the bias in exploration; caves formed in unconfined settings and genetically related to surface recharge are the most readily accessible and hence form the bulk of documented caves. Common caves display chiefly the branchwork forms where the dissolutional conduits occupy only a tiny proportion of the total length or area of penetrable fissures that is available to the groundwaters. The rules that govern the selection of the successful linkages that will be enlarged into the branchwork pattern are supported in the models presented in Chapter 4.2. In the long section caves may be divided into deep phreatic, multi-loop, mixed loop and water table, and ideal water table types, with drawdown vadose caves or invasion vadose caves above them. Many large systems display a mixture of the types. The concepts of plan pattern construction, phreatic, water table or vadose state, and multi-phase development of common caves are illustrated in the case studies that follow the introduction. They are organized broadly to begin with examples of comparatively simple deep phreatic and multi-loop systems (El Abra, Mexico, Ford, Section 5.3.1 and Castleguard Cave, Canada, Ford, Lauritzen and Worthington, Section 5.3.2), proceeding to large and complex multi-phase systems such as the North of Thun System, Switzerland (Jeannin, Bitterly and Hauselmann, Section 5.3.3) and Mammoth Cave, Kentucky (Palmer, Section 5.3.8), to representatives of mixed vadose and phreatic development in mountainous regions (the Alps, Audra, Section 5.3.4; the Pyrenees, Fernandez, Calaforra and Rossi, Section 5.3.5; Mexico, Hose, Section 5.3.6) and where there is strong lithologic or structural control (Folded Appalachians, W.White, Section 5.3.7; gypsum caves in the South of Spain, Calaforra and Pulido-Bosch, Section 5.3.10). Two special topics are considered by W.White in Section 5.3.9 (Speleogenesis of vertical shafts in the eastern US) and Palmer (Maze origin by diffuse recharge through overlying formation). The set concludes with two instances of nearly ideal water table cave development (in Belize and Hungary, Ford, Section 5.3.12), and a review of the latest models of speleogenesis from the region where modern karst studies in the West began, the Classical Karst of Slovenia and Trieste (?u?ter?ic, Section 5.3.13). In Parts 2-5 attention is directed primarily on how the gross geometry of a cave system is established. Part 6 switches focus to the forms at meso- and micro- scales, which can be created during enlargement of the cave. Lauritzen and Lundberg in Chapter 6.1 summarize the great variety of erosional forms ( speleogenetic facies ) that can be created by a wide range of speleogenetic agents operating in the phreatic or vadose zones. Some forms of cave passages have been subject to intensive research and may be interpreted by means of simple physical and chemical principles, but many others are polygenetic and hence difficult to decipher with certainty. However, in addition to the analysis of cave patterns (see Chapter 3.4), each morphological element is a potential tool that can aid our inferences on the origin of caves and on major characteristics of respective past hydrogeological settings. In Chapter 6.2 E.White and W.White review breakdown morphology in caves, generalizing that the processes are most active during the enlargement and decay phases of cave development. Early in the process breakdown occurs when the flow regime shifts from pipe-full conditions to open channel conditions (i.e. when the roof first loses buoyant support) and later in the process breakdown becomes part of the overall degradation of the karst system. The chapter addresses the mechanism of breakdown formation, the geological triggers that initiate breakdown, and the role that breakdown plays in the development of caves. As the great majority of both theoretical considerations and case studies in this book deal with speleogenesis in carbonate rocks, it is useful to provide a special forum to examine dissolution cave genesis in other rocks. This is the goal of Part 7. Klimchouk (7.1) provides a review of speleogenesis in gypsum. This appears to be a useful playground for testing the validity and limitations of certain general speleogenetic concepts. Differences in solution kinetics between gypsum and calcite impose some limitations and peculiar features on the early evolution of conduits in gypsum. These peculiarities appear to be an extreme and more obvious illustration of some rules of speleogenetic development devised from conceptual and digital modeling of early conduit growth in limestones. For instance, it is shown (e.g. Palmer, 1984, 1991; Dreybrodt, 1996; see also Chapter 3.4 and Section 4.2.2) that initiation of early, narrow and long pathways does not seem feasible under linear dissolution rate laws (n=1) due to exponential decrease of the dissolution rates. Although the dissolution kinetics of gypsum are not well known close to equilibrium it is generally assumed that they are controlled entirely by diffusion and therefore linear. If dissolution of gypsum is solely diffusion-controlled, with no change in the kinetic order, conduit initiation could not occur in phreatic settings or by lateral flow through gypsum from distant recharge areas in artesian settings. Hence, the fact that maze caves are common in gypsum in artesian conditions (see Section 5.2.1) gives strong support to a general model of "transverse" artesian speleogenesis where gypsum beds are underlain by, or sandwiched between, insoluble or low-solubility aquifers (Chapter 5.2), and suggests that it may be applicable to cave development in carbonates. In unconfined settings, speleogenesis in gypsum occurs along fissures wide enough to support undersaturated flow throughout their length. Linear or crudely branching caves overwhelmingly predominate, which rapidly adjust to the contemporary geomorphic setting and to the maximum available recharge. Also, if considerable conduit porosity has been created in deep-seated settings, it provides ready paths for more intense groundwater circulation and further cave development when uplift brings the gypsum into the shallow subsurface. Speleogenesis in salt, reviewed in general and exemplified by the Monte Sedom case in Israel (Frumkin, Chapter 7.2), has been documented only in open, unconfined settings, where it