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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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That land pan is an evaporation pan used to measure evaporation from a land surface; pan is usually mounted at the land surface [16].?

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Your search for hydrothermal dolomite (Keyword) returned 9 results for the whole karstbase:
CHEMICAL-REACTION PATH MODELING OF ORE DEPOSITION IN MISSISSIPPI VALLEY-TYPE PB-ZN DEPOSITS OF THE OZARK REGION UNITED-STATES MIDCONTINENT, 1994, Plumlee G. S. , Leach D. L. , Hofstra A. H. , Landis G. P. , Rowan E. L. , Viets J. G. ,
The Ozark region of the U.S. midcontinent is host to a number of Mississippi Valley-type districts, including the world-class Viburnum Trend, Old Lead Belt, and Tri-State districts and the smaller Southeast Missouri barite, Northern Arkansas, and Central Missouri districts. There is increasing evidence that the Ozark Mississippi Valley-type districts formed locally within a large, interconnected hydrothermal system that also produced broad fringing areas of trace mineralization, extensive subtle hydrothermal alteration, broad thermal anomalies, and regional deposition of hydrothermal dolomite cement. The fluid drive was provided by gravity flow accompanying uplift of foreland thrust belts during the Late Pennsylvanian to Early Permian Ouachita orogeny. In this study, we use chemical speciation and reaction path calculations, based on quantitative chemical analyses of fluid inclusions, to constrain likely hydrothermal brine compositions and to determine which precipitation mechanisms are consistent with the hydrothermal mineral assemblages observed regionally and locally within each Mississippi Valley-type district in the Ozark region. Deposition of the regional hydrothermal dolomite cement with trace sulfides likely occurred in response to near-isothermal effervescence of CO2 from basinal brines as they migrated to shallower crustal levels and lower confining pressures. In contrast, our calculations indicate that no one depositional process can reproduce the mineral assemblages and proportions of minerals observed in each Ozark ore district; rather, individual districts require specific depositional mechanisms that reflect the local host-rock composition, structural setting, and hydrology. Both the Northern Arkansas and Tri-State districts are localized by normal faults that likely allowed brines to rise from deeper Cambrian-Ordovician dolostone aquifers into shallower carbonate sequences dominated by limestones. In the Northern Arkansas district, jasperoid preferentially replaced limestones in the mixed dolostone-limestone sedimentary packages. Modeling results indicate that the ore and alteration assemblages in the Tri-State and Northern Arkansas districts resulted from the flow of initially dolomite-saturated brines into cooler limestones. Adjacent to fluid conduits where water/rock ratios were the highest, the limestone was replaced by dolomite. As the fluids moved outward into cooler limestone, jasperoid and sulfide replaced limestone. Isothermal boiling of the ore fluids may have produced open-space filling of hydrothermal dolomite with minor sulfides in breccia and fault zones. Local mixing of the regional brine with locally derived sulfur undoubtedly played a role in the development of sulfide-rich ore runs. Sulfide ores of the Central Missouri district are largely open-space filling of sphalerite plus minor galena in dolostone karst features localized along a broad anticline. Hydrothermal solution collapse during ore deposition was a minor process, indicating dolomite was slightly undersaturated during ore deposition. No silicification and only minor hydrothermal dolomite is present in the ore deposits. The reaction path that best explains the features of the Central Missouri sulfide deposits is the near-isothermal mixing of two dolomite-saturated fluids with different H2S and metal contents. Paleokarst features may have allowed the regional brine to rise stratigraphically and mix with locally derived, H2S-rich fluids

