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Enviroscan Ukrainian Institute of Speleology and Karstology

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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That polluted water is water that has become contaminated by sewage or other contaminants such that the water quality has become severely degraded.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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What is Karstbase?



Browse Speleogenesis Issues:

KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
See all featured articles
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for modeling (Keyword) returned 235 results for the whole karstbase:
Showing 16 to 30 of 235
The combined use of Sr-87/Sr-86 and carbon and water isotopes to study the hydrochemical interaction between groundwater and lakewater in mantled karst, 1996,
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Katz B. G. , Bullen T. D. ,
The hydrochemical interaction between groundwater and lakewater influences the composition of water that percolates downward from the surficial aquifer system through the underlying intermediate confining unit and recharges the Upper Floridan aquifer along highlands in Florida. The Sr-87/Sr-86 ratio along with the stable isotopes, D, O-18, and C-13 were used as tracers to study the interaction between groundwater, lakewater, and aquifer minerals near Lake Barco, a seepage lake in the mantled karst terrane of northern Florida. Upgradient from the lake, the Sr-87/Sr-86 ratio of groundwater decreases with depth (mean values of 0.71004, 0.70890, and 0.70852 for water from the surficial aquifer system, intermediate confining unit, and Upper Floridan aquifer, respectively), resulting from the interaction of dilute oxygenated recharge water with aquifer minerals that are less radiogenic with depth. The concentrations of Sr2 generally increase with depth, and higher concentrations of Sr2 in water from the Upper Floridan aquifer (20-35 mu g/L), relative to water from the surficial aquifer system and the intermediate confining unit, result from the dissolution of Sr-bearing calcite and dolomite in the Eocene limestone. Dissolution of calcite [delta(13)C = -1.6 permil (parts per thousand)] is also indicated by an enriched delta(13)C(DIC) (-8.8 to -11.4 parts per thousand) in water from the Upper Floridan aquifer, relative to the overlying hydrogeologic units (delta(13)C(DIC) < -16 parts per thousand). Groundwater downgradient from Lake Barco was enriched in O-18 and D relative to groundwater upgradient from the lake, indicating mixing of lakewater leakage and groundwater. Downgradient from the lake, the Sr-87/Sr-86 ratio of groundwater and aquifer material become less radiogenic and the Sr2 concentrations generally increase with depth. However, Sr2 concentrations are substantially less than in upgradient groundwaters at similar depths. The lower Sr2 concentrations result from the influence of anoxic lakewater leakage on the mobility of Sr2 from clays. Based on results from mass-balance modeling, it is probable that cation exchange plays the dominant role in controlling the Sr-87/Sr-86 ratio of groundwater, both upgradient and downgradient from Lake Barco. Even though groundwater from the three distinct hydrogeologic units displays considerable variability in Sr concentration and isotopic composition, the dominant processes associated with the mixing of lakewater leakage with groundwater, as well as the effects of mineral-water interaction, can be ascertained by integrating the use of stable and radiogenic isotopic measurements of groundwater, lakewater, and aquifer minerals

A combined continuum and discrete network reactive transport model for the simulation of karst development, 1996,
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Clemens T Huckinhaus D. , Sauter M. , Liedl R. , Teutsch G.

A Model of Structure and Genesis for the Gypsum Nest, Found in the Geophysicheskaya Cave (Kugitangtou Mountains,Turkmenistan), 1997,
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Maltsev, V. A.
A description, and a possible structure and genetic mechanism for a gypsum nest, a very rare speleothem consisting of gypsum needles growing from a drying clay massif, are considered. Because of conservation concerns, theoretical modeling is the only acceptable method for studying this complicated and delicate feature. The model suggested considers the nest as a screw-dislocated spherocrystal, with its sub-individuals separated by corrosion at some initial stage, and having separate growth at later stages.

