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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

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That silicate rock is rock containing silica in predominant proportions [16].?

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Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for permeability (Keyword) returned 236 results for the whole karstbase:
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Stone forest aquifers comprise an important class of shallow, unconfined karstic aquifers in the south China karst belt. They occur under flat areas such as floors of karst depressions, stream valleys, and karst plains. The frameworks for the aquifers are the undissolved carbonate spires and ribs in epikarst zones developed on carbonate strata. The ground water occurs within clastic sediments which infill the dissolution voids. The aquifers are thin, generally less than 100 meters thick, and are characterized by large lateral permeabilities and small storage. The result is that the aquifers are difficult to manage because recharge during the rainy season moves rapidly out of the aquifers. Water levels fall sharply as the dry season progresses and the ground-water supply falls off accordingly. The magnitude and duration of the seasonal recharge pulse that replenishes the stone forest aquifers have been severely impacted by massive post-1958 deforestation in the south China karst region. Water that was formerly retained beyond the wet season in the forested uplands, later to be released to the stone forest aquifers under the lowland plains, now passes quickly through the system during the wet season. The loss of this seasonal upland storage has resulted in both a reduction in the volume of recharge to the lowland stone forest aquifers and a shortening of the seasonal recharge event. The result is accelerated water-level declines in the stone forest aquifers as the dry season progresses which, in turn, causes premature dewatering of wells and decreased spring discharges. This response is compounded by increased ground-water withdrawals as the people attempt to offset the declining supply. Management of the total water-supply system requires not only tinkering with the aquifer, but massive reforestation efforts to restore dry season water retention in the upland parts of the watersheds

On Grand Cayman, freshwater bodies present in the Bluff Formation are typically small and occur as thin lenses floating on top of dense saline water. Evaluation of the water resource potential of these freshwater lenses is difficult because of their variable hydrological conditions, complex paleohydrogeology and aquifer heterogeneity. Secondary porosity created by preferential dissolution of aragonitic fossil components is common. Open fissures and joints developed under tectonic stress and karst development associated with sea-level fluctuations are, however, the two most important causes of porosity and permeability in the aquifers on Grand Cayman. Fracture and karst porosity control the lens occurrence by: (1) acting as avenues for the intrusion of seawater or upward migration of saline water; (2) acting as recharge focal points; (3) enhancing hydrodynamic dispersion; (4) defining lens geometry; (5) facilitating carbonate dissolution along joints and fissures. A clear understanding of the hydrological and geological conditions is important in developing small lenses in a setting similar to that on Grand Cayman. This pragmatic approach can help identify the optimum location of the well field and avoid areas particularly susceptible to saline water intrusion

Rospo Mare field is located in the Adriatic Sea, 20 km of the Abruzzes coast, at an average depth of 80 m. The reservoir is a karst which is essentially conductive; yet unlike a conventional porous medium, it cannot be simulated by the usual tools and techniques of reservoir simulation. Therefore, several approaches were used to describe the flow mechanism during the production period in greater detail. The first approach consisted of generating three-dimensional images which were constrained by both petrophysical and geological factors and then, using up-scaling techniques, obtaining the equivalent permeabilities (scalar or tensorial) of grid blocks located in different zones within the karst. This approach shows that within the infiltration zone it is possible, whatever the scale, to find an equivalent homogeneous porous medium; on the other hand, within the epikarst this equivalent medium does not exist below pluridecametric dimensions. Thus it is impossible to study the sweeping mechanism on a small scale, so we must use a deterministic model which describes the network of pipes in the compact matrix, in which a waterflood is simulated by means of a conform finite-element model. This constituted the second approach. The third and final approach consisted of inventing a system of equations to analytically solve the pressure field in a network of vertical pipes which are intersected by a production drain and submitted to a strong bottom water-drive. This model allows us to simulate the water-oil contact rise within the reservoir and study the flows depending on the constraints applied to the production well. It appears that cross flows occur in the pipes even during the production period