provides a model for simple vadose cave development. Chapter 7.3 deals with speleogenesis in quartzites, illustrated by case studies from southeastern Minas Gerais, Brasil (Correa Neto, 7.3.1) and South Africa (Martini, 7.3.2). The process involves initial chemical weathering of the quartzite to create zones of friable rocks (sanding, or arenisation) which then are removed by piping, with further conduit enlargement due to mechanical erosion by flowing water. Part 8 combines the theoretical with some applied aspects of speleogenetic studies. Worthington, Ford and Beddows (8.1) show the important implications of what might be termed "speleogenetic wisdom" when studying ground water behaviour in karst. They examine some standard hydrogeological concepts in the light of knowledge of caves and their patterns, considering a range of case studies to identify the characteristic enhancement of porosity and permeability due to speleogenesis that occurs in carbonate rocks. The chapter focuses on unconfined carbonate aquifers as these are the most studied from the speleological perspective and most important for water supplies. Four aquifers, differing in rock type, recharge type (allogenic and autogenic), and age (Paleozoic, Mesozoic and Cenozoic), are described in detail to demonstrate the extent of dissolutional enhancement of porosity and permeability. It is shown that all four cases are similar in hydraulic function, despite the fact that some of them were previously characterized as different end members of a "karst ? non-karst" spectrum. Enhancement of porosity by dissolution is relatively minor: enhancement of permeability is considerable because dissolution has created dendritic networks of channels able to convey 94% or more of all flow in the aquifer, with fractures providing a small proportion and the matrix a negligible amount. These conclusions may be viewed as a warning to hydrogeologists working in carbonate terranes: probably the majority of unconfined aquifers function in a similar manner. Sampling is a major problem in their analysis because boreholes (the conventional exploration tool in hydrogeology) are unlikely to intersect the major channels that are conveying most of the flow and any contaminants in it. It is estimated, using examples of comprehensively mapped caves, that the probability of a borehole intersecting a conduit ranges from 1 in 50 to 1 in 1000 or more. Boreholes simply cannot be relied upon to detect the presence of caves or to ?characterise? the hydrologic functioning of cavernous aquifers. Wherever comprehensive evidence has been collected in unconfined carbonate aquifers (cave mapping plus boreholes plus lab analysis of core samples) it suggests that dissolution inexorably results in a similar structure, with channel networks providing most of the permeability of the aquifer, yet occupying a very minor fraction of its volume (Worthington, Ford and Beddows). Lowe (Chapter 8.2) focuses on developments in understanding the vital role played by karstic porosity, (broadly viewed as being the product of speleogenesis), in the migration of mineralizing fluids (or hydrocarbons) and in their deposition (or storage), and comments on the potential role of new speleogenetic concepts in developing greater understanding in the future. Although some early workers were clearly aware of actual evidence for some kind of relationship, and others noted its theoretical likelihood, it has been ignored by many until relatively recent times. This shortfall has gradually been redressed; new understanding of the extent and variety of karst processes is ensuring that new relationships are being recognized and new interpretations and models are being derived. The chapter does not pretend to give a comprehensive account of the topic but clearly demonstrates the wide applicability of speleogenetic knowledge to issues in economic geology. In Chapter 8.3 Aley provides an overview of the water and land-use problems that occur in areas with conduit aquifers. He stresses that sound land management must be premised on an understanding that karst is a three-dimensional landscape where the surface and subsurface are intimately and integrally connected. Failure to recognize that activity at the surface affects the subsurface, and the converse, has long been the root cause of many of the problems of water and land use in karst regions. Karst areas have unique natural resource problems, whose management can have major economic consequences. Although there is an extensive literature on the nature of particular problems, resource protection and hazard minimization strategies in karst, it rarely displays an advanced understanding of the processes of the conduit formation and their characteristics yet these will always be involved. This book does not pretend to be a definitive text on speleogenesis. However, it is hoped that readers will find it to be a valuable reference source, that it will stimulate new ideas and approaches to develop and resolve some of the remaining problems, and that it will promote an appreciation of the importance of speleogenetic studies in karst hydrogeology and applied environmental sciences. Acknowledgements: We sincerely thank all contributors for their willing cooperation in the long and difficult process of preparing this book, for their participation in developing its logic and methodology and their cheerful response to numerous requests. We thank all colleagues who discussed the work with us and encouraged it in many ways, even though not contributing to its content as authors. We are particularly grateful to Margaret Palmer for invaluable help in editing the English in many contributions, to Nataly Yablokova for her help in performing many technical tasks and to Elizabeth White who prepared comprehensive index. Our thanks are due to Dr. David Drew, Dr. Philip LaMoreaux, Dr. George Moore and Prof. Marian Pulina for reviewing the manuscript and producing constructive notes and comments on improvement of the final product. The organizational costs and correspondence related to the preparation of the book were partially sponsored by the National Speleological Society, the publisher. We thank David McClurg, the Chair of the NSS Special Publication Committee, for his extensive technical and organizational support in the preparation and publishing processes.

