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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

Speleology in Kazakhstan

Shakalov on 11 Jul, 2012
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That barrier, freshwater is barrier of freshwater injected into an aquifer to stop the inflow of seawater into a coastal aquifer [16].?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
See all featured articles
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for aragonite (Keyword) returned 95 results for the whole karstbase:
Showing 16 to 30 of 95
Clastic and Solutional Boundaries as Nucleation SUrfaces for Aragonite in Speleothems, 1984, Craig Kevin D. , Horton Paul D. , Reams Max W.

A comparative study of the dissolution kinetics of calcite and aragonite, 1986, Busenberg E. , Plummer L. N.

Aragonite in Ogof Daren Cilau [South Wales], 1988, Kendall A.

Synthetic strontianite-aragonite solid-solution minerals were dissolved in CO2-saturated nonstoichiometric solutions of Sr(HCO3)2 and Ca(HCO3)2 at 25-degrees-C. The results show that none of the dissolution reactions reach thermodynamic equilibrium. Congruent dissolution in Ca(HCO3)2 solutions either attains or closely approaches stoichiometric saturation with respect to the dissolving solid. In Sr(HCO3)2 solutions the reactions usually become incongruent, precipitating a Sr-rich phase before reaching stoichiometric saturation. Dissolution of mechanical mixtures of solids approaches stoichiometric saturation with respect to the least stable solid in the mixture. Surface uptake from subsaturated bulk solutions was observed in the initial minutes of dissolution. This surficial phase is 0-10 atomic layers thick in Sr(HCO3)2 solutions and 0-4 layers thick in Ca(HCO3)2 solutions, and subsequently dissolves and/or recrystallizes, usually within 6 min of reaction. The initial transient surface precipitation (recrystallization) process is followed by congruent dissolution of the original solid which proceeds to stoichiometric saturation, or until the precipitation of a more stable Sr-rich solid. The compositions of secondary precipitates do not correspond to thermodynamic equilibrium or stoichiometric saturation states. X-ray photoelectron spectroscopy (XPS) measurements indicate the formation of solid solutions on surfaces of aragonite and strontianite single crystals immersed in Sr(HCO3)2 and Ca(HCO3)2 solutions, respectively. In Sr(HCO3)2 solutions, the XPS signal from the outer approximately 60 angstrom on aragonite indicates a composition of 16 mol% SrCO3 after only 2 min of contact, and 14-18 mol% SrCO3 after 3 weeks of contact. The strontianite surface averages approximately 22 mol% CaCO3 after 2 min of contact with Ca(HCO3)2 solution, and is 34-39 mol% CaCO3 after 3 weeks of contact. XPS analysis suggests the surface composition is zoned with somewhat greater enrichment in the outer approximately 25 angstrom (as much as 26 mol% SrCO3 on aragonite and 44 mol% CaCO3 on strontianite). The results indicate rapid formation of a solid-solution surface phase from subsaturated aqueous solutions. The surface phase continually adjusts in composition in response to changes in composition of the bulk fluid as net dissolution proceeds. Dissolution rates of the endmembers are greatly reduced in nonstoichiometric solutions relative to dissolution rates observed in stoichiometric solutions. All solids dissolve more slowly in solutions spiked with the least soluble component ((Sr(HCO3)2) than in solutions spiked with the more soluble component (Ca(HCO3)2), an effect that becomes increasingly significant as stoichiometric saturation is approached. It is proposed that the formation of a nonstoichiometric surface reactive zone significantly decreases dissolution rates

La grotte de la Movile (Dobroudja, Roumanie) : analyses _minralogiques, 1993, Diaconu G. , Morar M.
The authors present the results of X-ray analyses which, in the Movile cave, give evidence of the presence of a mineralogical association made up of calcite, aragonite, ankerite and quartz. They also take into consideration the conditions of a specific genesis for this cave which has been particularly affected by sulphurous thermomineral waters.

