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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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That antecedent-soil moisture is the degree of water saturation in the soil prior to a precipitation event [16].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for new-mexico (Keyword) returned 33 results for the whole karstbase:
Showing 16 to 30 of 33
Stratigraphy, sedimentology, and structural geology of gypsum caves in east central New Mexico, 1997, Forbes J, Nance R,
Hundreds of solution caves have developed in evaporites and carbonates of the Permian San Andres Formation where it crops out between Vaughn and Roswell, New Mexico, USA. Several of the caves are over 3.2 km (2 miles) in length, and the deepest has a vertical extent of over 120 m (400 feet). These gypsum caves afford an extraordinary opportunity to examine the evaporite rocks in which they are developed. We have examined interbedded gypsum and dolostone strata exposed in the walls of 11 of these caves, and show stratigraphic sections on two geologic cross sections. Gypsum textures exposed in the caves include massive, nodular, and laminar types. While we refer to them as ''gypsum caves,'' gypsum is not the only lithology exposed. Some cave passages and rooms are developed in thick dolostone units intercalated with or overlain by gypsum beds. Correlation of beds exposed in two or more caves has allowed us to infer the local geologic structure. The sedimentary sequence penetrated by a cave exerts a profound effect on the geometry and passage cross-section of the cave. Many cave passages have gypsum walls and a dolostone or limestone floor. Although many of the cave passages flood completely during major storm events, the stairstep profile of most of the caves is indicative of speleogenesis that has occurred predominantly within the vadose zone

Late Pleistocene microtine rodents from Snake Creek Burial Cave, White Pine County, Nevada, 1998, Bell Cj, Mead Ji,
A total of 395 microtine rodent specimens recovered from Snake Creek Burial Cave (SCBC) are referred to Microtus SP. and Lemmiscus curtatus. Radiocarbon and Uranium series dates indicate an ae for these fossils of between 9460 160) yr. B.P. and 15,1000 700 yr, B.P. The sample of lower first molars of Lemmiscus includes 4-, 5-, and B-closed triangle morphotypes. Earlier reports of the 4-closed triangle morphotype are from Irvingtonian deposits in Colorado, Nevada, and New Mexico and from early Rancholabrean deposits in Washington. The morphotype is not known in living populations of Lemmiscus. SCBC specimens constitute the youngest record of the 4-closed triangle morphotype and are the only-specimens reported item the late Rancholabrean. Thc time of disappearance of Lemmiscus with this molar morphology is unknown, but populations with this morphotype possibly became extinct at or near the end of the Pleistocene

Reef margin collapse, gully formation and filling within the Permian Capitan Reef: Carlsbad Caverns, New Mexico, USA, 1999, Harwood G. M. , Kendall A. C. ,
An area of reef margin collapse, gully formation and gully fill sedimentation has been identified and mapped within Left Hand Tunnel, Carlsbad Caverns. It demonstrates that the Capitan Reef did not, at all times, form an unbroken border to the Delaware Basin. Geopetally arranged sediments within cavities from sponge-algal framestones of the reef show that the in situ reef today has a 10 degrees basinwards structural dip. Similar dips in adjacent back-reef sediments, previously considered depositional, probably also have a structural origin. Reoriented geopetal structures have also allowed the identification of a 200-m-wide, 25-m-deep gully within the reef, which has been filled by large (some >15 m), randomly orientated and, in places, overturned blocks and boulders, surrounded by finer reef rubble, breccias and grainstones. Block supply continued throughout gully filling, implying that spalling of reef blocks was a longer term process and was not a by-product of the formation of the gully. Gully initiation was probably the result of a reef front collapse, with a continued instability of the gully bordering reef facies demonstrated by their incipient brecciation and by faults containing synsedimentary fills. Gully filling probably occurred during reef growth, and younger reef has prograded over the gully fill. Blocks contain truncated former aragonite botryoidal cements, indicating early aragonite growth within the in situ reef. In contrast, former high-magnesian calcite rind cements post-date sedimentation within the gully. The morphology of cavern passages is controlled by reef facies variation, with narrower passages cut into the in situ reef and wider passages within the gully fill. Gully fills may also constitute more permeable zones in the subsurface