The Padaeng Supergene Nonsulfide Zinc Deposit, Mae Sod, Thailand, 2003, Reynolds Neal A. , Chisnall Tony W. , Kaewsang Kriangsak, Keesaneyabutr Chanan, Taksavasu Taksorn,
The Padaeng deposit near Mae Sod in western Thailand was the first supergene nonsulfide zinc deposit in the world to be developed as a large modern mining operation. The mine and associated zinc smelter, operated by Padaeng Industry Public Company Ltd. since 1984, went into production with reserves of 4.59 Mt at a grade of 28.9 percent zinc with a 10 percent zinc cutoff. Current resources are 5.14 Mt at a grade of 12.0 percent zinc with a 3 percent zinc cutoff. The Padaeng deposit is hosted by a mixed carbonate-clastic sequence of Middle Jurassic age. The deposit occurs in the hanging wall of the Padaeng fault, a major northwest-trending structure that was active through Cretaceous and Tertiary tectonism and uplift. Nonsulfide zinc ore comprises dominant hemimorphite with minor smithsonite and hydrozincite. Strata-bound ore zones occur within a northwest-dipping, deeply weathered, dolomitic sandstone; steeply dipping and irregular karstic zones in underlying massive, silty dolomite are controlled by north-trending fracture zones. Sulfide zinc-lead mineralization of Mississippi Valley type occured extensively in the vicinity of the Padaeng mine, most notably the small resources at Pha De and Hua Lon. Mineral deposits are typically sphalerite rich with minor galena and pyrite, forming small-scale open-space fillings, veins, and replacements within hydrothermal dolomite. Mineralization is dominantly strata bound within a horizon of intense hydrothermal dolomitization that forms the stratigraphic hanging wall to the nonsulfide ore zones at Padaeng. The only significant sulfide at the Padaeng mine is within this unit. Only trace sulfide occurs peripheral to, or down dip of, strata-bound or steeply dipping, nonsulfide orebodies. Sulfide mineralization is believed to have accompanied Cretaceous uplift and deformation, related to the onset of oblique subduction beneath the western margin of the Shan-Thai terrane. The nonsulfide deposit is believed to have formed when a substantial body of sulfide ore was uplifted on the margin of the Mae Sod Tertiary intermontane basin, commencing in the middle to late Miocene. Zinc-bearing acidic supergene fluids, generated by oxidation of the precursor sulfide body, reacted with carbonate in the underlying stratigraphic section to precipitate hemimorphite and smithsonite. Fluids were channeled by permeable dolomitic sandstones and by steep fracture and fault zones. Acidic fluids promoted deep weathering and karst formation, allowing mineralization to extend down dip in sandstone units for at least 150 m and vertically for a similar distance in steep structural zones. Transport of zinc out of the precursor sulfide body was facilitated by a falling water table, owing to uplift of the Padaeng fault block and a change from wet tropical to monsoonal or semiarid climatic conditions. There is no evidence for significant in situ replacement of sulfide deposits, and the leached remnants of the precursor sulfide body have been removed by erosion. The supergene process of dissolution and reprecipitation of zinc in the host rocks increased zinc grades and separation of zinc from lead, producing an economically attractive deposit. Successful exploration for this type of deposit requires a good understanding of the controls on primary sulfide mineralization and a good knowledge of local neotectonism, uplift history, hydrogeology, climatic evolution, and weathering history

Discrimination of meteoric karst breccias from tectono-thermobaric breccias, 2005, Smith Langhorne B. , Palmer Arthur
Tectono-thermobaric breccias and associated hydrothermal dolomite reservoirs, such as those in the Trenton-Black River play, represent a major remaining resource in North America. Tectono-thermobaric breccias must be differentiated from paleokarst breccias for sound exploration and development decisions. Paleokarst breccias and collapsed meteoric caves are genetically related to sequence boundaries. Many have non-carbonate detrital matrix with vestiges of calcite speleothems. Perching on low-permeability strata is common. Modern meteoric caves are far more common in limestone than dolomite, typically <10 meters wide, and limited to areas of local topographic relief and discharge into a surface drainage system. Cavernous porosity is irregularly distributed and rarely more than 5% of the total rock volume. Ancient collapsed caves should show evidence for these characteristics. Tectono-thermobaric breccias form where space is created in active fault zones. Thermobaric (high-pressure, high-temperature) fluids flow up the active faults, enlarge fractures and precipitate minerals such as saddle dolomite, calcite and sulfides between clasts. Breccias follow fault trends, can be up to hundreds of meters wide, and are commonly concentrated beneath sealing shales or argillaceous limestones. These breccias can occur in limestone or dolomite but are commonly associated with hydrothermal matrix dolomitization. High permeability and porosity can be preserved between partially cemented clasts and in linked vugs, fractures and matrix. Tectono-thermobaric breccias form mainly in previously unbrecciated strata, but they may serendipitously intersect earlier meteoric karst. Tectono-thermobaric brecciated reservoirs commonly occur around wrench faults identifiable on seismic data. These reservoirs commonly do not require structural closure, so many potential targets remain undrilled. Tectono-thermobaric carbonate breccias also host many of the world's sulfide ore deposits. Many brecciated reservoirs and ore deposits that have been previously interpreted as meteoric karst may in fact be tectono-thermobaric in origin.