Geochemical and statistical evidence of recharge, mixing, and controls on spring discharge in an eogenetic karst aquifer, 2009, Moore Paul J. , Martin Jonathan B. , Screaton Elizabeth J.

Information about sources of recharge, distributions of flow paths, and the extent of water–rock reactions in karst aquifers commonly result from monitoring spring chemistry and discharge. To investigate the relationship between spring characteristics and the complexities of karst aquifers, we couple variations in surface- and groundwater chemistry to physical conditions including river stage, precipitation, and  evapotranspiration (ET) within a sink-rise system through a 6-km portion of the Upper Floridan aquifer (UFA) in north-central Florida. Principal component analysis (PCA) of time series major-element compositions suggests that at least three sources of water affect spring discharge, including allogenic recharge into a swallet, diffuse recharge through a thin vadose zone, and water upwelling from deep within the aquifer. The deep-water source exerts the strongest influence on water chemistry by providing a majority of Na+, Mg2+, K+, Cl, and SO2 4 to the system. Anomalously high temperature at one of several monitoring wells reflects vertical flow of about 1 m/year. Mass-balance calculations suggest diffuse recharge and deep-water upwelling can provide up to 50% of the spring discharge; however, their contributions depend on head gradients between the conduit and surrounding aquifer matrix, which are influenced
by variations in precipitation, ET, and river stage. Our results indicate that upwelling from deep flow paths may provide significant contributions of water to spring discharge, and that monitoring only springs limits interpretations of karst systems by masking critical components of the aquifer, such as water sources and flow paths. These results also suggest the matrix in eogenetic aquifers is a major pathway for flow even in a system dominated by conduits.


Response of the Karst Phreatic Zone to Flood Events in a Major River (Bohemian Karst, Czech Republic) and its Implications for Cave Genesis, 2012, Vysok H. , Bruthans J. , k K. , Mls J.

Hydraulic and hydrochemical relationships between a medium gradient river and a karst aquifer were studied by water level and temperature logging combined with water geochemistry and d13C. The cave lakes are separated from the river by a floodplain up to 150 m wide formed by a gravel and sand layer up to 13 m thick covered with finegrained floodplain sediments. During minor discharge peaks (water level in the river , 1.5 m above the normal river stage), a water level oscillation in the cave lakes situated 40 to 190 m away from river is induced by the river level oscillation, but the river water does not enter any of the lakes. The groundwater chemistry in the cave lakes differs from that of the river water. Low bicarbonate content and high d13C values indicate that some of cave lakes’ waters have undergone CO2 degassing and calcite precipitation. During a major flood (recurrence interval . 100 years, level rising 7 m above the normal stage), the river water rapidly flooded the caves through openings in the river canyon (floodflow injection), while those connected to the river via alluvium only were flooded by an elevated groundwater stage, and the resulting water level rise was only about 50 percent of the river level increase. A simple hydraulic model was successfully used to simulate and explain the water table oscillations in the cave lakes. Flood-flow injection has recently been substantially reduced by low-permeability, fine-grained late Holocene fluvial sediments that cap coarse gravels in the river floodplain. Fast speleogenesis by flood injection would be expected in periods when the river canyon was bare or filled by gravel alone (glacial periods, transition to Holocene). Ice jams causing local increases in the river level are recognized as one of factors that can be important in speleogenesis.