Sources et hydrosystmes karstiques des rgions arides et semi-arides, essai gographique, 2000, Nicod, Jean
SPRINGS AND KARSTIC HYDROSYSTEMS IN THE ARID AND SEMI-ARID AREAS. A GEOGRAPHICAL ESSAY - The patterns of the main springs and hydrosystems in the deserts and surroundings are sorted, according to their geomorphological situation (piedmont, coastal or inner plateau), to structure of the aquifers and working of groundwater (storage capacity, artesian systems) and to the hydrochemical criteria particularly the solute load in Mg2+, SO42- and Cl-. From the best known examples, the main problems on the genesis and working of the karstic hydro-systems in arid environment are discussed: - the incidence of tectonic stress and paleokarstic and paleoclimatic inheritances; - the recent periods of recharge (in Northern Sahara and Near and Middle East); - the interactions in ionic solutions and hyper-karstic processes: particular_ly with the strong acid, H2SO4, the "double solvency effect", and the mixing water corrosion near the salt water wedge in the coastal karsts.

Lechuguilla Cave is a hypogene cave formed by oxidation of ascending hydrogen sulfide from the Delaware Basin. A unique sediment deposit with characteristics suggesting derivation from the land surface, some 285 m above, was investigated. At this location, the observed stratigraphy (oldest to youngest) was: bedrock floor (limestone), cave clouds (secondary calcite), calcite-cemented silstone, finely laminated clay, and calcite rafts. Grain-size analysis indicates that the laminated clay deposits are composed of 59-82% clay-size minerals. The major minerals of the clay were determined by X-ray diffraction analysis and consist of interstratified illite-smectite, kaolinite, illite, goethite, and quartz. Scanning electron microscopy observations show that most of the clay deposit is composed of densely packed irregular-shaped clay-size flakes. One sample from the top of the deposit was detrital, containing well-rounded, silt-size particles. Surface soils are probably the source of the clay minerals. The small amount of sand- and silt-size particles suggests that detrital particles were transported in suspension. The lack of endellite and alunite is evidence that the clays were emplaced after the sulfuric-acid dissolution stage of cave formation. Fossil evidence also suggests a previously existing link to the surface

Trioctahedral smectite is a constituent of Mg-rich carbonate crusts and moonmilks (pasty deposits) in caves of the Guadalupe Mountains of southeastern New Mexico. Energy dispersive X-ray microanalysis of individual crystallites and their aggregates along with the X-ray diffraction analysis indicates that the smectite is probably stevensite. Saponite is likely present in some samples also. The smectite is intimately associated with dolomite crusts and huntite moonmilks in Carlsbad Cavern, Lechuguilla Cave, and other dolostone caves. Clay particles appear as fibers and films, with aggregates comprising decimicron-sized filamentous masses that envelop crystals of dolomite, huntite, and magnesite. The occurrence of smectite is related to the genesis of the Mg-rich carbonate minerals. In water films, progressive evaporation and carbon dioxide loss results in the sequential precipitation of Mg-rich calcite, aragonite, dolomite, huntite, and magnesite. This sequence of carbonate precipitation removes Ca and greatly increases the Mg/Ca ratio in the solutions. Silica is commonly available probably because of high pH conditions, and consequently, smectite forms in the Mg-rich alkaline environment. Along with the Mg-rich carbonate minerals, opal, quartz, and uranyl vanadates may precipitate with the smectite

