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Enviroscan Ukrainian Institute of Speleology and Karstology

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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That covered karren is any karren that is covered by soil. draining water is oversaturated with respect to co2 so that corrosion is extensive [3]. see also wave karren; root karren; cavernous karren.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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Browse Speleogenesis Issues:

KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for organic-carbon (Keyword) returned 23 results for the whole karstbase:
Showing 16 to 23 of 23
C and O stable isotope variability in recent freshwater carbonates (River Krka, Croatia), 2004, Lojen S. , Dolenec T. , Vokal B. , Cukrov N. , Mihelcic G. , Papesch W. ,
Three types of recent carbonate precipitates from the River Krka, Croatia, were analysed: (1) bulk tufa from four main cascades in a 34 km long section of the river flow through the Krka National Park; (2) a laminar stromatolite-like incrustation formed in the tunnel of a hydroelectric power plant close to the lowest cascade; and (3) recent precipitates collected on artificial substrates during winter, spring and summer periods. Stable isotope compositions of carbon (delta(13)C) and oxygen (delta(18)O) in the carbonate and organic carbon (delta(13)C(org)) were determined and compared with delta(18)O of water and delta(13)C of dissolved inorganic carbon (DIC). The source of DIC, which provides C for tufa precipitation, was determined from the slope of the line ([DIC]/[DIC0]-1) vs. (delta(13)C-DIC x ([DIC]/[DIC0])) (Sayles & Curry, 1988). The delta(13)C value of added DIC was -13.6parts per thousand, corresponding to the dissolution of CO2 with delta(13)C between -19.5 and -23.0parts per thousand Vienna Pee Dee Belemnite (VPDB). The observed difference between the measured and calculated equilibrium temperature of precipitation of bulk tufa barriers indicates that the higher the water temperature, the larger the error in the estimated temperature of precipitation. This implies that the climatic signals may be valid only in tufas precipitated at lower and relatively stable temperatures. The laminar crust comprising a continuous record of the last 40 years of precipitation shows a consistent trend of increasing delta(13)C and decreasing delta(18)O. The lack of covariation between delta(13)C and delta(18)O indicates that precipitation of calcite was not kinetically controlled for either of the elements. delta(13)C and delta(18)O of precipitates collected on different artificial substrates show that surface characteristics both of substrates and colonizing biota play an important role in C and O isotope fractionation during carbonate precipitation

REE3 and Mn2 activated cathodoluminescence in lateglacial and Holocene stalagmites of central Europe: evidence for climatic processes?, 2004, Richter Detlev K. , Gotte Thomas, Niggemann Stefan, Wurth Georg,
Combined visual cathodoluminescence (CL) and spectral analyses of CL reveals periodic enrichments of rare earth elements (REE3) and manganese (Mn2) within the laminations of eight calcitic lateglacial to postglacial stalagmites. In the annual layers, the enrichment of trace elements can be correlated with the autumn/winter laminae, which are strongly pigmented and rich in organic carbon. During the Holocene, they occur especially in the Atlantic stage and in subrecent/recent times. The enrichment of REE3 and Mn reflects times of more intense weathering, which presumably prevailed during the Atlantic warm and humid climate. In subrecent/recent times, especially the last 100 years, these enrichments may have been at least partially anthropogenically induced

The Geomicrobiology of Ore Deposits, 2005, Southam G. , Saunders James A. ,
Bacterial metabolism, involving redox reactions with carbon, sulfur, and metals, appears to have been important since the dawn of life on Earth. In the Archean, anaerobic bacteria thrived before the Proterozoic oxidation of the atmosphere and the oceans, and these organisms continue to prosper in niches removed from molecular oxygen. Both aerobes and anaerobes have profound effects on the geochemistry of dissolved metals and metal-bearing minerals. Aerobes can oxidize dissolved metals and reduced sulfur, as well as sulfur and metals in sulfide minerals can contribute to the supergene enrichment of sulfide ores, and can catalyze the formation of acid mine drainage. Heterotrophic anaerobes, which require organic carbon for their metabolism, catalyze a number of thermodynamically favorable reactions such as Fe-Mn oxyhydroxide reductive dissolution (and the release of sorbed metals to solution) and sulfate reduction. Bacterial sulfate reduction to H2S can be very rapid if reactive organic carbon is present and can lead to precipitation of metal sulfides and perhaps increase the solubility of elements such as silver, gold, and arsenic that form stable Me-H2S aqueous complexes. Similarly, the bacterial degradation of complex organic compounds such as cellulose and hemicellulose to simpler molecules, such as acetate, oxalate, and citrate, can enhance metal solubility by forming Me organic complexes and cause dissolution of silicate minerals. Bacterially induced mineralization is being used for the bioremediation of metal-contaminated environments. Through similar processes, bacteria may have been important contributors in some sedimentary ore-forming environments and could be important along the low-temperature edges of high-temperature systems such as those that form volcanogenic massive sulfides