Marine carbonate cements, which are superficially like travertines from meteoric caves, are coating and binding some intertidal sedimentary rock surfaces occurring in coastal Abu Dhabi, the United Arab Emirates, (UAE). Near Jebel Dhana these surficial cements can be up to 3 cm thick and envelope beach rock surfaces and fossils. They are also present both as thin coats and a fracture-fill cement in the intertidal hard grounds associated with the Khor Al Bazam algal flats. The thickness, microscopic characteristics, and morphology of the marine cement coatings from Jebel Dhana indicates incremental deposition of aragonite in conjunction with traces of sulfate minerals. Most of these cement coatings are micritic, but the layers which encrust the hard grounds from the algae flat of the Khor al Bazam have a more radial and fibrous micro-structure and are composed solely of aragonite. The stable isotopic composition of coatings from Jebel Dhana (delta(18)O = .35, delta(13)C = .00) falls within the compositional range for modem marine non skeletal aragonite and suggests that the marine travertine-like cements precipitate from the agitated slightly hypersaline Arabian Gulf sea water during repeated cycles of exposure, evaporation and immersion. Similar cement coatings and microfabrics are present in the tepee structured and brecciated sediments of the Guadalupe Mountains (Permian) and the Italian Alps (Triassic), in Holocene algal head cements from the Great Salt Lace, and in similar Tertiary algal heads in the Green River Formation of the western US. The petrographic similarity of these ancient ''flow stone'' like cements with Recent hypersaline marine cement coatings suggests that high rates of carbonate cementation and hypersaline conditions contribute to tepee formation and cavity fill

Environmental controls on the petrology of a late Holocene speleothem from Botswana with annual layers of aragonite and calcite, 1994, Railsback L. Bruce, Brook George A. , Chen Jian, Kalin Robert, Fleisher Christopher J. ,

Vadose weathering of sulfides and limestone cave development-Evidence from eastern Australia., 1996, Osborne R. A. L.

Many significant limestone caves in eastern Australia (particularly New South Wales, Tasmania) are associated with sulfide deposits and other ore bodies. These deposits have a variety of origins (hydrothermal, paleokarst, volcaniclastic). The sulfides weather on exposure to oxygen - rich vadose seepage water, lowering the water pH and releasing sulfate and magnesium which can lead to the deposition of gypsum and aragonite speleothems. Removal of weathered ores and ore - bearing paleokarst sediments in the vadose zone is, in places, an important mechanism for the formation of large caverns.

Thermodynamic equilibrium, kinetics, activation barriers, and reaction mechanisms for chemical reactions in Karst Terrains, 1997, White W. B. ,
Chemical reactions pertinent to karst systems divide broadly into (a) speciation reactions within aqueous solutions, (b) dissolution/precipitation and other acid/base reactions between aqueous solutions and solid minerals, and (c) redox reactions involving various carbon and sulfur-bearing species. As a backdrop against which other chemistry can be evaluated, selected phase diagrams and equilibrium speciation diagrams were calculated for the system Ca--Mg--O--H--C--S. The kinetics of reactions within this system span time scales from milliseconds for homogeneous reactions in solution through hundreds of hours for carbonate mineral dissolution reactions, to geologic time scales for reactions such as the aragonite/calcite inversion or the oxidation/reduction of native sulfur. In purely inorganic systems, kinetic barriers, typically on the order of tens of kJ/mole, are set by nucleation processes and by activated complex formation. Biological processes impact the purely inorganic chemistry by the following mechanisms: (a) Secretions and waste products from biological activity or consumption of CO2 by organisms changes the chemistry in the microenvironments of reaction surfaces. Oxidation potentials, pH, and ion activities may be modified, thus shifting equilibria. (b) Reaction rates may be increased due to modification of activated complexes and thus the activation barriers to reaction. (c) Organic compounds or microorganisms may act as substrates, thus lowering nucleation barriers. The preservation of microorganisms in cave deposits does not necessarily prove a cause and effect relationship

