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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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That condensation nucleus is a small solid particle around which condensation occurs [16].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for mechanisms (Keyword) returned 221 results for the whole karstbase:
Showing 211 to 221 of 221
SPELEOGENESIS BY THE SULFIDIC SPRINGS AT NORTHERN SIERRA DE CHIAPAS, MEXICO, BASED ON THEIR WATER CHEMISTRY, 2014, Rosaleslagarde L. , Boston P. J.

Conspicuous brackish sulfidic springs have been described at the northern Sierra the Chiapas, Mexico. These springs are produced by a mixture between regional and local groundwater flow paths. The regional groundwater has an average Total Dissolved Ions of 3081 mg/L so it has a brackish composition. This brackish water is saturated with respect to calcite and dolomite but undersaturated with respect to gypsum, anhydrite and halite. The mass balance and the discharge rate are used to quantify the mass and volume of minerals that are dissolved by the brackish spring water following Appelo and Postma (1993). This quantification will allow comparing the various speleogenetic mechanisms in the area. This is considering the composition of the spring water is relatively constant over time, as it is suggested by periodic measurements at the Cueva de Villa Luz springs during the last 10 years.
Sulfur isotopes in the water are consistent with anhydrite dissolution as the main source of the sulfate to the brackish spring water. Thus, the average 6 mol/L of sulfate in the brackish springs are produced by dissolution of 6 mol of anhydrite after subtracting the sulfate that could result from evapotranspiration of rainwater. Each liter of brackish water dissolved an average of 882 mg of anhydrite, which are equivalent to dissolving 0.36 cm3 of this mineral considering a density of 2.981 g/cm3. Additionally, using the average brackish water discharge rate of 144 L/s, an average of 57 g of anhydrite are being dissolved each second per every liter of brackish water. This is a minimal value because some of the sulfate in the water is used by sulfate-reducing bacteria in the subsurface to produce the hydrogen sulfide in the spring water. The anhydrite subject to dissolution is found interbedded in the Cretaceous carbonates, either from the subsurface at 4,000 m below sea level to the carbonate outcrops.
Similarly, we can calculate the volume of halite that is being dissolved by the brackish springs, considering chloride is a conservative element and subtracting the chloride concentration from the rainwater from that of the spring water following Appelo & Postma (1993). The 22 mol/L of chloride in the brackish water can result from dissolution in the subsurface of 22 moles or 1.3 g of halite per liter of brackish water. This mass of halite dissolved is equal to 0.59 cm3 considering a density of 2.168 g/cm3. Alternatively, 118 g of halite are dissolved per second per each liter of brackish water if we use the average discharge rate of 144 L/s.
Even when the brackish springs are oversaturated with respect to calcite and dolomite, their dissolution is still possible due to the common ion-effect of calcium after anhydrite dissolution and by mixing of waters with different compositions. A range of 10 to 80 % of brackish water from the regional aquifers mixes with fresh water from the local aquifer based on their water chemistry. Additionally, sulfuric acid speleogenesis occurs due to the oxidation of hydrogen sulfide to sulfuric acid.
Finally, the increase in the chloride concentration of the fresh water springs with respect to the concentration in rainwater was used to estimate that from the 4000 mm/y of annual precipitation, only 4%, 158 to 182 mm/y, recharge the aquifers. This low percentage is slightly higher than the 3.3% recharge in marls, marly limestone, silts and clays (Sanz et al., 2011), probably because of the relatively small area of carbonate outcrops over the entire region and the lack of recharge in altitudes higher than 1500 m above sea level.
Sulfuric acid is the most obvious speleogenetic mechanism occurring in the caves of the northern Sierra de Chiapas, Mexico due to the high hydrogen sulfide concentration in the spring water. In addition, the location of the springs at a zone of regional and local discharge where waters from different composition converge and mix, and the amount of mixing calculated suggests mixing is also an important speleogenetic mechanism. However, the depth and the time constrains at which these two hypogenic mechanisms occur is still unknown. The relatively low rainwater recharge rate suggests epigenesis is limited. Most likely, the porosity created by dissolution of anhydrite and halite in the subsurface is occluded by the precipitation of calcite. Chemical modeling and petrography will help to elucidate the order of the reactions occurring in the subsurface.