Structurally controlled hydrothermal dolomite reservoir facies: An overview, 2006, Davies G. R. , Smith Jr. L. B.

Structurally controlled hydrothermal dolomite (HTD) reservoir facies and associated productive leached limestones are major hydrocarbon producers in North America and are receiving increased exploration attention globally. They include multiple trends in the Ordovician (locally, Silurian and Devonian) of the Michigan, Appalachian, and other basins of eastern Canada and the United States, and in the Devonian and Mississippian of the Western Canada sedimentary basin. They also occur in Jurassic hosts along rifted Atlantic margins, in the Jurassic–Cretaceous of the Arabian Gulf region and elsewhere. Hydrothermal dolomitization is defined as dolomitization occurring under burial conditions, commonly at shallow depths, by fluids (typically very saline) with temperature and pressure (T and P) higher than the ambient T and P of the host formation. The latter commonly is limestone. Proof of a hydrothermal origin for HTD reservoir facies requires integration of burial-thermal history plots, fluidinclusion temperature data, and constraints on timing of emplacement. Hydrothermal dolomite reservoir facies are part of a spectrum of hydrothermal mineral deposits that include sedimentary-exhalative lead-zinc ore bodies and HTD-hostedMississippi Valley–type sulfide deposits. All three hydrothermal deposits show a strong structural control by extensional and/or strike-slip (wrench) faults, with fluid flowtypically focused at transtensional and dilational structural sites and in the hanging wall. Transtensional sags above negative flower structures on wrench faults are favored drilling sites for HTD reservoir facies. Saddle dolomite in both replacive and void-fillingmodes is characteristic of HTD facies. For many reservoirs, matrix-replacive dolomite and saddle dolomite appear to have formed near-contemporaneously and from the same fluid and temperature conditions. The original host facies exerts a major influence on the lateral extent of dolomitization, resultant textures, pore type, and pore volume. Breccias zebra fabrics, shear microfractures, and other rock characteristics record short-term shear stress and pore-fluid-pressure transients, particularly proximal to active faults. High-temperature hydrothermal pulses may alter kerogen in host limestones, a process designated ‘‘forced maturation.’’ basement highs, underlying sandstone (and/ or carbonate?) aquifers (probably overpressured), and overlying and internal shale seals and aquitards also may constrain or influence HTD emplacement. Although many questions and uncertainties remain, particularly in terms of Mg and brine source and mass balance, recognition and active exploration of the HTD play continues to expand. Increasing use of three-dimensional seismic imagery and seismic anomaly mapping, combined with horizontal drilling oblique to linear trends defined by structural sags, helps to reduce risk 


Origin and reservoir characteristics of Upper Ordovician TrentonBlack River hydrothermal dolomite reservoirs in New York , 2006, Smith, Jr. , L. B.

