Conduit enlargement in an eogenetic karst aquifer, , Moore Paul J. , Martin Jonathan B. , Screaton Elizabeth J. , Neuhoff Philip S.

Most concepts of conduit development have focused on telogenetic karst aquifers, where low matrix permeability focuses flow and dissolution along joints, fractures, and bedding planes. However, conduits also exist in eogenetic karst aquifers, despite high matrix permeability which accounts for a significant component of flow. This study investigates dissolution within a 6-km long conduit system in the eogenetic Upper Floridan aquifer of north-central Florida that begins with a continuous source of allogenic recharge at the Santa Fe River Sink and discharges from a first-magnitude spring at the Santa Fe River Rise. Three sources of water to the conduit include the allogenic recharge, diffuse recharge through epikarst, and mineralized water upwelling from depth. Results of sampling and inverse modeling using PHREEQC suggest that dissolution within the conduit is episodic, occurring only during 30% of 16 sampling times between March 2003 and April 2007. During low flow conditions, carbonate saturated water flows from the matrix to the conduit, restricting contact between undersaturated allogenic water with the conduit wall. When gradients reverse during high flow conditions, undersaturated allogenic recharge enters the matrix. During these limited periods, estimates of dissolution within the conduit suggest wall retreat averages about 4 × 10−6 m/day, in agreement with upper estimates of maximum wall retreat for telogenetic karst. Because dissolution is episodic, time-averaged dissolution rates in the sink-rise system results in a wall retreat rate of about 7 × 10−7 m/day, which is at the lower end of wall retreat for telogenetic karst. Because of the high permeability matrix, conduits in eogenetic karst thus enlarge not just at the walls of fractures or pre-existing conduits such as those in telogenetic karst, but also may produce a friable halo surrounding the conduits that may be removed by additional mechanical processes. These observations stress the importance of matrix permeability in eogenetic karst and suggest new concepts may be necessary to describe how conduits develop within these porous rocks.

Speleothems and paleoglaciers, , Spotl Christoph, Mangini Augusto,

Ice and speleothems are widely regarded as mutually exclusive as the presence of liquid water is a fundamental prerequisite for speleothem deposition. Here we show that speleothems may form in caves overlain by a glacier, as long as the temperature in the cave is above freezing and the conduits are not completely flooded by melt water. Carbonate dissolution is accomplished via sulfide oxidation and the resultant speleothems show high [delta]13C values approaching and locally exceeding those of the parent host rock (lack of soil-derived biogenic C). The [delta]18O values reflect the isotopic composition of the melt water percolating into the karst fissure network and carry an atmospheric (temperature) signal, which is distinctly lower than those of speleothems formed during periods when soil and vegetation were present above the cave. These `subglacial' speleothems provide a means of identifying and dating the former presence of warm-based paleoglaciers and allow us to place some constraints on paleotemperature changes

The Aggitis karst system, Eastern Macedonia, Greece: Hydrologic functioning and development of the karst structure, , Novel Jean Paul, Dimadi Agoro, Zervopoulou Anna, Bakalowicz Michel,

SummaryThe Aggitis karst system developed in the marbles of the Rhodope massif. The conditions of the development of its karst drainage network are determined from the geological and geomorphologic settings by means of a microstructural analysis, following Eraso's method. This analysis shows that the karst conduit network intensely developed in the western part of the mountain Falakro where the majority of the open fractures oriented in the same direction as the hydraulic gradient, while the two directions are perpendicular in its eastern part drained by the spring of Drama.The behaviour of the system was analysed by means of hydrodynamic and water geochemical techniques. Despite the extension of the cave system and of the favourable development conditions of conduits, the functioning appears complex, with a significant storage, and a slow infiltration as well as an easy drainage. On the contrary the Drama karst system, characterised by a low variability in its hydrological and geochemical characteristics does not show any karst functioning.In the Aggitis karst system the initial groundwater flow conditions in combination with the aperture planes of which the directions are in agreement with the hydraulic gradient, favoured the rapid development of a drainage network system. The recharge from a large surface catchment area on non-karstic rocks, through swallow holes in a wide polje contributed to increase the groundwater flow through the karst part of the system, facilitating the development of the conduits

Transport and variability of fecal bacteria in carbonate conglomerate aquifers, , Goeppert N. , Goldscheider N.