The Salt That Wasn't There: Mudflat Facies Equivalents to Halite of the Permian Rustler Formation, Southeastern New Mexico, 2000, Powers Dennis W. , Holt Robert M. ,
Four halite beds of the Permian Rustler Formation in southeastern New Mexico thin dramatically over short lateral distances to correlative clastic (mudstone) beds. The mudstones have long been considered residues after post-burial dissolution (subrosion) of halite, assumed to have been deposited continuously across the area. Hydraulic properties of the Culebra Dolomite Member have often been related to Rustler subrosion. In cores and three shafts at the Waste Isolation Pilot Plant (WIPP), however, these mudstones display flat bedding, graded bedding, cross-bedding, erosional contacts, and channels filled with intraformational conglomerates. Cutans indicate early stages of soil development during subaerial exposure. Smeared intraclasts developed locally as halite was removed syndepositionally during subaerial exposure. We interpret these beds as facies formed in salt-pan or hypersaline-lagoon, transitional, and mudflat environments. Halite is distributed approximately as it was deposited. Breccia in limited areas along one halite margin indicates post-burial dissolution, and these breccias are key to identifying areas of subrosion. A depositional model accounts for observed sedimentary features of Rustler mudstones. Marked facies and thickness changes are consistent with influence by subsidence boundaries, as found in some modern continental evaporites. A subrosion model accounts for limited brecciated zones along (depositional) halite margins, but bedding observed in the mudstones would not survive 90% reduction in rock volume. Depositional margins for these halite beds will be useful in reconstructing detailed subsidence history of the Late Permian in the northern Delaware Basin. It also no longer is tenable to attribute large variations in Culebra transmissivity to Rustler subrosion

Wetter and cooler late Holocene climate in the southwestern United States from mites preserved in stalagmites, 2001, Polyak Victor J. , Cokendolpher James C. , Norton Roy A. , Asmerom Yemane,
The presence of at least 12 species of well-preserved mites in two late Holocene stalagmites from Hidden Cave, Guadalupe Mountains, New Mexico, depicts changing climate over the past 3200 yr. Growth of both stalagmites, determined by uranium-series dating, occurred from at least 3171 {} 48 yr ago and ceased by 819 {} 82 yr ago. Some of the 12 subfossil genera and species in the stalagmites are like those currently found in wetter and cooler climates, northern-like, and distinctly different from those known in the cave (n = 16) and on the surface immediately around the cave (n = 32). The mismatch of genera and species in the stalagmites, cave, and surface near the cave argues for a wetter and cooler late Holocene climate in the southwestern United States from ca. 3200 to 800 yr ago

Geomicrobiology of caves: A review, 2001, Northup D. E. , Lavoie K. H. ,
In this article, we provide a review of geomicrobiological interactions in caves, which are nutrient-limited environments containing a variety of redox interfaces. Interactions of cave microorganisms and mineral environments lead to the dissolution of, or precipitation on, host rock and speleothems (secondary mineral formations). Metabolic processes of sulfur-, iron-, and manganese-oxidizing bacteria can generate considerable acidity, dissolving cave walls and formations. Examples of possible microbially influenced corrosion include corrosion residues (e.g., Lechuguilla and Spider caves, New Mexico, USA), moonmilk from a number of caves (e.g., Spider Cave, New Mexico, and caves in the Italian Alps), and sulfuric acid speleogenesis and cave enlargement (e.g., Movile Cave, Romania, and Cueva de Villa Luz, Mexico). Precipitation processes in caves, as in surface environments, occur through active or passive processes. In caves, microbially induced mineralization is documented in the formation of carbonates, moonmilk, silicates, clays, iron and manganese oxides, sulfur, and saltpeter at scales ranging from the microscopic to landscape biokarst. Suggestions for future research are given to encourage a move from descriptive, qualitative studies to more experimental studies