The role of condensation in the evolution of dissolutional forms in gypsum caves: Study case in the karst of Sorbas (SE Spain), 2014, Gazquez F. , Calaforra J. M. , Forti P. , Waele J. D. , Sanna L.

The karst of Sorbas (SE Spain) is one of the most important gypsum areas worldwide. Its underground karst network comprises over 100 km of cave passages. Rounded smooth forms, condensation cupola and pendant-like features appear on the ceiling of the shallower passages as a result of gypsum dissolution by condensation water. Meanwhile, gypsum speleothems formed by capillarity, evaporation and aerosol deposition such as coralloids, gypsum crusts and rims are frequently observed closer to the passages floors. The role of condensation-dissolution mechanisms in the evolution of geomorphological features observed in the upper cave levels has been studied by means of long-term Micro-Erosion Meter (MEM) measurements, direct collection and analysis of condensation waters, and micrometeorological monitoring. Monitoring of erosion at different heights on gypsum walls of the Cueva del Agua reveals that the gypsum surface retreated up to 0.033 mm yr- 1 in MEM stations located in the higher parts of the cave walls. The surface retreat was negligible at the lowest sites, suggesting higher dissolution rates close to the cave ceiling, where warmer and moister air flows. Monitoring of microclimatic parameters and direct measurements of condensation water were performed in the Covadura Cave system in order to estimate seasonal patterns of condensation. Direct measurements of condensation water dripping from a metal plate placed in the central part of the El Bosque Gallery of Covadura Cave indicate that condensation takes place mainly between July and November in coincidence with rainless periods. The estimated gypsum surface lowering due to this condensation water is 0.0026 mm yr- 1. Microclimatic monitoring in the same area shows differences in air temperature and humidity of the lower parts of the galleries (colder and drier) with respect to the cave ceiling (warmer and wetter). This thermal sedimentation controls the intensity of the condensation-evaporation mechanisms at different heights in the cave.


Limestone weathering rates accelerated by micron-scale grain detachment, 2014,

The weathering of carbonate rocks plays a critical role in the evolution of landscapes, the erosion of buildings and monuments, and the global-scale shifting of carbon from the atmosphere to the ocean. Chemical dissolution is often assumed to govern the rates of weathering of carbonate rocks, although some studies have suggested that mechanical erosion could also play an important role. Quantifying the rates of the different processes has proved challenging, in part due to the high degree of variability encountered across different scales in both field and laboratory conditions. To constrain the rates and mechanisms controlling long-term limestone weathering, we analyze a lidar scan of the Western Wall, a Roman-period edifice located in Jerusalem. We find that extreme erosion rates in fine-grained micritic limestone blocks are as much as two orders of magnitude higher than the average rates estimated for coarse-grained limestone blocks at the same site. Atomic force microscope imaging of dissolving micritic limestone suggests that these elevated reaction rates are likely to be the result of rapid dissolution along micron-scale grain boundaries, followed by mechanical detachment of tiny particles from the surface. Our analysis indicates that such grain detachment could be the dominant erosional mode for fine-grained carbonate rocks in many regions on Earth.


Karstification of Dolomitic Hills at south of Coimbra (western-central Portugal) - Depositional facies and stratigraphic controls of the (palaeo)karst affecting the Coimbra Group (Lower Jurassic), 2014, Dimuccio, Luca Antonio

An evolutionary model is proposed to explain the spatio-temporal distribution of karstification affecting the Lower Jurassic shallow-marine carbonate succession (Coimbra Group) of the Lusitanian Basin, cropping out in the Coimbra-Penela region (western-central Portugal), in a specific morphostructural setting (Dolomitic Hills). Indeed, in the Coimbra Group, despite the local lateral and vertical distributions of dolomitic character and the presence of few thick sandy-argillaceous/shale and marly interbeds, some (meso)karstification was identified, including several microkarstification features. All types of karst forms are commonly filled by autochthonous and/or allochthonous post-Jurassic siliciclastics, implying a palaeokarstic nature.