Dedolomitization as a driving mechanism for karst generation in Permian Blaine formation, southwestern Oklahoma, USA, 1997,
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Raines M. A. , Dewers T. A. ,
Cyclic deposits of Permian shales, dolomites, and halite and gypsum-bearing strata in the Blaine Formation of Southwestern Oklahoma contain abundant karst features. The present study shows that an important mechanism of karst development in these sequences is dedolomitization, wherein gypsum and dolomite in close spatial proximity dissolve and supersaturate groundwaters with respect to calcite. The net loss of mass accompanying this process (dolomite and gypsum dissolution minus calcite precipitation) can be manifest in secondary porosity development while the coupled nature of this set of reactions results in the retention of undersaturated conditions of groundwater with respect to gypsum. The continued disequilibrium generates karst voids in gypsum-bearing aquifers, a mineral-water system that would otherwise rapidly equilibrate. Geochemical modeling (using the code PHRQPITZ, Plummer et al 1988) of groundwater chemical data from Southwestern Oklahoma from the 1950's up to the present suggests that dedolomitization has occurred throughout this time period in evaporite sequences in Southwestern Oklahoma. Reports from groundwater well logs in the region of vein calcite suggest secondary precipitation, an observation in accord with dedolomite formation In terms of the amounts of void space produced by dissolution, dedolomitization can dominate gypsum dissolution alone, especially in periods of quiescent aquifer recharge when gypsum-water systems would have otherwise equilibrated and karst development ceased. Mass balance modeling plus molar volume considerations show that for every cubic cm of original rock (dolomite plus gypsum), there is 0.54 cm(3) of calcite and 0.47 cm(3) of void space produced Only slightly more pore space results if the dedolomitization reaction proceeds by psuedomorphic replacement of dolomite by calcite than in a reaction mechanism based on conservation of bicarbonate

Risk assessment methodology for karst aquifers .2. Solute-transport modeling, 1997,
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Field Ms,
Ground-water flow and solute-transport simulation modeling are major components of most exposure and risk assessments of contaminated aquifers. Model simulations provide information on the spatial and temporal distributions of contaminants in subsurface media but are difficult to apply to karst aquifers in which conduit flow is important. Ground-water flow and solute transport in karst conduits typically display rapid-flow velocities, turbulent-flow regimes, concentrated pollutant-mass discharge, and exhibit open-channel or closed-conduit how Conventional groundwater models, dependent on the applicability of Darcy's law, are inappropriate when applied to karst aquifers because of the (1) nonapplicability of Darcian-flow parameters, (2) typically nonlaminar flow regime, and (3) inability to locate the karst conduits through which most flow and contaminant transport occurs. Surface-water flow and solute-transport models conditioned on a set of parameters determined empirically from quantitative ground-water tracing studies may be effectively used to render fate-and-transport values of contaminants in karst conduits. Hydraulic-flow and geometric parameters developed in a companion paper were used in the surface-water model, TOXI5, to simulate hypothetical slug and continuous-source releases of ethylbenzene in a karst conduit. TOXI5 simulation results showed considerable improvement for predicted ethylbenzene-transport rates and concentrations over qualitative tracing and analytical ground-water model results. Ethylbenzene concentrations predicted by TOXI5 simulations were evaluated in exposure and risk assessment models

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Field Ms,

The problem of modeling limestone springs: The case of Bagnara (north Apennines, Italy), 1997,
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Angelini P, Dragoni W,
The Bagnara spring (Central Italy), fed by a fractured, carbonate, and, in some areas, karstic aquifer, was examined. The available information is derived from geological mapping and daily flows over a period of 20 consecutive years. There are no data on the hydrogeological parameters nor on the aquifer hydraulic head, which is known only at the elevation of the spring. The objective of the work was to construct an appropriate mathematical model for the spring despite the scarcity of available information. The MODFLOW code was used to simulate the system following the equivalent porous media approach. The hydraulic conductivity and the specific yield equivalents were estimated by calibrating the model on the master depletion curve and taking into consideration the topographic elevation of the system's surface. The size of the protection area around the spring was investigated on the basis of the isochrons constructed from the results of the model

Simulation of the evolution of maze caves., 1997,
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Clemens T. , Hiickinghaus D. , Sauter M. , Liedl R. , Teutsch G.
The development of cave systems in carbonate rocks depends on a variety of boundary and initial conditions. Among the cave systems, two main types of geometries can be distinguished: the dendritic and maze pattern. A numerical model has been developed capable of modeling the genesis of karst systems in complex geological environments. It is applied to simulate the development of the above mentioned two different types of cave geometries. The results confirm that a prerequisite for the development of maze caves is evenly distributed recharge (White 1969). However more important for the development of maze caves is that flow through the system is restricted by an overlying less conductive horizon, e.g. a sandstone caprock. Thus the feed back mechanism of higher flow rates leading to higher dissolution rates and therefore the preferential development of a small number of tubes does not dominate the evolution of the karst aquifer. This hydraulic restriction furthers the development of other conduits also to achieve a significant diameter.