The Rospo Mare oil field is located in the Adriatic Sea, 20 km off the Italian coast. The reservoir lies at a depth of 1300 m and consists of a paleokarst oi Oligocene to Miocene age which developed within Cretaceous limestones, now covered by 1200 m of Mio-Pliocene sequences. The oil column is about 140 m 8 high. The karstic nature of the reservoir was identified through vertical, cored drill holes which allowed us to analyse the various solution features and the sedimentary infilling (speleothems, terra rossa, marine clays), as well as their vertical distribution. Erosion morphology at the top of the karst is highly irregular, including in particular paleovalleys as well as many pit-shaped sink holes. Detailed geophysical knowledge of that morphology helped to optimize the development of the field through horizontal drilling. Observations concerning the upper part of the reservoir were compared to a palaeokarst of the same age, outcropping widely onshore, in quarries located nearby. The Rospo Mare paleokarst is an integral part of the ante Miocene paleokarst assemblages of the periphery of the Mediterranean which were formed in tropical conditions. Only the fractures enhanced by meteoric water during the formation of the karat are important for reservoir connectivity. During the formation of the karst there were several phases of dissolution and infilling which modified the geometry of the open fissures and only these fractures play an important role in the reservoir drainage. Vertically we can distinguish three very different zones from top to bottom: at the top the epikarst (0-35 m) in a zone of extension. All the fractures have been enlarged by dissolution but the amount of infilling by clay is substantial. The clays are derived either from alteration of the karat fabric or by deposition during the Miocene transgression; the percolation zone (15-45 m) is characterized by its network of large fractures vertically enlarged by dissolution which corresponds to the relict absorption zones in the paleokarst. These fractures, which usually have a pluridecametric spacing, connect the epi-karst with the former sub-horizontal river system. This zone has been intersected by the horizontal wells during the field development. In this zone there are local, horizontal barriers oi impermeable clay which can block vertical transmissibility. In these low permeability zones the vertical fractures have not been enlarged due to dissolution hence the horizontal barrier; the zone of underground rivers (35-70 m) is characterized by numerous horizontal galleries which housed the subterranean ground water circulation. When these fissures are plurimetric in extent this can lead to gallery collapse with the associated fill by rock fall breccia. This can partly block the river system but always leaves a higher zone of free circulation with high permeabilities of several hundreds of Darcys. These galleries form along the natural fracture system relative to the paleohydraulic gradient which in some cases has been preserved. The zone below permanent ground water level with no circulation of fluids is characterized by dissolution limited to non-connected vugs. Very locally these fissures can be enlarged by tectonic fractures which are non-connected and unimportant for reservoir drainage. Laterally, only the uppermost zone can be resolved by seismic imaging linked with horizontal well data (the wells are located at the top of the percolation zone). The Rospo Mare reservoir shows three distinct horizontal zones: a relict paleokarst plateau with a high index of open connected fractures, (area around the A and B platforms); a zone bordering the plateau (to the north-east of the plateau zone) very karstified but intensely infilled by cap rock shales (Miocene - Oligocene age); a zone of intensely disturbed and irregular karst paleotopography which has been totally infilled by shales. The performance of the production wells is dependent on their position with respect to the three zones noted above and their distance from local irregularities in the karst paleotopography (dolines, paleovalleys)