Iron oxide-rich filaments: Possible fossil bacteria in Lechuguilla Cave, New Mexico, 2001, Provencio P. P. , Polyak V. J. ,
Reddish filaments in two fragments of unusual iron oxide bearing stalactites, 'the Rusticles' from Lechuguilla Cave, New Mexico, are found only within the central canals of the Rusticles. The curved, helical, and/or vibrioidal filaments vary from 1 to 6 mum in outer diameter and 10 to >50 mum in length. SEM and TEM show the filaments have 0.5-mum diameter central tubes, with goethite crystals radiating outwardly along their lengths. The diameter of the central tubes is consistent with the diameter of many iron-oxidizing filamentous bacteria. Although most iron oxide depositing bacteria do not deposit well-crystallized radiating goethite, we propose thick hydrous iron oxide was slowly crystallized from amorphous material to goethite, in place, over a relatively long period of time. From the gross morphology and the particular setting, we suggest this represents an occurrence of fossilized, acidophilic iron-oxidizing bacteria

The influence of bedrock-derived acidity in the development of surface and underground karst: Evidence from the Precambrian carbonates of semi-arid northeastern Brazil, 2003, Auler As, Smart Pl,
Very extensive cave systems are developed in Precambrian Una Group carbonates in the Campo Formoso area, eastern Brazil. In contrast, the area is largely devoid of significant surface karst landforms, as would be expected given its semi-arid climate. The caves in the area display many morphological features characteristic of deep-seated hypogenic caves, such as lack of relationship with the surface, ramiform/network pattern, abrupt variations of passage cross-sections and absence of fluvial sediments, but do not show evidence of vertical passages marking the ascending path of acidic water nor present extensive gypsum or acid clay mineral deposits. Hydrochemical analyses of present-day ground water indicate that oxidation of bedrock sulphide is an active process, and sulphuric acid may be the main agent driving carbonate dissolution in the area. A shallow mode of speleogenesis is thus proposed, in which sulphuric acid produced through the oxidation of sulphide beds within the carbonates controls cave initiation and development. Moreover, the geological situation of the area in an ancient stable passive margin precludes the possibility of deep-seated sources of acidity. Under dry climate, due to the absence of recharge, solutional landforms will be largely subdued in the surface. Hypogenic processes, if present, are likely to predominate, producing a landscape characterized by a marked disparity in the comparative degree of development between surface and underground landforms. Rates of karst landform development have traditionally been analysed through a climatic perspective, runoff being the main controlling factor in promoting karst development. This view needs to be reassessed in the light of the growing awareness of the importance of climate-independent processes related to hypogenic sources of acidity.

Diverse microbial communities inhabiting ferromanganese deposits in Lechuguilla and Spider Caves, 2003, Northup D. E. , Barns S. M. , Yu L. E. , Spilde M. N. , Schelble R. T. , Dano K. E. , Crossey L. J. , Connolly C. A. , Boston P. J. , Natvig D. O. , Dahm C. N. ,
Lechuguilla Cave is an ancient, deep, oligotrophic subterranean environment that contains an abundance of low-density ferromanganese deposits, the origin of which is uncertain. To assess the possibility that biotic factors may be involved in the production of these deposits and to investigate the nature of the microbial community in these materials, we carried out culture-independent, small subunit ribosomal RNA (SSU rRNA) sequence-based studies from two sites and from manganese and iron enrichment cultures inoculated with ferromanganese deposits from Lechuguilla and Spider Caves. Sequence analysis showed the presence of some organisms whose closest relatives are known iron- and manganese-oxidizing/reducing bacteria, including Hyphomicrobium, Pedomicrobium, Leptospirillum, Stenotrophomonas and Pantoea. The dominant clone types in one site grouped with mesophilic Archaea in both the Crenarchaeota and Euryarchaeota. The second site was dominated almost entirely by lactobacilli. Other clone sequences were most closely related to those of nitrite-oxidizing bacteria, nitrogen-fixing bacteria, actinomycetes and beta- and gamma-Proteobacteria. Geochemical analyses showed a fourfold enrichment of oxidized iron and manganese from bedrock to darkest ferromanganese deposits. These data support our hypothesis that microorganisms may contribute to the formation of manganese and iron oxide-rich deposits and a diverse microbial community is present in these unusual secondary mineral formations

