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Enviroscan Ukrainian Institute of Speleology and Karstology

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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That capacity, carrying is the capacity of a watercourse to transport solids [16].?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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What is Karstbase?



Browse Speleogenesis Issues:

KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
See all featured articles
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
See all featured articles from other geoscience journals

Search in KarstBase

Your search for constant (Keyword) returned 155 results for the whole karstbase:
Showing 151 to 155 of 155
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Rosaleslagarde L. , Boston P. J.

Conspicuous brackish sulfidic springs have been described at the northern Sierra the Chiapas, Mexico. These springs are produced by a mixture between regional and local groundwater flow paths. The regional groundwater has an average Total Dissolved Ions of 3081 mg/L so it has a brackish composition. This brackish water is saturated with respect to calcite and dolomite but undersaturated with respect to gypsum, anhydrite and halite. The mass balance and the discharge rate are used to quantify the mass and volume of minerals that are dissolved by the brackish spring water following Appelo and Postma (1993). This quantification will allow comparing the various speleogenetic mechanisms in the area. This is considering the composition of the spring water is relatively constant over time, as it is suggested by periodic measurements at the Cueva de Villa Luz springs during the last 10 years.
Sulfur isotopes in the water are consistent with anhydrite dissolution as the main source of the sulfate to the brackish spring water. Thus, the average 6 mol/L of sulfate in the brackish springs are produced by dissolution of 6 mol of anhydrite after subtracting the sulfate that could result from evapotranspiration of rainwater. Each liter of brackish water dissolved an average of 882 mg of anhydrite, which are equivalent to dissolving 0.36 cm3 of this mineral considering a density of 2.981 g/cm3. Additionally, using the average brackish water discharge rate of 144 L/s, an average of 57 g of anhydrite are being dissolved each second per every liter of brackish water. This is a minimal value because some of the sulfate in the water is used by sulfate-reducing bacteria in the subsurface to produce the hydrogen sulfide in the spring water. The anhydrite subject to dissolution is found interbedded in the Cretaceous carbonates, either from the subsurface at 4,000 m below sea level to the carbonate outcrops.
Similarly, we can calculate the volume of halite that is being dissolved by the brackish springs, considering chloride is a conservative element and subtracting the chloride concentration from the rainwater from that of the spring water following Appelo & Postma (1993). The 22 mol/L of chloride in the brackish water can result from dissolution in the subsurface of 22 moles or 1.3 g of halite per liter of brackish water. This mass of halite dissolved is equal to 0.59 cm3 considering a density of 2.168 g/cm3. Alternatively, 118 g of halite are dissolved per second per each liter of brackish water if we use the average discharge rate of 144 L/s.
Even when the brackish springs are oversaturated with respect to calcite and dolomite, their dissolution is still possible due to the common ion-effect of calcium after anhydrite dissolution and by mixing of waters with different compositions. A range of 10 to 80 % of brackish water from the regional aquifers mixes with fresh water from the local aquifer based on their water chemistry. Additionally, sulfuric acid speleogenesis occurs due to the oxidation of hydrogen sulfide to sulfuric acid.
Finally, the increase in the chloride concentration of the fresh water springs with respect to the concentration in rainwater was used to estimate that from the 4000 mm/y of annual precipitation, only 4%, 158 to 182 mm/y, recharge the aquifers. This low percentage is slightly higher than the 3.3% recharge in marls, marly limestone, silts and clays (Sanz et al., 2011), probably because of the relatively small area of carbonate outcrops over the entire region and the lack of recharge in altitudes higher than 1500 m above sea level.
Sulfuric acid is the most obvious speleogenetic mechanism occurring in the caves of the northern Sierra de Chiapas, Mexico due to the high hydrogen sulfide concentration in the spring water. In addition, the location of the springs at a zone of regional and local discharge where waters from different composition converge and mix, and the amount of mixing calculated suggests mixing is also an important speleogenetic mechanism. However, the depth and the time constrains at which these two hypogenic mechanisms occur is still unknown. The relatively low rainwater recharge rate suggests epigenesis is limited. Most likely, the porosity created by dissolution of anhydrite and halite in the subsurface is occluded by the precipitation of calcite. Chemical modeling and petrography will help to elucidate the order of the reactions occurring in the subsurface.

The Recession of Spring Hydrographs, Focused on Karst Aquifers, 2014,
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Fiorillo, F.

This study constitutes a review of spring hydrograph recession analysis, and it is focused on karst aquifers. The different literature models have been separated into empirical and physically-based models; in the last ones, only analytical models have been considered, as they provide the discharge equation during recession. Under constant geometrical and hydraulic aquifer characteristics, it has been found that the “exponential form” appears to be the most recurrent theoretical type, at least during the long-term flow recession. During this stage, any deviation from the exponential form, may suggest hydraulic anisotropy of actual aquifers, as well as aquifer geometry has a fundamental role in controlling the shape of spring hydrographs. The hydrodynamics of karst aquifer under recession has been described, associating any segment of the hydrograph to a specific hydrologic condition of the aquifer, and also to a specific physical law which control the water flow.