An approach for collection of nearfield groundwater samples in submerged limestone caverns, 2013, Mills Aaron L. , Tysall Terrence N. , Herman Janet S.

Walls of submerged caves feeding Florida springs are often lined with a heavy mat of filamentous bacteria, many of which are able to oxidize reduced sulfur in groundwater migrating from the porous bedrock into the cave conduit. To determine changes in water chemistry as water passes through the microbial mat, a simple device made from standard well screen and sealed with a rubber stopper and controllable vents was installed in a hole drilled in the wall of the cave passage. The sampler was sealed in place with marine epoxy. we measured anions in water from the sampler and from the water-filled conduit taken just outside the sampler. Most anions measured viz., Cl, NO3, and PO43−, increased slightly between the matrix and conduit waters. However, traces of sulfide were measured in the water from the rock matrix, but not in the conduit. SO4 2−concentrations in the conduit were about twice that measured in the water from the sampler, about 22 and 11 mg SO42− L−1, respectively, providing further evidence that sulfur oxidation is an important process in the bacterial mats attached to the limestone surfaces in these caves. An additional use of the sampling device is to measure discharge from the local bedrock into the cave conduit.


Hydrogeological Characteristics of Carbonate Formations of the Cuddapah Basin, India, 2014, Farooq Ahmad Dar

Karst hydrogeology is an important field of earth sciences as the aquifers in carbonate formations represent vital resource of groundwater that feeds a large part of the world population particularly in semi-arid climates. These unique aquifers posses peculiar characteristics developed by dissolutional activities of water. Karst aquifers possess a typical hydrogeological setup from surface to subsurface. The aquifers are governed by slow groundwater flow in matrix porosity, a medium to fast flow in fractures and rapid flow in conduits and channels. This large variability in their properties makes the prediction and modeling of flow and transport very cumbersome and data demanding. The aquifers are vulnerable to contamination as the pollutants reach the aquifer very fast with little or no attenuation. The geomorphological and hydrogeological properties in these aquifers demand specific techniques for their study. The carbonate aquifers of the semi-arid Cuddapah basin were characterized based on geomorphological, hydrogeological and hydrochemical investigations. All the formations are highly karstified possessing one of the longest and deepest caves of India and few springs along with unique surface features. Karstification is still in progress but at deeper levels indicated by growing speleothems of different architectural size. Model of karstification indicates that lowering of base level of erosion resulted in the dissolution of deeper parts of the limestone as represented by paleo-phreatic conduits in the region. Moist conditions of the past were responsible for the karst development which has been minimized due to the onset of monsoon conditions. Karst has developed at various elevations representing the past base levels in the region.

The recharge processes in these aquifers are complex due to climatic and karst specificities. Point recharge is the major contributor which enters the aquifer as allogenic water. It replenishes the groundwater very rapidly. Diffuse recharge travels through soil and epikarst zone. Average annual recharge of semi-arid Narji limestone aquifer is 29% of the rainfall which occurs during 5-7 rain events in the year.

The hydrogeochemical characteristic of karst aquifers is quite varaible. A significant difference is observed in hydrochemistry. High concentrations of SO42-, Cl-, NO3- suggests the anthropogenic source particularly from agriculture. Local Meteoric Water Line of δ2H and δ18O isotopes of rain and groundwater shows a slope of 7.02. Groundwater isotope data shows more depletion in heavy isotopes -a result of high evaporation of the area. Groundwater samples show a trend with a slope of 4 and 3.1 for δ2H and δ18O respectively. Groundwater during dry months gets more fractionated due to higher temperature and little rainfall. The irrigated water becomes more enriched and then recharges the aquifer as depleted irrigation return flow. The isotopes show large variation in spring water. Few springs are diffuse or mixed type and not purely of conduit type in the area. Tracer results indicate that the tracer output at the sampling location depends on the hydrogeological setup and the nature of karstification.

The study has significantly dealt with in disclosing the typical characteristics of such aquifer systems and bringing out a reliable as well as detailed assessment of various recharges to the system. The groundwater chemistry has been elaborated to establish the nature of possible hydrochemical processes responsible for water chemistry variation in semi-arid karst aquifer. Such study has thrown light on the aquifers that are on one hand very important from social and strategic point of view and on the hand were left unattended from the detailed scientific studies.


Results 1 to 12 of 12
You probably didn't submit anything to search for