Fallen arches: Dispelling myths concerning Cambrian and Ordovician paleogeography of the Rocky Mountain region, 2003, Myrow Paul M. , Taylor John F. , Miller James F. , Ethington Raymond L. , Ripperdan Robert L. , Allen Joseph,
High-resolution sedimentologic, biostratigraphic, and stable isotope data from numerous measured sections across Colorado reveal a complex architecture for lower Paleozoic strata in the central Cordilleran region. A lack of precise age control in previous studies had resulted in misidentification and miscorrelation of units between separate ranges. Corrections of these errors made possible by our improved data set indicate the following depositional history. The quartz-rich sandstone of the Sawatch Formation was deposited during onlap of the Precambrian erosion surface in the early Late Cambrian. The overlying Dotsero Formation, a regionally extensive carbonate- and shale-rich succession records blanket-like deposition with only minor facies changes across the state. An extremely widespread, meter-scale stromatolite bed, the Clinetop Bed, caps the Dotsero Formation in most areas. However, a latest Cambrian erosional episode removed 9-11 m of the upper Dotsero Formation, including the Clinetop Bed, from just east of the Homestake shear zone in the Sawatch Range eastward to the Mosquito Range. The overlying Manitou Formation differs in character, and thus in member stratigraphy, on the east vs. west sides of the state. These differences were previously interpreted as the result of deposition on either side of a basement high that existed within the Central Colorado Embayment or Colorado 'Sag,' a region of major breaching across the Transcontinental Arch. This paleogeographic reconstruction is shown herein to be an artifact of miscorrelation. Biostratigraphic data show that the northwestern members of the Manitou Formation are older than the members exposed in the southeastern part of the state and that there is little or no overlap in age between the two areas. This circumstance is the result of (1) removal of older Manitou Formation strata in the southeast by an unconformity developed during the Rossodus manitouensis conodont Zone, and (2) erosion of younger Manitou strata in central and western Colorado along Middle Ordovician and Devonian unconformities. Deciphering these complex stratal geometries has led to invalidation of long-held views on western Laurentian paleogeography during the Cambrian and earliest Ordovician, specifically the existence of the Colorado Sag and a northeast-trending high within the sag that controlled depositional patterns on either side. The mid- Rossodus uplift and resultant unconformity eliminated any and all Upper Cambrian and Lower Ordovician deposits in southern Colorado and northern New Mexico, and thus their absence should not be misconstrued as evidence for earlier nondeposition in this region. Lithofacies distribution patterns and isopach maps provide no evidence that highlands of the Transcontinental Arch existed in Colorado prior to the mid-Rossodus age uplift event. In fact, regional reconstructions of earliest Paleozoic paleogeography along the entire length of the purported Transcontinental Arch should be reevaluated with similarly precise biostratigraphic data to reconsider all potential causes for missing strata and to eliminate topographic elements not supported by multiple stratigraphic techniques. This study illustrates how seriously paleogeographic reconstructions can be biased by the presumption that missing strata represent periods of nondeposition rather than subsequent episodes of erosion, particularly in thin cratonic successions where stratigraphic gaps are common and often inconspicuous