Groundwater circulation and geochemistry of a karstified bank-marginal fracture system, South Andros Island, Bahamas, 1997, Whitaker Fiona F. , Smart Peter L. ,
On the east coast of South Andros Island, Bahamas, a major bank-marginal fracture system characterised by vertically extensive cavern systems (blue holes) is developed sub-parallel to the steep-sided deep-water re-entrant of the Tongue of the Ocean. In addition to providing a discharge route for meteoric, mixed and geochemically evolved saline groundwaters, a strong local circulation occurs along the fracture system. This generates enhanced vertical mixing within voids of the fracture system, evidenced by the increasing mixing zone thickness, and the thinning and increasing salinity of brackish lens waters from north to south along the fracture system. Furthermore, tidally driven pumping of groundwaters occurs between the fracture and adjacent carbonate aquifer affecting a zone up to 200 m either side of the fracture.The resultant mixing of groundwaters of contrasting salinity and within and along the fracture system and with the surrounding aquifer waters, together with bacterial oxidation of organic matter, generates significant potential for locally enhanced diagenesis. Undersaturation with respect to calcite within the fresh (or brackish)-salt water mixing zone is observed in the fracture system and predicted in the adjacent aquifer, while mixing between the brackish fracture lens and surrounding high fresh waters causes dissolution of aragonite but not calcite. The latter gives rise to considerable secondary porosity development, because active tidal pumping ensures continued renewal of dissolutional potential. This is evidenced by calcium and strontium enrichment in the brackish lens which indicates porosity generation by aragonite dissolution at a maximum rate of 0.35% ka-1, up to twice the average estimated for the fresh water lens. In contrast saline groundwaters are depleted in calcium relative to open ocean waters suggesting the formation of calcite cements.The development of a major laterally continuous cavernous fracture zone along the margin of the carbonate platform permits enhanced groundwater flow and mixing which may result in generation of a diagenetic `halo' at a scale larger than that generally recognised around syn-sedimentary fractures in fossil carbonates. This may be characterised by increased secondary porosity where a relative fall in sea-level results in exposure and formation of a meteoric groundwater system, or cementation by `marine' calcite both below this meteoric system, and where the bank surface is flooded by seawater

Groundwater Geochemistry of Isla de Mona, Puerto Rico, 1998, Wicks C. M. , Troester Jo. W.
In this study, we explore the differences between the hydrogeochemical processes observed in a setting that is open to input from the land surface and in a setting that is closed with respect to input from the land surface. The closed setting was a water-filled passage in a cave. Samples of groundwater and of a solid that appeared to be suspended in the relatively fresh region of saline-freshwater mixing zone were collected. The solid was determined to be aragonite. Based on the analyses of the composition and saturation state of the groundwater, the mixing of fresh and saline water and precipitation of aragonite are the controlling geochemical processes in this mixing zone. We found no evidence of sulfate reduction. Thus, this mixing zone is similar to that observed in Caleta Xel Ha, Quintana Roo, also a system that is closed with respect to input from the land surface.The open setting was an unconfined aquifer underlying the coastal plain along which four hand-dug wells are located. Two wells are at the downgradient ends of inferred flowpaths and one is along a flowpath. The composition of the groundwater in the downgradient wells is sulfide-rich and brackish. In contrast, at the well located along a flow line, the groundwater is oxygenated and brackish. All groundwater is oversaturated with respect to calcite, aragonite, and dolomite. The composition is attributed to mixing of fresh and saline groundwater, CO2 outgassing, and sulfate reduction. This mixing zone is geochemically similar to that observed in blue holes and cenotes.

Blue Lagon, Afrique du Sud, une grotte remplissage palokarstique permien et concrtions daragonite, 1998, Martini J. E. J. , Moen H. F. G.
The authors de scribe a 7 km long phreatic maze they discovered and explored during the last decade of the 2Oth century in South Africa, developed in the late Archean dolostone in the Malmani Subgroup. This cave is of interest mainly for two aspects. Firstly the cave intersects paleokarst channels filled with bleached kaolinic residuals of Permian age. This paleokarst is most likely to have developed relatively shortly after the Gondwana glaciation in a cool, humid climate. Secondly the cave is remarkable by the abundance of aragonite speleothems. Particularly interesting are subaquatic aragonite formations: rafts, cones, volcanoes, sea urchins and pool floor crust. Aragonite rafts are always associated with more or less calcite, which seems to have formed first and was apparently essential in the initial formation of this speleothem. In the pool floor crust, a cyclical calcite-aragonite deposition seems to correspond to alternation of humid and dry periods, calcite representing wet years. The amplitude of this cycle is possibly in the order of a few decades. Phosphate minerals which developed on cave soil, rock and carbonate speleothems in contact with bat guano, have been identified, in particular the rare mineral collinsite

A mineralogical analysis of karst sediments and its implications to the middle-late Pleistocene climatic changes on the Tibetan Plateau, 1998, Zhang D. D. ,
The minerals in various categories of Tibetan karst sediments were divided into three groups: carbonate, iron and silicate. The carbonate minerals, including calcite, aragonite and dolomite, consist mainly of speleothem, tufa and sinter. Most of the speleothems indicates wetter and warmer periods in early and middle Pleistocene, the youngest being 194,000 years old. The second formation of carbonate mineral, tufa, implies an arid period starting 91,000 years BP. The iron minerals, goethite and hematite, are often mixed up with cave alluvial sediments that are interbedded with flowstones, and the depression sediments. They indicate strong oxidizing environments during their deposition, which is absent at present. The clay minerals, specially kaolinite, were contained in cave alluvial, flowstone and the depression sediments as well. Combined with stratigraphic study and U-series dating, the mineral analysis shows that warmer and wetter climates, which were suitable for speleothem development, probably disappeared 200 ka ago, and drier and colder climates dominated this plateau since then