We collected 43 km of high resolution seismic reflection profiles from a 14.5-hectare lake in the central Florida sinkhole district and data from three adjacent boreholes to determine the relationship between falling lake levels and the underlying karst stratigraphy. The lake is separated from karstified Paleogene to early Neogene carbonates by 65-80 m of siliciclastic sands and clays. The carbonate and clastic strata include three aquifer systems separated by clay-confining units: a surficial aquifer system (fine to medium quartz sand in the upper 20-30 m), the 25-35 m thick intermediate aquifer system (in Neogene siliciclastics), and the highly permeable upper Floridan aquifer system in Paleogene to early Neogene limestones. Hydraulic connection between these aquifer systems is indicated by superjacent karst structures throughout the section. Collapse zones of up to 1000 m in diameter and > 50 m depth extend downward from a prominent Middle Miocene unconformity into Oligocene and Upper Eocene limestones. Smaller sinkholes (30-100 m diameter, 10-25 m depth) are present in Middle to Late Neogene clays, sands, and carbonates and extend downward to or below the Middle Miocene unconformity. Filled and open shafts (30-40 m diameter; 10-25 m depth) ring the lake margin and overlie subsurface karst features. The large collapse zones are localized along a northeast-southwest line in the northern ponds and disrupt or deform Neogene to Quaternary strata and at least 50 m of the underlying Paleogene carbonate rocks. The timing and vertical distribution of karst structures are used to formulate a four-stage model that emphasizes stratigraphic and hydrogeologic co-evolution. (1) Fracture-selective shallow karst features formed on Paleogene/early Neogene carbonates. (2) Widespread karstification was limited by deposition of Middle Miocene clays, but vertical karst propagation continued and was focused because of the topographic effects of antecedent karst. (3) Groundwater heads, increase with the deposition of thick sequences of clastics over the semipermeable clays during Middle and Late Neogene time. The higher water table and groundwater heads allowed the accumulation of acidic, organic-rich soils and chemically aggressive waters that percolated down to Paleogene carbonates via localized karst features. (4) After sufficient subsurface dissolution, the Paleogene carbonates collapsed, causing disruption and deformation of overlying strata. The seismic profiles document an episodic, vertically progressive karst that allows localized vertical leakage through the clay-confining units. The spatial and temporal karst distribution is a result of deposition of sediments with different permeabilities during high sea levels and enhanced karst dissolution during low sea levels. Recent decreases in the potentiometric elevation of the Floridan Aquifer System simulates a sea-level lowstand, suggesting that karst dissolution will increase in frequency and magnitude

Ring of cenotes (sinkholes), Northwest Yucatan, Mexico; its hydrogeologic characteristics and possible association with the Chicxulub impact crater, 1995, Perry Eugene, Marin Luis E. , Mcclain Jana, Velazquez Guadalupe,
A 180-km-diameter semicircular band of abundant karst sinkholes (Ring of Cenotes) in Northwest Yucatan, Mexico, coincides approximately with a concentric ring of the buried Chicxulub structure, a circular feature manifested in Cretaceous and older rocks, that has been identified as the product of the impact of a bolide. The ring, expressed in Tertiary rocks, marks a zone of high permeability as shown by (1) the sinkholes themselves, (2) breaks in the coastal dune system and high density of springs where the ring intersects the coast, and (3) water-level transects characterized by a decline in water level toward the ring. Any direct relation that exists between the Ring of Cenotes and the Chicxulub structure bears on regional hydrogeology. If the layer or zone responsible for the ring is deeply buried, it may act as a barrier to the movement of ground water across the main flow direction. Shallower zones of horizontal permeability could result in less complete diversion of ground water. Through its influence on Yucatan aquifer characteristics, the ring may provide a link between modern environmental problems and astrogeology. Possible origins for the Ring of Cenotes are (1) faulting, perhaps reactivated by post-Eocene-mid-Miocene basin loading, (2) permeability in a buried reef complex developed in the shallow Paleocene sea around the crater rim, or (3) breccia collapse occasioned by consolidation or by solution of evaporite components. If the ring developed on ancient faults, it may outline hydrothermal systems and mineral deposits produced during Paleocene cooling of the Chicxulub melt sheet

Coastal karst aquifers have highly variable distributions of porosity and permeability. The ability to assess the volume of aquifer occupied by freshwater in coastal karst aquifers is limited by both the lack of understanding of the effect that regions of cavernous porosity and permeability have on the configuration of the saline-freshwater mixing zone and by the limited knowledge of the location of the cavernous regions. A dual-density ground-water flow and solute transport model was used to explore the effect that the depth, lateral extent, and proximity to the coast of zones of high porosity and permeability has on the configuration of the saline-freshwater mixing zone. These aquifer heterogeneities tend to shift the mixing zone upward relative to the position it would have in aquifers with homogeneous porosity and permeability, Zones of high porosity and permeability located at positions shallow in the aquifer or nearer to the coast had the greatest effect. In fact, for the conditions modeled, position was more important in modifying the configuration of the mixing zone than was changing the ratio of the intrinsic permeability of the cavernous zone to the aquifer matrix from 100 to 1000. Modeling results show that ground-water flow is concentrated into the zones of high porosity and permeability and that flow configuration results in steep salinity gradients with depth, Field observations of the location of the halocline and of step changes in ground-water composition coincident with regions of cavernous porosity in coastal karst aquifers corroborate the model results, In a coastal setting with saline water intruding into an aquifer, the effect of cavernous porosity and associated high permeability is to decrease the volume of aquifer in which freshwater occurs by a greater degree than would occur in an aquifer with homogeneous porosity and permeability