The main aim of this work is to infer the interplay between depositional facies, diagenesis, syn- and postdepositional discontinuities and the spatio-temporal distribution of palaeokarst. Here, the palaeokarst concept is not limited to the definition of a landform and/or possibly to an associated deposit (both resulting from one or more processes/mechanisms), but is considered as part of the local and regional geological record.

Detailed field information from 21 stratigraphic sections (among several dozens of other observations) and from structural-geology and geomorphological surveys, was mapped and recorded on graphic logs showing the lithological succession, including sedimentological, palaeontological and structural data. Facies determination was based on field observations of textures and sedimentary structures and laboratory petrographic analysis of thin-sections. The karst and palaeokarst forms (both superficial and underground) were classified and judged on the basis of present-day geographic location, morphology, associated discontinuities, stratigraphic position and degree of burial by post-Jurassic siliciclastics that allowed to distinguish a exposed karst (denuded or completely exhumed) than a palaeokarst (covered or partially buried).

A formal lithostratigrafic framework was proposed for the local ca. 110-m-thick combined successions of Coimbra Group, ranging in age from the early Sinemurian to the early Pliensbachian and recorded in two distinct subunits: the Coimbra formation, essentially dolomitic; and the overlying S. Miguel formation, essentially dolomitic-limestone and marly-limestone.

The 15 identified facies were subsequently grouped into 4 genetically related facies associations indicative of sedimentation within supra/intertidal, shallow partially restricted subtidal-lagoonal, shoal and more open-marine (sub)environments - in the context of depositional systems of a tidal flat and a very shallow, inner part of a low-gradient, carbonate ramp. In some cases, thick bedded breccia bodies (tempestites/sismites) are associated to synsedimentary deformation structures (slumps, sliding to the W to NW), showing the important activity of N–S and NNE–SSW faults, during the Sinemurian. All these deposits are arranged into metre-scale, mostly shallowing-upward cycles, in some cases truncated by subaerial exposure events. However, no evidence of mature pedogenetic alteration, or the development of distinct soil horizons, was observed. These facts reflect very short-term subaerial exposure intervals (intermittent/ephemeral), in a semiarid palaeoclimatic setting but with an increase in the humidity conditions during the eogenetic stage of the Coimbra Group, which may have promoted the development of micropalaeokarstic dissolution (eogenetic karst).

Two types of dolomitization are recognized: one (a) syndepositional (or early diagenetic), massive-stratiform, of “penesaline type”, possibly resulting from refluxing brines (shallow-subtidal), with a primary dolomite related to the evaporation of seawater, under semiarid conditions (supra/intertidal) and the concurrent action of microbial activity; another (b) later, localized, common during diagenesis (sometimes with dedolomitization), particularly where fluids followed discontinuities such as joints, faults, bedding planes and, in some cases, pre-existing palaeokarstic features.

The very specific stratigraphic position of the (palaeo)karst features is understood as a consequence of high facies/microfacies heterogeneities and contrasts in porosity (both depositional and its early diagenetic modifications), providing efficient hydraulic circulation through the development of meso- and macropermeability contributed by syn- and postdepositional discontinuities such as bedding planes, joints and faults. These hydraulic connections significantly influenced and controlled the earliest karst-forming processes (inception), as well as the degree of subsequent karstification during the mesogenetic/telogenetic stages of the Coimbra Group. Multiple and complex karstification (polyphase and polygenic) were recognized, including 8 main phases, to local scale, integrated in 4 periods, to regional scale: Jurassic, Lower Cretaceous, pre-Pliocene and Pliocene-Quaternary. Each phase of karstification comprise a specific type of (palaeo)karst (eogenetic, subjacent, denuded, mantled-buried and exhumed).

