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Anomalous behaviour of specific electrical conductivity (SEC) was observed at a karst spring in Slovenia during 26 high-flow events in an 18-month monitoring period. A conceptual model explaining this anomalous SEC variability is presented and reproduced by numerical modelling, and the practical relevance for source protection zoning is discussed. After storm rainfall, discharge increases rapidly, which is typical for karst springs. SEC displays a first maximum during the rising limb of the spring hydrograph, followed by a minimum indicating the arrival of freshly infiltrated water, often confirmed by increased levels of total organic carbon (TOC). The anomalous behaviour starts after this SEC minimum, when SEC rises again and remains elevated during the entire high-flow period, typically 20–40 µS/cm above the baseflow value. This is explained by variable catchment boundaries: When the water level in the aquifer rises, the catchment expands, incorporating zones of groundwater with higher SEC, caused by higher unsaturated zone thickness and subtle lithologic changes. This conceptual model has been checked by numerical investigations. A generalized finite-difference model including high-conductivity cells representing the conduit network (“discrete-continuum approach”) was set up to simulate the observed behaviour of the karst system. The model reproduces the shifting groundwater divide and the nearly simultaneous increase of discharge and SEC during high-flow periods. The observed behaviour is relevant for groundwater source protection zoning, which requires reliable delineation of catchment areas. Anomalous behaviour of SEC can point to variable catchment boundaries that can be checked by tracer tests during different hydrologic conditions.
Karst aquifers represent dual flow systems consisting of a highly conductive conduit system embedded in a less permeable rock matrix. Hybrid models iteratively coupling both flow systems generally consume much time, especially because of the nonlinearity of turbulent conduit flow. To reduce calculation times compared to those of existing approaches, a new iterative equation solver for the conduit system is developed based on an approximated Newton–Raphson expression and a Gauß–Seidel or successive over-relaxation scheme with a single iteration step at the innermost level. It is implemented and tested in the research code CAVE but should be easily adaptable to similar models such as the Conduit Flow Process for MODFLOW-2005. It substantially reduces the computational effort as demonstrated by steady-state benchmark scenarios as well as by transient karst genesis simulations. Water balance errors are found to be acceptable in most of the test cases. However, the performance and accuracy may deteriorate under unfavorable conditions such as sudden, strong changes of the flow field at some stages of the karst genesis simulations.
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Unusual speleothems resembling giant mushrooms occur in Cueva Grande de Santa
Catalina, Cuba. Although these mineral buildups are considered a natural heritage, their
composition and formation mechanism remain poorly understood. Here we characterize
their morphology and mineralogy and present a model for their genesis. We propose that
the mushrooms, which are mainly comprised of calcite and aragonite, formed during four
different phases within an evolving cave environment. The stipe of the mushroom is an
assemblage of three well-known speleothems: a stalagmite surrounded by calcite rafts
that were subsequently encrusted by cave clouds (mammillaries). More peculiar is the
cap of the mushroom, which is morphologically similar to cerebroid stromatolites and
thrombolites of microbial origin occurring in marine environments. Scanning electron
microscopy (SEM) investigations of this last unit revealed the presence of fossilized
extracellular polymeric substances (EPS)—the constituents of biofilms and microbial
mats. These organic microstructures are mineralized with Ca-carbonate, suggesting that
the mushroom cap formed through a microbially-influenced mineralization process. The
existence of cerebroid Ca-carbonate buildups forming in dark caves (i.e., in the absence
of phototrophs) has interesting implications for the study of fossil microbialites preserved
in ancient rocks, which are today considered as one of the earliest evidence for life on
Earth.
The historical study of Australian caves and caving areas is fascinating although involving the expenditure of vast amounts of time. Australia's early days are unusually well-documented, but in the case of caves the early history is usually wrapped up in rumour, hearsay and clouded by lack of written record. Most research work means long hours poring over old newspaper files, mine reports, land department records and so on, little of which is catalogued. A small number of exploration journals and scientific studies have extensive material on special cave areas, and of these, the volume by Rev. Julian Edmund Woods, F.G.S., F.R.S.V., F.P.S., etc., and is one of the most interesting. This book gives the ideas and beliefs of 100 years ago concerning the origin, development and bone contents of caves and makes interesting reading in the light of more recent studies of cave origins. Wood's study "Geological Observations in South Australia : Principally in the District South-East of Adelaide" was published in 1862 by Longman, Green, Roberts and Green, London. In a preface dated November 15, 1861, Rev. Woods points out that the book was written while he was serving as a missionary in a 22,000 square mile district, and "without the benefit of reference, museum, library, or scientific men closer than England". Up to the time of writing, almost no scientific or geological work had been done in South Australia and much of the area was completely unexplored. The book, also, contained the first detailed description of caves in the south-east of the state. Father Woods writes about many different types of caves in South Australia, for instance, the "native wells" in the Mt. Gambier/Mt. Shanck area. These are caves, rounded like pipes, and generally leading to water level. Woods points out their likeness to artificial wells. He also writes of sea cliff caves, particularly in the Guichen Bay area, and blow holes caused by the action of the waves on the limestone cliffs. Woods discusses many other types of caves found further inland, particularly bone caves. Father Woods discusses cave origins under two sub-heads: 1. Trap rock caves generally resulting from violent igneous action, and 2. Limestone caves resulting from infiltration of some kind. He is mainly concerned with limestone caves which he sub-divides into (a) crevice caves - caves which have arisen from fissures in the rock and are therefore wedge-shaped crevices, widest at the opening, (b) sea-beach caves, caves which face the seashore and are merely holes that have been worn by the dashing of the sea on the face of the cliff, (c) egress caves, or passages to give egress to subterranean streams, (d) ingress caves, or passages caused by water flowing into the holes of rocks and disappearing underground. These caves would have entrance holes in the ground, opening very wide underneath, and having the appearance of water having entered from above, (e) finally a group of caves which he lists by use as "dens of animals".
The geology and nature of the caves is discussed. Cave development has been affected by glacial outwash and periglacial conditions which must be taken into account when considering the development and distribution of cave fauna. The food supply in the caves is limited by the absence of cave-inhabiting bats. Floods while adding to the food supply must be destructive to some forms of terrestrial cave life. The cave fauna consists entirely of invertebrates. The carab genus Idacarabus Lea contains the only troglobites found in Tasmania. A common troglophile throughout the island is Hickmania troglodytes (Higgins and Petterd) which belongs to a very small group of relict spiders. Five species of cave crickets are known from Tasmania and Flinders Island. Three species belong to the genus Micropathus Richards and show an interesting distribution pattern. A single species of glow-worm, Arachnocampa (Arachnocampa) tasmaniensis Ferguson occurs in a number of Tasmanian caves. It is more closely related to the New Zealand species than to glow worms found on the Australian mainland. Other terrestrial cave life is briefly discussed. Aquatic cave life is poorly known. The syncarid Anaspides tasmaniae (Thomson) has been recorded from several caves. It differs from epigean forms in reduction of pigment.
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