In the past decade, more than 20 new natural gas fields have been discovered in laterally discontinuous dolomites of the Upper Ordovician Black River Group in south-central New York. The dolomites form around basement-rooted wrench faults that are detectable on seismic data. Most fields occur in and around elongate faultbounded structural lows interpreted to be negative flower structures. Away from these faults, the formation is composed of impermeable limestone and forms the lateral seal for the reservoirs. In most cases, the faults die out within the overlying Trenton Limestone and Utica Shale. Most porosity occurs in saddle dolomitecoated vugs, breccias, and fractured zones. Matrix porosity is uncommon in the Black River cores described for this study. The patchy distribution around basement-rooted faults and geochemical and fluid-inclusion analyses supports a fault-related hydrothermal origin for the saddle and matrix dolomites. This play went for many years without detection because of its unconventional structural setting (i.e., structural lows versus highs). Using the appropriate integrated structural-stratigraphic-diagenetic model, more hydrothermal dolomite natural gas reservoirs are likely to be discovered in the Black River of New York and in carbonates around the world. 


Three-dimensional seismic-based definition of fault-related porosity development: TrentonBlack River interval, Saybrook, Ohio, 2006, Sagan J. A. , Hart B. S.

Oil and gas reservoirs of the Ordovician Trenton–Black River interval in the Appalachian Basin are commonly associated with fault-related hydrothermal dolomites. However, relationships between porosity development and fault geometry in these fields are poorly documented. In this article, we integrate three-dimensional (3-D) seismic and wire-line data from the Trenton–Black River interval at Saybrook field in northeastern Ohio to study relationships between faulting and porosity development there. Faults were mapped using a combination of amplitude and coherency versions of the seismic data, and a 3-D porosity volume was generated for the Trenton–Black River interval by integrating attributes derived from the seismic data with log-based measures of porosity.

The productive trend in the Trenton–Black River interval at Saybrook is controlled by a 3.4-mi (5.5-km)-long, northwest-southeast–oriented basement fault that was probably reactivated during the Taconic orogeny (i.e., Late Ordovician). Strike-slip movement along the fault generated en echelon synthetic shear faults that branch at least 1350 ft (411.5 m) upward into the Trenton–Black River interval. The best porosity is developed in areas between overlapping synthetic shear faults. Antithetic shear faults probably formed at these locations and, when combined with minor dip-slip movement, created conduits for subsequent porosity-generating fluids. Circular collapse structures associated with localized extension between overlapping shear faults are the primary drilling targets, and horizontal wells running parallel to the strike of the fault would have the best chances of intercepting good porosity development.

Justine Sagan obtained her B.Sc. and M.Sc. degrees in the Earth and Planetary Sciences Department at McGill University. The work presented in this article is based on her M.Sc. thesis. She is currently employed by Devon Canada Corporation in Calgary.

 Bruce Hart held positions with the Geological Survey of Canada, Pennsylvania State University, and the New Mexico Bureau of Mines and Mineral Resources prior to joining McGill University in 2000. His research focuses on the integration of three-dimensional seismic and other data types for reservoir characterization programs. He has been an associate editor of the AAPG


Fractured hydrothermal dolomite reservoirs in the Devonian Dundee Formation of the central Michigan Basin, 2006, Luczaj J. A. , Harrison Iii. W. B. , Williams N. S.

The Middle Devonian Dundee Formation is the most prolific oilproducing unit in the Michigan Basin, with more than 375 million bbl of oil produced to date. Reservoir types in the Dundee Formation can be fracture controlled or facies controlled, and each type may have been diagenetically modified. Although fracture-controlled reservoirs produce more oil than facies-controlled reservoirs, little is known about the process by which they were formed and diagenetically modified. In parts of the Dundee, preexisting sedimentary fabrics have been strongly overprinted by medium- to coarse-grained dolomite. Dolomitized intervals contain planar and saddle dolomite, with minor calcite, anhydrite, pyrite, and uncommon fluorite. Fluid inclusion analyses of two-phase aqueous inclusions in dolomite and calcite suggest that some water-rock interaction in these rocks occurred at temperatures as high as 120–150jC in the presence of dense Na-Ca-Mg-Cl brines. These data, in conjunction with published organic maturity data and burial reconstructions, are not easily explained by a long-term burial model and have important implications for the thermal history of the Michigan Basin. The data are best explained by a model involving short-duration transport of fluids and heat from deeper parts of the basin along major fault and fracture zones connected to structures in the Precambrian basement. These data give new insight into the hydrothermal processes responsible for the formation of these reservoirs. 