Finally, geological, geomorphological and hydrogeological characteristics allowed to describe the local aquifer. The elaborated map of intrinsic vulnerability shows a karst/fissured and partially buried aquifer (palaeokarst) with high to very high susceptibility to the contamination.


Stable isotope data as constraints on models for the origin of coralloid and massive speleothems: The interplay of substrate, water supply, degassing, and evaporation, 2015, Caddeo Guglielmo A. , Railsback L. Bruce, Dewaele Jo, Frau Franco

Many speleothems can be assigned to one of two morphological groups: massive speleothems, which consist of compact bulks of material, and coralloids, which are domal to digitate in form. Faster growth on protrusions of the substrate occurs in the typical growth layers of coralloids (where those layers are termed “coralloid accretions”), but it is not observed in the typical layers of massive speleothems, which in contrast tend to smoothen the speleothem surface (and can therefore be defined as "smoothing accretions"). The different growth rates on different areas of the substrate are explainable by various mechanisms of CaCO3 deposition (e.g., differential aerosol deposition, differential CO2 and/or H2O loss from a capillary film of solution, deposition in subaqueous environments). To identify the causes of formation of coralloids rather than massive speleothems, this article provides data about d13C and d18O at coeval points of both smoothing and coralloid accretions, examining the relationship between isotopic composition and the substrate morphology. In subaerial speleothems, data show an enrichment in heavy isotopes both along the direction of water flow and toward the protrusions. The first effect is due to H2O evaporation and CO2 degassing during a gravity-driven flow of water (gravity stage) and is observed in smoothing accretions; the second effect is due to evaporation and degassing during water movement by capillary action from recesses to prominences (capillary stage) and is observed in subaerial coralloids. Both effects coexist in smoothing accretions interspersed among coralloid ones (intermediate stage). Thus this study supports the origin of subaerial coralloids from dominantly capillary water and disproves their origin by deposition of aerosol from the cave air. On the other hand, subaqueous coralloids seem to form by a differential mass-transfer from a still bulk of water towards different zones of the substrate along diffusion flux vectors of nutrients perpendicular to the isodepleted surfaces. Finally, this isotopic method has proved useful to investigate the controls on speleothem morphology and to obtain additional insights on the evolution of aqueous solutions inside caves.


Stable isotope data as constraints on models for the origin of coralloid and massive speleothems: The interplay of substrate, water supply, degassing, and evaporation, 2015,

Many speleothems can be assigned to one of two morphological groups: massive speleothems, which consist of compact bulks of material, and coralloids, which are domal to digitate in form. Faster growth on protrusions of the substrate occurs in the typical growth layers of coralloids (where those layers are termed “coralloid accretions”), but it is not observed in the typical layers of massive speleothems, which in contrast tend to smoothen the speleothem surface (and can therefore be defined as "smoothing accretions"). The different growth rates on different areas of the substrate are explainable by various mechanisms of CaCO3 deposition (e.g., differential aerosol deposition, differential CO2 and/or H2O loss from a capillary film of solution, deposition in subaqueous environments). To identify the causes of formation of coralloids rather than massive speleothems, this article provides data about d13C and d18O at coeval points of both smoothing and coralloid accretions, examining the relationship between isotopic composition and the substrate morphology. In subaerial speleothems, data show an enrichment in heavy isotopes both along the direction of water flow and toward the protrusions. The first effect is due to H2O evaporation and CO2 degassing during a gravity-driven flow of water (gravity stage) and is observed in smoothing accretions; the second effect is due to evaporation and degassing during water movement by capillary action from recesses to prominences (capillary stage) and is observed in subaerial coralloids. Both effects coexist in smoothing accretions interspersed among coralloid ones (intermediate stage). Thus this study supports the origin of subaerial coralloids from dominantly capillary water and disproves their origin by deposition of aerosol from the cave air. On the other hand, subaqueous coralloids seem to form by a differential mass-transfer from a still bulk of water towards different zones of the substrate along diffusion flux vectors of nutrients perpendicular to the isodepleted surfaces. Finally, this isotopic method has proved useful to investigate the controls on speleothem morphology and to obtain additional insights on the evolution of aqueous solutions inside caves.