'Sour gas' hydrothermal jarosite: ancient to modem acid-sulfate mineralization in the southern Rio Grande Rift, 2005, Lueth V. W. , Rye R. O. , Peters L. ,
As many as 29 mining districts along the Rio Grande Rift in southern New Mexico contain Rio Grande Rift-type (RGR) deposits consisting of fluorite-barite sulfide-jarosite, and additional RGR deposits occur to the south in the Basin and Range province near Chihuahua, Mexico. Jarosite occurs in many of these deposits as a late-stage hydrothermal mineral coprecipitated with fluorite, or in veinlets that crosscut barite. In these deposits, many of which are limestone-hosted, jarosite is followed by natrojarosite and is nested within silicified or argillized wallrock and a sequence of fluorite-barite sulfide and late hematite-gypsum. These deposits range in age from similar to 10 to 0.4 Ma on the basis of Ar-40/Ar-39 dating of jarosite. There is a crude north-south distribution of ages, with older deposits concentrated toward the south. Recent deposits also occur in the south, but are confined to the central axis of the rift and are associated with modem geothermal systems. The duration of hydrothermal jarosite mineralization in one of the deposits was approximately 1.0 my. Most Delta(18)O(SO4)-OH values indicate that jarosite precipitated between 80 and 240 degrees C, which is consistent with the range of filling temperatures of fluid inclusions in late fluorite throughout the rift, and in jarosite (180 degrees C) from Pena Blanca, Chihuahua, Mexico. These temperatures, along with mineral occurrence, require that the jarosite have had a hydrothermal origin in a shallow steam-heated environment wherein the low pH necessary for the precipitation of jarosite was achieved by the oxidation of H2S derived from deeper hydrothermal fluids. The jarosite also has high trace-element contents (notably As and F), and the jarosite parental fluids have calculated isotopic signatures similar to those of modem geothermal waters along the southern rift; isotopic values range from those typical of meteoric water to those of deep brine that has been shown to form from the dissolution of Permian evaporite by deeply circulating meteoric water. Jarosite delta(34)S values range from -24 parts per thousand to 5 parts per thousand, overlapping the values for barite and gypsum at the high end of the range and for sulfides at the low end. Most delta(34)S values for barite are 10.6 parts per thousand to 13.1 parts per thousand and many delta(34)S values for gypsum range from 13.1 parts per thousand to 13.9 parts per thousand indicating that a component of aqueous sulfate was derived from Permian evaporites (delta(34)S = 12 2 parts per thousand). The requisite H2SO4 for jarosite formation was derived from oxidation of H2S which was likely largely sour gas derived from the thermochemical reduction of Permian sulfate. The low delta(34)S values for the precursor H2S probably resulted from exchange deeper in the basin with the more abundant Permian SO42-- at similar to 150 to 200 degrees C. Jarosite formed at shallow levels after the PH buffering capacity of the host rock (typically limestone) was neutralized by precipitation of earlier minerals. Some limestone-hosted deposits contain caves that may have been caused by the low pH of the deep basin fluids due to the addition of deep-seated HF and other magmatic gases during periods of renewed rifting. Caves in other deposits may be due to sulfuric acid speleogenesis as a result of H2S incursion into oxygenated groundwaters. The isotopic data in these 'sour gas' jarosite occurrences encode a recod of episodic tectonic or hydrologic processes that have operated in the rift over the last 10 my. (c) 2004 Elsevier B.V. All rights reserved

Geomicrobiology of cave ferromanganese deposits: A field and laboratory investigation, 2005, Spilde M. N. , Northup D. E. , Boston P. J. , Schelble R. T. , Dano K. E. , Crossey L. J. , Dahm C. N. ,
Unusual ferromanganese deposits are found in several caves in New Mexico. The deposits are enriched in iron and manganese by as much as three orders of magnitude over the bedrock, differing significantly in mineralogy and chemistry from bedrock-derived insoluble residue. The deposits contain metabolically active microbial communities. Enrichment cultures inoculated from the ferromanganese deposits produced manganese oxides that were initially amorphous but developed into crystalline minerals over an 8-month period and beyond; no such progression occurred in killed controls. Phylogenetic analyses of sequences from clone libraries constructed from culture DNA identified two genera known to oxidize manganese, but most clones represent previously unknown manganese oxidizers. We suggest that this community is breaking down the bedrock and accumulating iron and manganese oxides in an oligotrophic environment

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