The fate of CO2 derived from thermochemical sulfate reduction (TSR) and effect of TSR on carbonate porosity and permeability, Sichuan Basin, China, 2015,
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Hao Fang, Zhang Xuefeng, Wang Cunwu, Li Pingping, Guo Tonglou, Zou Huayao, Zhu Yangming, Liu Jianzhang, Cai Zhongxian

This article discusses the role ofmethane in thermochemical sulfate reduction (TSR), the fate of TSR-derived CO2 and the effect of TSR on reservoir porosity and permeability, and the causes of the anomalously high porosity and permeability in the Lower Triassic soured carbonate gas reservoirs in the northeast Sichuan Basin, southwest China. The Lower Triassic carbonate reservoirs were buried to a depth of about 7000 m and experienced maximum temperatures up to 220 °C before having been uplifted to the present-day depths of 4800 to 5500 m, but they still possess porosities up to 28.9% and permeabilities up to 3360 md. The present-day dry gas reservoirs evolved from a paleo-oil accumulation and experienced varying degrees of TSR alteration as evidenced from the abundant sulfur-rich solid bitumens and varying H2S and CO2 concentrations. TSR occurred mainly within the oil and condensate/wet gas windows, with liquid hydrocarbons and wet hydrocarbon gases acting as the dominant reducing agents responsible for sulfate reduction, sulfur-rich solid bitumen and H2S generation, and calcite precipitation. Methane-dominated TSR was a rather late event and had played a less significant role in altering the reservoirs. Intensive H2S and CO2 generation during TSR resulted in calcite cementation rather than carbonate dissolution, which implies that the amount of water generated during TSR was volumetrically insignificant. 13C-depleted CO2 derived from hydrocarbon oxidation preferentially reacted with Ca2+ to form isotopically light calcite cements, and the remaining CO2 re-equilibrated with the 13C-enriched water–rock systems with its δ13C rapidly approaching the values for the host rocks, which accounted for the observed heavy and relatively constant CO2 δ13C values. The carbonate reservoirs suffered from differential porosity loss by TSR-involved solid bitumen generation and TSR-induced calcite and pyrite precipitation. Intensive TSR significantly reduced the porosity and permeability of the intervals expected to have relatively high sulfate contents (the evaporative-platform dolostones and the platform-margin shoal dolostones immediately underlying the evaporative facies). Early oil charge and limited intensity of TSR alteration, together with very low phyllosilicate content and early dolomitization, accounted for the preservation of anomalously high porosities in the reservoirs above the paleo-oil/water contact. A closed system seems to have played a special role in preserving the high porosity in the gas zone reservoirs below the paleo-oil/water contact. The closed system, which is unfavorable for deep burial carbonate dissolution and secondary porosity generation, was favorable for the preservation of early-formed porosity in deeply buried carbonates. Especially sucrosic and vuggy dolostones have a high potential to preserve such porosity.

Chemistry and Karst, 2015,
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White, William B.

The processes of initiation and development of characteris­tic surface karst landforms and underground caves are nearly all chemical processes. This paper reviews the advances in understanding of karst chemistry over the past 60 years. The equilibrium chemistry of carbonate and sulfate dissolution and deposition is well established with accurate values for the necessary constants. The equations for bulk kinetics are known well enough for accurate modeling of speleogenetic processes but much is being learned about atomic scale mechanisms. The chemistry of karst waters, expressed as parameters such as total dissolved carbonates, saturation index, and equilibrium carbon dioxide pressure are useful tools for probing the internal char­acteristics of karst aquifers. Continuous records of chemical parameters (chemographs) taken from springs and other karst waters mapped onto discharge hydrographs reveal details of the internal flow system. The chemistry of speleothem deposi­tion is well understood at the level of bulk processes but much has been learned of the surface chemistry on an atomic scale by use of the atomic force microscope. Least well understood is the chemistry of hypogenetic karst. The main chemical reac­tions are known but equilibrium modeling could be improved and reaction kinetics are largely unknown.

Calculating flux to predict future cave radon concentrations, 2016,
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Rowberry Matt, Marti Xavi, Frontera Carlos, Van De Wiel Marco, Briestensky Milos

Cave radon concentration measurements reflect the outcome of a perpetual competition which pitches flux against ventilation and radioactive decay. The mass balance equations used to model changes in radon concentration through time routinely treat flux as a constant. This mathematical simplification is acceptable as a first order approximation despite the fact that it sidesteps an intrinsic geological problem: the majority of radon entering a cavity is exhaled as a result of advection along crustal discontinuities whose motions are inhomogeneous in both time and space. In this paper the dynamic nature of flux is investigated and the results are used to predict cave radon concentration for successive iterations. The first part of our numerical modelling procedure focuses on calculating cave air flow velocity while the second part isolates flux in a mass balance equation to simulate real time dependence among the variables. It is then possible to use this information to deliver an expression for computing cave radon concentration for successive iterations. The dynamic variables in the numerical model are represented by the outer temperature, the inner temperature, and the radon concentration while the static variables are represented by the radioactive decay constant and a range of parameters related to geometry of the cavity. Input data were recorded at Driny Cave in the Little Carpathians Mountains of western Slovakia. Here the cave passages have developed along splays of the NE-SW striking Smolenice Fault and a series of transverse faults striking NW-SE. Independent experimental observations of fault slip are provided by three permanently installed mechanical extensometers. Our numerical modelling has revealed four important flux anomalies between January 2010 and August 2011. Each of these flux anomalies was preceded by conspicuous fault slip anomalies. The mathematical procedure outlined in this paper will help to improve our understanding of radon migration along crustal discontinuities and its subsequent exhalation into the atmosphere. Furthermore, as it is possible to supply the model with continuous data, future research will focus on establishing a series of underground monitoring sites with the aim of generating the first real time global radon flux maps.

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