Stable isotope data as constraints on models for the origin of coralloid and massive speleothems: The interplay of substrate, water supply, degassing, and evaporation, 2015, Caddeo Guglielmo Angelo, Railsback Loren Bruce, De Waele Jo, Frau Franco

Many speleothems can be assigned to one of two morphological groups: massive speleothems, which consist of compact bulks of material, and coralloids, which are domal to digitate in form. Faster growth on protrusions of the substrate occurs in the typical growth layers of coralloids (where those layers are termed “coralloid accretions”),

but it is not observed in the typical layers of massive speleothems, which in contrast tend to smoothen the speleothem surface (and can therefore be defined as “smoothing accretions”). The different growth rates on different areas of the substrate are explainable by various mechanisms of CaCO3 deposition (e.g., differential aerosol deposition, differential CO2 and/or H2O loss fromacapillary filmof solution, deposition in subaqueous environments).

To identify the causes of formation of coralloids rather than massive speleothems, this article provides data about δ13C and δ18O at coeval points of both smoothing and coralloid accretions, examining the relationship between isotopic composition and the substratemorphology. In subaerial speleothems, data showenrichment in heavy isotopes both along the direction of water flow and toward the protrusions. The first effect is due to H2O evaporation and CO2 degassing during a gravity-driven flow of water (gravity stage) and is observed in smoothing accretions; the second effect is due to evaporation and degassing duringwatermovement by capillary action from recesses to prominences (capillary stage) and is observed in subaerial coralloids. Both effects coexist in smoothing accretions interspersed among coralloid ones (intermediate stage). Thus this study supports the origin of subaerial coralloids from dominantly capillary water and disproves their origin by deposition of aerosol fromthe cave air. On the other hand, subaqueous coralloids seem to form by a differential mass-transfer from a still bulk of water toward different zones of the substrate along diffusion flux vectors of nutrients perpendicular to the iso-depleted surfaces. Finally, this isotopic method has proved useful to investigate the controls on speleothem morphology and to obtain additional insights on the evolution of aqueous solutions inside caves.


The role of condensation in the evolution of dissolutional forms in gypsum caves: Study case in the karst of Sorbas (SE Spain), 2015, Gazquez Fernando, Calaforra José Maria, Forti Paolo, De Waele Jo, Sanna Laura

The karst of Sorbas (SE Spain) is one of the most important gypsum areas worldwide. Its underground karst network comprises over 100 km of cave passages. Rounded smooth forms, condensation cupola and pendant-like features appear on the ceiling of the shallower passages as a result of gypsum dissolution by condensation water. Meanwhile, gypsum speleothems formed by capillarity, evaporation and aerosol deposition such as coralloids, gypsum crusts and rims are frequently observed closer to the passage floors. The role of condensation–dissolution mechanisms in the evolution of geomorphological features observed in the upper cave levels has been studied by means of long-term micro-erosion meter (MEM) measurements, direct collection and analysis of condensation waters, and micrometeorological monitoring. Monitoring of erosion at different heights on gypsum walls of the Cueva del Agua reveals that the gypsum surface retreated up to 0.033 mm yr−1 in MEM stations located in the higher parts of the cave walls. The surface retreat was negligible at the lowest sites, suggesting higher dissolution rates close to the cave ceiling, where warmer and moister air flows. Monitoring of microclimatic parameters and direct measurements of condensation water were performed in the Covadura Cave system in order to estimate seasonal patterns of condensation. Direct measurements of condensation water dripping from a metal plate placed in the central part of the El Bosque Gallery of Covadura Cave indicate that condensation takes place mainly between July and November in coincidence with rainless periods. The estimated gypsum surface lowering due to this condensation water is 0.0026 mm yr−1. Microclimatic monitoring in the same area shows differences in air temperature and humidity of the lower parts of the galleries (colder and drier) with respect to the cave ceiling (warmer and wetter). This thermal sedimentation controls the intensity of the condensation–evaporation mechanisms at different heights in the cave.