Spatial heterogeneity of the soil cover in the Yucatan karst: Comparison of Mayan, WRB, and numerical classifications, 2005, Bautista F, Azgarrido S, Castillogonzalez M, Zinck Ja,
In karstic areas, geopedologic information integrating soil and relief features, especially concerning short-distance variability, is usually scarce. The aim of this paper was to compare soil classes in the Yucatan karst using the Mayan soil nomenclature, the World Reference Base for Soil Resources (WRB), numerical soil classification (NSC), and geostatistics. The landscape is a flat-to-slightly-undulating karstic plain. Soil properties were determined at 54 sampling points on a regular grid covering an area of 1350 m(2). Six indigenous soil classes were identified on the basis of the terrain position, topsoil color, stoniness, rockiness. rock type. and soil depth. Five WRB soil units were recognized belonging mainly to Leptosols. Furthermore, six NSC groups were determined mainly on the basis of organic matter and stoniness. Soil organic material and texture explained 57% of the variation of the soil cover. An isotropic model of organic carbon shows a range of 39 m

Influence of hydrological and climatic parameters on spatial-temporal variability of fluorescence intensity and DOC of karst percolation waters in the Santana Cave System, Southeastern Brazil, 2005, Cruz J, Karmann I, Magdaleno Gb, Coichev N, Viana J,
Fluorescence intensity (FI) and organic carbon concentration of groundwater percolating through soil and rock into the Santana Cave were monitored at eight different cave sites between 2000 and 2002 to investigate their relationships to climatic parameters, stalactite discharge and thickness of rock overlying the cave. FI values, compared among sampling sites, are inversely proportional to depth and directly proportional to discharge; in contrast, dissolved organic matter (DOC) shows no significant spatial variability. Time-series analysis demonstrated similarities in DOC trends of different waters, but no correlation was observed with FI trends. Combined evaluation of DOC of infiltration waters, rainfall data and chemical parameters of Fe, O2, pH, Eh in soil solution indicate that peaks in DOC content coincide with more reduced conditions in the soil and have a lag time of 2-3 months after heavy showers. Variation of FI throughout the year occurs at all sampling sites but only higher drip discharge and rimstone pool waters were correlatable to rainfall events. FI of lower discharge sampling sites shows similar trends, but no relationship between drip discharge and rainfall variation was observed. Ranges and means of FI for all drip waters were significantly higher in the 2001-2002 period than in the preceding 2000-2001 period, which correlates with a 5.5 [deg]C increase in mean austral winter temperatures in 2001. Hence, FI variations of karst waters that form carbonate speleothems under a humid subtropical climate may provide a useful proxy in paleoenvironmental reconstruction