The role of high-energy events (hurricanes and/or tsunamis) in the sedimentation, diagenesis and karst initiation of tropical shallow water carbonate platforms and atolls, 1998, Jan F. G. B. L. ,
Karst morphology appears early, even during carbonate sediment deposition. Examples from modern to 125-ka-old sub-, inter- and supratidal sediments are given from the Bahamas (Atlantic Ocean) and from Tuamotuan atolls (southeastern Pacific Ocean), with mineralogical and hydrological analyses. Karstification is favoured by the aragonitic composition of bioclasts coming from the shallow marine bio-factory. Lithification by aragonite cements appears as a rim around carbonate deposits and dissolution and non-cementation start at the same time on modern supratidal deposits (Andros micrite or atoll coral rudite) and provoke the formation of a central depression on small or large carbonate platforms. In fact, this early solution of the centre of platforms is closely related to the location of each of the studied examples on hurricane tracks. High-energy events, such as hurricanes and tsunamis, affect sediment transport but hurricanes also affect diagenesis as a result of the enormous volume of freshwater carried and discharged along their paths. This couple, lithification- solution, is localised at sea level and accompanies sea-level fluctuations along the eustatic curve. Because of the precise location of hurricane action all around the Earth, early karstification by aragonite solution, cementation and supratidal carbonate sediment accumulations thigh-energy trails) act together on all the platforms and atolls located inside the Tropics (23 degrees 27') between roughly 5 degrees-10 degrees and 25 degrees on both hemispheres. However, early karstification acts alone on shallow carbonate platforms including atolls along the equatorial belt between 5 degrees-10 degrees N and 5 degrees-10 degrees S. These early steps of karstification are linked to the ocean-atmosphere interface due to the bathymetrical position of shallow carbonate platforms, including atolls. They lead to complex karstified emerged platforms, called high carbonate islands, where carbonate diagenesis, together with the development of bauxite- and/or a phosphate-rich cover and phreatic lens, will occur. (C) 1998 Elsevier Science B.V. All rights reserved

Growth and demise of an Archean carbonate platform, Steep Rock Lake, Ontario, Canada, 1999, Kusky T. P. , Hudleston P. J. ,
The Steep Rock Group of northwest Ontario's Wabigoon subprovince is one of the world's thickest Archean carbonate platform successions. It was deposited unconformably over a 3001-2928 Ma gneissic terrane, and contains a remarkable group of biogenic and oolitic limestones, dolostones, micrites, and karat breccias capped by a thick paleosol developed between and over karst towers. The presence of aragonite fans, herringbone calcite, and rare gypsum molds suggests that the carbonate platform experienced at least local anaerobic and hypersaline depositional conditions. This sequence shows that a combination of chemical and biological processes was able to build a carbonate platform 500 m thick by 3 billion years ago. The carbonate platform is structurally overlain by a mixture of complexly deformed rocks of the Dismal Ashrock forming a melange with blocks of ultramafic volcaniclastic rocks, mafic volcanics, carbonate, tonalite, lenses of Fe-ore rock, and metasedimentary rocks, in a shaly, serpentinitic, and fragmental ultramafic volcaniclastic matrix. The melange shows evidence of polyphase deformation, with early high-strain fabrics formed at amphibolite facies, and later superimposed brittle fabrics related to the final emplacement of the melange over the carbonate platform. An amphibolite- through greenschist-grade shear zone marks the upper contact of the melange with overlying mafic volcanic and tuffaceous rocks of the ca. 2932 Ma Witch Bay allochthon, interpreted as a primitive island are sequence. We suggest an evolutionary model for the area that begins with rifting of an are sequence (Marmion Complex of the Wabigoon are) that initiated subsidence and sedimentation on the Steep Rock platform and its correlatives that extend for a restored strike length exceeding 1000 km. Shallow water carbonate sedimentation continued until the platform was uplifted on the flanks of a flexural bulge related to the approach of the Witch Bay allochthon, representing collision of the rifted are margin of the Wabigoon subprovince with the Witch Bay are. Melange of the Dismal Ashrock was formed as off-axis volcanic rocks were accreted to the base of the Witch Bay allochthon prior to its collision with the Steep Rock platform

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