Parameter identification in double-continuum models applied to karst aquifers., 1997,
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Mohrlok U. , Kienie J. , Teutsch G.
One modelling approach which proved successful in describing the groundwater flow within karst terraines is based on the double-continuum concept. This concept was first introduced by Teutsch (1988) and subsequently used by Teutsch & Sauter (1991), Sauter (1992), Lang (1995), Mohrlok (1996) and others to describe the ambivalent characteristics of karst aquifers. However, the approach has the drawback that the double-continuum model parameters can be determined only through model calibration (inverse approach), i.e. so far the model parameters cannot be related directly to physical field measurements. Therefore, in order to develop a better understanding of the physical significance of hydraulic parameters within double-continuum systems, a detailed numerical modeling study was conducted. For this purpose a number of synthetic but realistic karst aquifer network geometries were generated and analysed. The response of the karst network to recharge events was simulated using a detailed discrete fracture flow model with the resulting head and spring flow variographs being subsequently assumed as field measurements. This 'measured' data was then used for the calibration of a double-continuum model and the resulting parameters were compared to the original karst network geometry data. This comparison was used to develop mathematical/physical relationships between the discrete karst network geometry representing reality and the double-continuum parameter representation of it.

Modeling of CO2 degassing and pH in a stream-aquifer system., 1998,
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Choi J. , Hulseapple M. N. , Conklin M. N. , Harwey J. W.
(for the Abstract see Hydrofacts, July 1998 p.4)

Modeling of storm responses in conduit flow aquifers with reservoirs., 1998,
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Halihan Todd. , Wick Carol M.

Physical response of a karst drainage basin to flood pulses: Example of the Devil's Icebox cave system (Missouri, USA), 1998,
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Halihan T. , Wicks C. M. , Engeln J. F. ,
In karst aquifers, water moves from the recharge area (sinkhole plains and swallets) to the discharge area (springs), traveling kilometers through the groundwater system in a period of hems to days. Transit rimes through karst aquifers are a function of the conduit geometry and connectedness, intensity and duration of the recharge event, and antecedent soil moisture. Often many of these factors are unknown or difficult to quantify. Therefore, predicting the response of a karst basin to recharge is difficult. Numerous researchers have attempted to understand the response of a karst basin, but a good understanding of whether the response is dependent on local features or regional effects is currently lacking. From April 1994 to May 1995, flood pulse hydrographs from a karst aquifer with well-developed and well-documented conduits (Devil's Icebox cave system) were obtained from a gaging station near the spring of the karst basin. Data were also collected from within the conduit system in an attempt to determine whether flow was locally controlled by constrictions in the conduits. Based on an application of Bernoulli's equation, analyses of the changes in kinetic head and potential head over time indicated local control during storm events. The observed sediment patterns and water level variations also support localized flow control during storm events. A numerical model of the constrictions was rested and reproduced the responses observed at the spring during initial periods of storm events. The model illustrated that the constricted flow was very sensitive to recharge. It also illustrated the transition from local control due to constriction to regional controls due to the aquifer matrix. (C) 1998 Elsevier Science B.V

Modeling of storm responses in conduit flow aquifers with reservoirs, 1998,
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Halihan Todd, Wicks Carol M. ,
In aquifers containing large voids, such as karst aquifers with caves or basaltic aquifers with lava tubes, hydrographs at wells or springs are used to analyze the structure and response of the hydrogeological system. Numerical modeling of hydrograph response is commonly based on either inverse techniques or postulated flow geometries. However, the range of mechanisms for generating hydrograph responses have not been fully investigated.Physical modeling of these complex non-Darcian systems permits better understanding of the storm responses that conduit systems may generate. Using a numerical model of conduit flow systems which incorporates turbulent flow, some of the mechanisms that can alter storm pulses were investigated by treating them as combinations of pipes that connect reservoirs.The results indicate that the response of a conduit-flow aquifer can range from what has been called 'diffuse' or 'steady' to 'conduit' or 'flashy', without employing a diffusive component. A full range of behavior can be the result of changes from phreatic to epiphreatic conditions in a conduit, changes in conduit geometry, or multiple springs draining the same system. The results provide a quantitative tool to assess spring and well hydrographs, and illustrate mechanisms that can generate observed responses, which have previously been qualitatively interpreted