Methane discharge into the Black Sea and the global ocean via fluid flow through submarine mud volcanoes, 2006, Wallmann Klaus, Drews Manuela, Aloisi Giovanni, Bohrmann Gerhard,
During the MARGASCH cruise M52/1 in 2001 with RV Meteor we sampled surface sediments from three stations in the crater of the Dvurechenskii mud volcano (DMV, located in the Sorokin Trough of the Black Sea) and one reference station situated 15[no-break space]km to the northeast of the DMV. We analysed the pore water for sulphide, methane, alkalinity, sulphate, and chloride concentrations and determined the concentrations of particulate organic carbon, carbonate and sulphur in surface sediments. Rates of anaerobic oxidation of methane (AOM) were determined using a radiotracer (14CH4) incubation method. Numerical transport-reaction models were applied to derive the velocity of upward fluid flow through the quiescently dewatering DMV, to calculate rates of AOM in surface sediments, and to determine methane fluxes into the overlying water column. According to the model, AOM consumes 79% of the average methane flux from depth (8.9 [middle dot] 10 6[no-break space]mol a- 1), such that the resulting dissolved methane emission from the volcano into the overlying bottom water can be determined as 1.9 [middle dot] 10 6[no-break space]mol a- 1. If it is assumed that all submarine mud volcanoes (SMVs) in the Black Sea are at an activity level like the DMV, the resulting seepage represents less than 0.1% of the total methane flux into this anoxic marginal sea. The new data from the DMV and previously published studies indicate that an average SMV emits about 2.0 [middle dot] 10 6[no-break space]mol a- 1 into the ocean via quiescent dewatering. The global flux of dissolved methane from SMVs into the ocean is estimated to fall into the order of 10 10[no-break space]mol a- 1. Additional methane fluxes arise during periods of active mud expulsion and gas bubbling occurring episodically at the DMV and other SMVs

Hydrocarbon Biomarkers in the Topla-Mezica Zinc-Lead Deposits, Northern Karavanke/Drau Range, Slovenia: Paleoenvironment at the Site of Ore Formation, 2006, Spangenberg Jorge E. , Herlec Ursos,
The Mississippi Valley-type zinc and lead deposits at Topla (250,150 metric tons (t) of ore grading 10 wt % Zn and 3.3 wt % Pb) and Me[z]ica (19 million metric tons (Mt) of ore grading 5.3 wt % Pb and 2.7 wt % Zn) occur within the Middle to Upper Triassic platform carbonate rocks of the northern Karavanke/Drau Range geotectonic units of the Eastern Alps, Slovenia. The ore and host rocks of these deposits have been investigated by a combination of inorganic and organic geochemical methods to determine major, trace, and rare earth element (REE) concentrations, hydrocarbon distribution, and stable isotope ratios of carbonates, kerogen, extractable organic matter, and individual hydrocarbons. These data combined with sedimentological evidence provide insight into the paleoenvironmental conditions at the site of ore formation. The carbonate isotope composition, the REE patterns, and the distribution of hydrocarbon biomarkers (normal alkanes and steranes) suggest a marine depositional environment. At Topla, a relatively high concentration of redox sensitive trace elements (V, Mo, U) in the host dolostones and REE patterns parallel to that of the North American shale composite suggest that sediments were deposited in a reducing environment. Anoxic conditions enhanced the preservation of organic matter and resulted in relatively higher total organic carbon contents (up to 0.4 wt %). The isotopic composition of the kerogen ({delta}13Ckerogen = -29.4 to -25.0{per thousand}, {delta}15Nkerogen = -13.6 to 6.8{per thousand}) suggests that marine algae and/or bacteria were the main source of organic carbon with a very minor contribution from detrital continental plants and a varying degree of alteration. Extractable organic matter from Topla ore is generally depleted in 13C compared to the associated kerogen, which is consistent with an indigenous source of the bitumens. The mineralization correlates with {delta}15Nkerogen values around 0 per mil, 13C depleted kerogen, 13C enriched n-heptadecane, and relatively high concentrations of bacterial hydrocarbon biomarkers, indicating a high cyanobacterial biomass at the site of ore formation. Abundant dissimilatory sulfate-reducing bacteria, feeding on the cyanobacterial remains, led to accumulation of biogenic H2S in the pore water of the sediments. This biogenic H2S was mainly incorporated into sedimentary organic matter and diagenetic pyrite. Higher bacterial activity at the ore site also is indicated by specific concentration ratios of hydrocarbons, which are roughly correlated with total Pb plus Zn contents. This correlation is consistent with mixing of hydrothermal metal-rich fluids and local bacteriogenic sulfide sulfur. The new geochemical data provide supporting evidence that Topla is a low-temperature Mississippi Valley-type deposit formed in an anoxic supratidal saline to hypersaline environment. A laminated cyanobacterial mat, with abundant sulfate-reducing bacteria was the main site of sulfate reduction

Dynamics and interaction of organic carbon, turbidity and bacteria in a karst aquifer system, 2006, Pronk Michiel, Goldscheider Nico, Zopfi Jakob,

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