Biology of the Caves at Sinkhole Flat, Eddy County, New Mexico, 1996, Cokendolpher, J. C. , Polyak, V. J.
Quantification of limestone petrology and structure in a 25 km section of the northern Vaca Plateau, Belize, facilitated development of a model of speleogenesis and evolution of area caves and the karst landscape. The limestones in the study area are mostly depositional breccias developed between the mid-Cretaceous and mid-Tertiary adjacent to the emergent Maya Mountain Fault Block. Micritic and some fossiliferous-pelletic lithoclasts of the Cretaceous Campur Formation are cemented by sparite which formed in a shallow-sea high energy environment adjacent to the emergent area. Planes of structural weakness developed in the Campur Limestone have similar orientations to contemporary karst landform features including solution valleys, the long-axis of depressions, and cave passages. This correspondence suggests an important structural control on the formation and evolution of area caves and the karst landscape. Base level modification by way of valley incision and the development of secondary permeability enhanced interfluve development, causing caves to be truncated along valley sides and abandoned as active flow routes. The dry valleys and stair-step cave profiles indicate that the lowering of base level through time was interspersed with stable periods when horizontal cave passages were excavated.

Hydrogeological investigations in northwestern Yucatan, Mexico, using resistivity surveys, 1996, Steinich B. , Marin L. E. ,
Eight Schlumberger soundings and four Wenner anisotropy measurements were conducted in the northwestern section of the Yucatan Peninsula for hydrogeological investigations of a karst aquifer. This system is influenced by a circular high permeability zone (Ring of Cenotes) probably related to the Chicxulub Impact Crater. Schlumberger soundings and Wenner anisotropy measurements show that the karst aquifer can be modeled as an electrically anisotropic medium. Anisotropy is related to preferential permeability directions channeling ground-water flow within the aquifer. Directions of maximum permeability were determined using Wenner anisotropy measurements. Electrical soundings were conducted at different sites near the Ring of Cenotes. Resistivity values decrease toward the Ring of Cenotes supporting the hypothesis that selected segments of the Ring have high permeability. Several soundings were conducted in order to study lateral permeability variations along the Ring. A high permeability section can be identified by low resistivity models and is related to a zone of high cenote density. A low permeability section of the Ring was found showing high resistivity models. This zone overlaps with an area of low cenote density. Electrical soundings were used to determine the depth of the fresh-water lens; the interface was detected along two profiles perpendicular and parallel to the Ring of Cenotes resulting in a depth that ranged from 18 m near the coast up to 110 m in the southeastern part of the study area. The predicted depths of the interface using electrical methods showed a good correlation with Ghyben-Herzberg and measured interface depths at some sites. Discrepancies between calculated and interpreted interface depths at two sites may be explained by horizontal-to-vertical permeability anisotropy

Discussion on 'The Chalk as a karstic aquifer: evidence from a tracer test at Stanford Dingley, Berkshire, UK': Quarterly Journal of Engineering Geology, 28, S31-S38, 1996, Banks D, Davies C, Davies W,
M. Price writes: Banks et al. (1995) address the nature of the permeability of parts of the Chalk aquifer, provide useful data from a tracer test, and draw attention to the potential dangers of disposing of agricultural and road run-off to swallow holes. The paper includes a calculation of fissure conductivity and aperture from the results of the tracer test. In this it has to be emphasized that the calculations relate to Darcian flow in an equivalent smooth, plane, parallel-plate opening, not the more likely turbulent flow in a natural fissure. The true average aperture of the fissure is therefore likely to be significantly greater than that calculated (Price 1987, 1996). The situation described at Stanford Dingely is one where drainage originating from impermeable Tertiary strata flows onto the Chalk and sinks into the aquifer. The majority of active Chalk sinks appear to be of this type; the drainage sinking into them originates as run-off from other strata. Rain falling anywhere on the outcrop of the Chalk is normally able to infiltrate, so water flowing across the Chalk outcrop is almost invariably allogenic drainage or water that has infiltrated the Chalk and emerged as baseflow. Drainage to sinks is therefore a minor component of recharge to the Chalk. The tracer test undertaken into at Stanford Dingley involved introducing tracer into a known point of entry in the aquifer, and observing its arrival at a known point of emergence. Such tests almost inevitably measure the speed of groundwater movement along a ... This 250-word extract was created in the absence of an abstract