Quaternary faulting in the Tatra Mountains, evidence from cave morphology and fault-slip analysis, 2015, Szczygieł Jacek

Tectonically deformed cave passages in the Tatra Mts (Central Western Carpathians) indicate some fault activity during the Quaternary. Displacements occur in the youngest passages of the caves indicating (based on previous U-series dating of speleothems) an Eemian or younger age for those faults, and so one tectonic stage. On the basis of stress analysis and geomorphological observations, two different mechanisms are proposed as responsible for the development of these displacements. The first mechanism concerns faults that are located above the valley bottom and at a short distance from the surface, with fault planes oriented sub-parallel to the slopes. The radial, horizontal extension and vertical σ1 which is identical with gravity, indicate that these faults are the result of gravity sliding probably caused by relaxation after incision of valleys, and not directly from tectonic activity. The second mechanism is tilting of the Tatra Mts. The faults operated under WNW-ESE oriented extension with σ1 plunging steeply toward the west. Such a stress field led to normal dip-slip or oblique-slip displacements. The faults are located under the valley bottom and/or opposite or oblique to the slopes. The process involved the pre-existing weakest planes in the rock complex: (i) in massive limestone mostly faults and fractures, (ii) in thin-bedded limestone mostly inter-bedding planes. Thin-bedded limestones dipping steeply to the south are of particular interest. Tilting toward the N caused the hanging walls to move under the massif and not toward the valley, proving that the cause of these movements was tectonic activity and not gravity.


The current status of mapping karst areas and availability of public sinkhole-risk resources in karst terrains of the United States, 2015,

Subsidence from sinkhole collapse is a common occurrence in areas underlain by water-soluble rocks such as carbonate and evaporite rocks, typical of karst terrain. Almost all 50 States within the United States (excluding Delaware and Rhode Island) have karst areas, with sinkhole damage highest in Florida, Texas, Alabama, Missouri, Kentucky, Tennessee, and Pennsylvania. A conservative estimate of losses to all types of ground subsidence was $125 million per year in 1997. This estimate may now be low, as review of cost reports from the last 15 years indicates that the cost of karst collapses in the United States averages more than $300 million per year. Knowing when a catastrophic event will occur is not possible; however, understanding where such occurrences are likely is possible. The US Geological Survey has developed and main-tains national-scale maps of karst areas and areas prone to sinkhole formation. Several States provide additional resources for their citizens; Alabama, Colorado, Florida, Indiana, Iowa, Kentucky, Minnesota, Missouri, Ohio, and Pennsylvania maintain databases of sinkholes or karst features, with Florida, Kentucky, Missouri, and Ohio providing sinkhole reporting mechanisms for the public.


Chemistry and Karst, 2015, White, William B.

The processes of initiation and development of characteris­tic surface karst landforms and underground caves are nearly all chemical processes. This paper reviews the advances in understanding of karst chemistry over the past 60 years. The equilibrium chemistry of carbonate and sulfate dissolution and deposition is well established with accurate values for the necessary constants. The equations for bulk kinetics are known well enough for accurate modeling of speleogenetic processes but much is being learned about atomic scale mechanisms. The chemistry of karst waters, expressed as parameters such as total dissolved carbonates, saturation index, and equilibrium carbon dioxide pressure are useful tools for probing the internal char­acteristics of karst aquifers. Continuous records of chemical parameters (chemographs) taken from springs and other karst waters mapped onto discharge hydrographs reveal details of the internal flow system. The chemistry of speleothem deposi­tion is well understood at the level of bulk processes but much has been learned of the surface chemistry on an atomic scale by use of the atomic force microscope. Least well understood is the chemistry of hypogenetic karst. The main chemical reac­tions are known but equilibrium modeling could be improved and reaction kinetics are largely unknown.


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