Changes in the isotopic and chemical composition of ground water resulting from a recharge pulse from a sinking stream, 1998,
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Katz B. G. , Catches J. S. , Bullen T. D. , Michel R. L. ,
The Little River, an ephemeral stream that drains a watershed of approximately ss km(2) in northern Florida, disappears into a series of sinkholes along the Cody Scarp and flows directly into the carbonate Upper Floridan aquifer, the source of water supply in northern Florida. The changes in the geochemistry of ground water caused by a major recharge pulse from the sinking stream were investigated using chemical and isotopic tracers and mass-balance modeling techniques, Nine monitoring wells were installed open to the uppermost part of the aquifer in areas near the sinks where numerous subterranean karst solution features were identified using ground penetrating radar. During high-flow conditions in the Little River, the chemistry of water in some of the monitoring wells changed, reflecting the mixing of river water with ground water. Rapid recharge of river water into some parts of the aquifer during high-flow conditions was indicated by enriched values of delta O-18 and delta deuterium (-1.67 to -3.17 per mil and -9.2 to -15.6 per mil, respectively), elevated concentrations of tannic acid, higher (more radiogenic) Sr-87/Sr-86 ratios, and lower concentrations of Rn-222, silica, and alkalinity compared to low-how conditions. The proportion of river water that mixed with ground water ranged from 0.10 to 0.67 based on binary mixing models using the tracers O-18, deuterium, tannic acid, silica, Rn-222, and Sr-87/Sr-86. On the basis of mass-balance modeling during steady-state how conditions, the dominant processes controlling carbon cycling in ground water are the dissolution of calcite and dolomite in aquifer material, and aerobic degradation of organic matter. (C) 1998 Elsevier Science B.V. All rights reserved

Processes controlling colloid composition in a fractured and karstic aquifer in eastern Tennessee, USA, 1998,
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Mccarthy J. F. , Shevenell L. ,
Groundwater was sampled from a number of wells along recharge pathways between fractured shale and karstic formations to evaluate the chemical and hydrologic mechanisms controlling the nature and abundance of groundwater colloids. The colloids recovered using low flow rate purging and sampling exhibited a composition and abundance consistent with lithology, flow paths, and effects of hydrology and aqueous chemistry on colloid mobilization and stability. In general, the larger-size colloids and Ca-containing colloids were more abundant in the karstic lithologies, while Na-containing colloids were more important in the shales. The composition of the colloids reflected recharge pathways from the fractured shale and dolomite formations on the ridges into the limestone in the valley floor. The Mg-colloids in the limestone reflect the possible contributions from the dolomite, while the Na, K, and Si reflect possible contributions from the shale, However, it was not possible to use the colloid composition as a signature to demonstrate colloid transport from one lithology to another. Mixing of recharge water from the shale with groundwater within the limestone formation and precipitation/dissolution reactions could account for the colloids present in the limestone without invoking transport of specific shale-derived colloids into the limestone formation. The abundance of colloids in groundwater appears to be controlled by both chemical factors affecting colloid stability, as well as physical factors related to hydrology (storm-driven recharge and water velocities). In general, colloids were more abundant in wells with low ionic strength, such as shallow wells in water table aquifers near sources of recharge at the top of the ridges, Increases in cation concentrations due to dissolution reactions along Bow paths were associated with decreases in colloid abundance. However, in spite of elevated ionic strength, colloid concentrations tended to be unexpectedly high in karstic wells that were completed in cavities or water-bearing fractures. The higher levels of colloids appear to be related to storm-driven changes in chemistry or flow rates that causes resuspension of colloids settled within cavities and fractures. Published by Elsevier Science B.V

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