Clastic sedimentary rocks are generally considered non-karstifiable and thus less vulnerable to pathogen contamination than karst aquifers. However, dissolution phenomena have been observed in clastic carbonate conglomerates of the Subalpine Molasse zone of the northern Alps and other regions of Europe, indicating karstification and high vulnerability, which is currently not considered for source protection zoning. Therefore, a research program was established at the Hochgrat site (Austria/Germany), as a demonstration that karst-like characteristics, flow behavior and high vulnerability to microbial contamination are possible in this type of aquifer. The study included geomorphologic mapping, comparative multi-tracer tests with fluorescent dyes and bacteria-sized fluorescent microspheres, and analyses of fecal indicator bacteria (FIB) in spring waters during different seasons. Results demonstrate that (i) flow velocities in carbonate conglomerates are similar as in typical karst aquifers, often exceeding 100 m/h; (ii) microbial contaminants are rapidly transported towards springs; and (iii) the magnitude and seasonal pattern of FIB variability depends on the land use in the spring catchment and its altitude. Different ground water protection strategies than currently applied are consequently required in regions formed by karstified carbonatic clastic rocks, taking into account their high degree of heterogeneity and vulnerability.

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GHOST-ROCK KARSTIFICATION IN �ENTRE-DEUX-MERS� (GIRONDE, FRANCE), IMPLICATIONS FOR KARSTOGENESIS AND KARSTIC MORPHOLOGY, , Dubois Caroline, Lans Benjamin, Kaufmann Olivier, Maire Richard, Quinif Yves

The formation of the Oligocene « calcaires à Astéries » in the region of « Entre-deux-Mers » is affected by a karstification with subhorizontal caves that drained rivers from swallow-holes to resurgences. Observations in quarries show that ghost-rock alterites are present. This paper describes the ghost-rocks in the quarry of Piquepoche exploiting the Frontenac stone. We have studied horizontally developed ghost-rocks with vertical extensions still containing the residual alterite. They can be badly consolidated calcarenites up to soft material which has been sampled. Speleogenesis is reviewed in the frame of the mechanical erosion of the alterite of a horizontal ghost-rock followed by an incision by free-flowing waters which form a passage with promontories and potholes. Finally, we show that ceiling anastomoses can form by ghost-rock karstification.

A New Equation Solver for Modeling Turbulent Flow in Coupled Matrix‐Conduit Flow Models, ,

Karst aquifers represent dual flow systems consisting of a highly conductive conduit system embedded in a less permeable rock matrix. Hybrid models iteratively coupling both flow systems generally consume much time, especially because of the nonlinearity of turbulent conduit flow. To reduce calculation times compared to those of existing approaches, a new iterative equation solver for the conduit system is developed based on an approximated Newton–Raphson expression and a Gauß–Seidel or successive over-relaxation scheme with a single iteration step at the innermost level. It is implemented and tested in the research code CAVE but should be easily adaptable to similar models such as the Conduit Flow Process for MODFLOW-2005. It substantially reduces the computational effort as demonstrated by steady-state benchmark scenarios as well as by transient karst genesis simulations. Water balance errors are found to be acceptable in most of the test cases. However, the performance and accuracy may deteriorate under unfavorable conditions such as sudden, strong changes of the flow field at some stages of the karst genesis simulations.