Burial dolomitization and dissolution of Upper Jurassic Abenaki platform carbonates, Deep Panuke reservoir, Nova Scotia, Canada, 2006, Wierzbicki R. , Dravis J. J. , Alaasm I. , Harland N.

A large gas reservoir was discovered in the previously unproductive Jurassic-aged Abenaki carbonate margin in 1998. Most of the reservoir porosity is developed in dolostones. These dolostones replaced preexisting wackestones, packstones, and grainstones(?) associated with reefal and adjacent depositional environments. Many dolomites were subsequently recrystallized or dissolved, accounting for much of the preserved secondary porosity. Subsequent fracturing helped enhance reservoir permeabilities. Enhanced petrographic techniques established that dissolution of previously dolomitized fabrics generated much of the secondary porosity in these dolostones. Diffused plane-polarized light revealed relict grains and textures invisible with standard microscopic observations. Petrographic and geochemical observations also confirmed that dissolution occurred under deep-burial conditions after incipient pressure solution. Dissolutionwas not confined to the centers of dolomitized grains, as is commonly seen when remnant calcitic grains dissolve out during the advanced stages of replacement dolomitization. Instead, dissolution was random within relict grains, as isolated dolomite crystals were also variably dissolved. The geochemistry of these dolomites and associated late-stage calcites implied precipitation from basinal hot fluids, as well as hydrothermal fluids. Later diagenetic fluids, either acidic or calcium rich, or perhaps both at different times (based on associated mineralization), seemingly promoted dolomite dissolution. The presence of tectonic fractures and stylolites, helium gas, and faults observed in seismic data implied that dolomitization and subsequent dissolution along the Abenaki platform margin were controlled by reactivated wrench faults tied to basement. On a finer scale, diagenetic fluids moved through fractures and pressuresolution seams. The data collected to date support our contention that the dolomitization and dissolution process, which has created most of the porosity in the Abenaki reservoir, was poststylotization and deeper burial in origin. Given the timing of tectonic activity in the area and its inferred connection to diagenesis, it is probable that at least a part of the diagenetic fluids were hydrothermal in nature 


Outcrop analog for TrentonBlack River hydrothermal dolomite reservoirs, Mohawk Valley, New York , 2006, Slater B. E. , Smith Jr. L. B.

Geochemical analysis and field relations of linear dolomite bodies occurring in outcrop in the Mohawk Valley of New York suggest that the area has undergone a significant faultrelated hydrothermal alteration. The dolomite occurs in the Lower Ordovician Tribes Hill Formation, which is regionally a Lower Ordovician shaley limestone with patchy dolomitization. The outcrop has an en echelon fault, fracture, and fold pattern. A three-dimensional (3-D) ground-penetrating radar (GPR) survey of the quarry floor has helped to map out faults, fractures, anticlines, synclines, and the extent of dolomitization. Most of the dolomitization occurs in fault-bounded synclines or sags flanked by anticlines. The dolomite structures are highly localized, occurring around faults, and are absent away from the faults and fractures. Trenches cut across the outcrop help relate offset along faults to the overall geometry of the dolomitized bodies. Geochemical analysis, although helpful in characterizing the conditions of dolomitization, does not define its origin absolutely. This study uses fluid inclusions, stable isotopes, 3-D GPR, core analysis, and surficial observations, which all show a link between faulting, dolomitization, and other hydrothermal alteration. Although the outcrop is much too small and shallow to act as a producing gas field, it serves as a scaled analog for the Trenton–Black River hydrothermal dolomite reservoirs of eastern United States. It may therefore be studied to help petroleum geologists characterize existing gas plays and prospect future areas of exploration.


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