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Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, , Bontognali Tomaso R. R. , D’angeli Ilenia M. , Tisato Nicola, Vasconcelos Crisogono, Bernasconi Stefano M. , Gonzales Esteban R. G. , De Waele Jo

Unusual speleothems resembling giant mushrooms occur in Cueva Grande de Santa
Catalina, Cuba. Although these mineral buildups are considered a natural heritage, their
composition and formation mechanism remain poorly understood. Here we characterize
their morphology and mineralogy and present a model for their genesis. We propose that
the mushrooms, which are mainly comprised of calcite and aragonite, formed during four
different phases within an evolving cave environment. The stipe of the mushroom is an
assemblage of three well-known speleothems: a stalagmite surrounded by calcite rafts
that were subsequently encrusted by cave clouds (mammillaries). More peculiar is the
cap of the mushroom, which is morphologically similar to cerebroid stromatolites and
thrombolites of microbial origin occurring in marine environments. Scanning electron
microscopy (SEM) investigations of this last unit revealed the presence of fossilized
extracellular polymeric substances (EPS)—the constituents of biofilms and microbial
mats. These organic microstructures are mineralized with Ca-carbonate, suggesting that
the mushroom cap formed through a microbially-influenced mineralization process. The
existence of cerebroid Ca-carbonate buildups forming in dark caves (i.e., in the absence
of phototrophs) has interesting implications for the study of fossil microbialites preserved
in ancient rocks, which are today considered as one of the earliest evidence for life on
Earth.

On the Geology of the Western States of North America, 0000, Owen David Dale,

The remarks here submitted will be confined chiefly to that part of the Western States of North America watered by the rivers Ohio, Wabash, Illinois, Rock, Wisconsin, Cumberland and Tennessee, lying between the 35th and 43rd degree of N. latitude and the 81st and 91st of W. longitude. The district includes the states of Illinois, Indiana, Ohio, Kentucky, Tennessee, and the Du Buque and Mineral Point districts of Iowa and Wisconsin. This territory occupies an area of about half a million of square miles, but its geological features are remarkably uniform, belonging, with a few partial exceptions, to the periods of the bituminous coal and carboniferous limestone as found in Europe, and the Silurian rocks as described by Sir R. Murchison; the exceptions are the superficial deposits which occasionally cover up these from view over considerable tracts, and these must either be referred to the age of gigantic mammalia and formations of a much newer date, or belong to a marl and greensand found in the western district of Tennessee, probably a portion of the greensand and other members of the cretaceous group. A general idea of the geological formations of the whole tract may be obtained from the annexed diagram. ... This 250-word extract was created in the absence of an abstract

Agressive action of water on carbonate rocks, gypsum and concrete, 1939, Laptev F. F.

Caves as Rockshelters in Southwestern Asia, 1951, Field, Henry

Cave in Rock, 1951, Jackson, George F.

A Rock Fall in Swildons Hole [Somerset], 1960, Crabtree P. W.

A Fall of Rock in Eastwater Cavern, Mendip, 1960, Lloyd O. C.

Bermuda--A partially drowned, late mature, Pleistocene karst, 1960, Bretz Jh,

During Pleistocene time, the Bermuda Islands repeatedly underwent partial inundation and re-emergence. The land areas were continuously attacked and reduced by rain and ground water but repeatedly renewed, during times of submergence, by deposition of marine limestone and by contemporaneous additions of shore-born and wind-transported carbonate sand, now eolianite. Soils formed under subaerial conditions are now buried beneath later deposits and constitute important stratigraphic markers. The igneous foundation rock appears to have been exposed during some low marine stands, and the former shorelines seem to be recorded by submerged terraces. The major karst features are largely below sea level, and they must date from times of continental glaciations. Previous writers have assigned eolian accumulation to times of Pleistocene low sea level and soil-making to times of interglacial high sea. Both conclusions are held to be erroneous

Basic concepts in the theory of homogeneous liquids in fractured rocks,, 1960, Barenblatt, G. E. , I. P. Zheltov, And I. N. Kochina