Structure et comportement hydraulique des aquifers karstiques, DSc thesis, 1996, Jeannin, P. Y.

This thesis aims to provide a better knowledge of karst flow systems, from a functional point of view (behaviour with time), as well as from a structural one (behaviour in space). The first part of the thesis deals with the hydrodynamic behaviour of karst systems, and the second part with the geometry of karstic networks, which is a strong conditioning factor for the hydrodynamic behaviour.
Many models have been developed in the past for describing the hydrodynamic behaviour of karst hydrogeological systems. They usually aim to provide a tool to extrapolate, in time and/or space, some characteristics of the flow fields, which can only be measured at a few points. Such models often provide a new understanding of the systems, beyond what can be observed directly in the field. Only special field measurements can verify such hypotheses based on numerical models. This is an significant part of this work. For this purpose, two experimental sites have been equipped and measured: Bure site or Milandrine, Ajoie, Switzerland, and Holloch site, Muotathal, Schwyz, Switzerland. These sites gave us this opportunity of simultaneously observe hydrodynamic parameters within the conduit network and, in drillholes, the "low permeability volumes" (LPV) surrounding the conduits.
These observations clearly show the existence of a flow circulation across the low permeability volumes. This flow may represent about 50% of the infiltrated water in the Bure test-field. The epikarst appears to play an important role into the allotment of the infiltrated waters: Part of the infiltrated water is stored at the bottom of the epikarst and slowly flows through the low permeability volumes (LPV) contributing to base flow. When infiltration is significant enough the other part of the water exceeds the storage capacity and flows quickly into the conduit network (quick flow).
For the phreatic zone, observations and models show that the following scheme is adequate to describe the flow behaviour: a network of high permeability conduits, of tow volume, leading to the spring, is surrounded by a large volume of low permeability fissured rock (LPV), which is hydraulically connected to the conduits. Due to the strong difference in hydraulic conductivity between conduits and LPV, hydraulic heads and their variations in time and space are strongly heterogeneous. This makes the use of piezometric maps in karst very questionable.
Flow in LPV can be considered as similar to flow in fractured rocks (laminar flow within joints and joints intersections). At a catchment scale, they can be effectively considered as an equivalent porous media with a hydraulic conductivity of about 10-6 to 10-7 m/s.
Flow in conduits is turbulent and loss of head has to be calculated with appropriate formulas, if wanting any quantitative results. Our observations permitted us to determine the turbulent hydraulic conductivity of some simple karst conduits (k', turbulent flow), which ranges from 0.2 to 11 m/s. Examples also show that the structure of the conduit network plays a significant role on the spatial distribution of hydraulic heads. Particularity hydraulic transmissivity of the aquifer varies with respect to hydrological conditions, because of the presence of overflow conduits located within the epiphreatic zone. This makes the relation between head and discharge not quadratic as would be expected from a (too) simple model (with only one single conduit). The model applied to the downstream part of Holloch is a good illustration of this phenomena.
The flow velocity strongly varies along the length of karst conduits, as shown by tracer experiments. Also, changes in the conduit cross-section produce changes in the (tow velocity profile. Such heterogeneous flow-field plays a significant role in the shape of the breakthrough curves of tracer experiments. It is empirically demonstrated that conduit enlargements induce retardation of the breakthrough curve. If there are several enlargements one after the other, an increase of the apparent dispersivity will result, although no diffusion with the rock matrix or immobile water is present. This produces a scale effect (increase of the apparent dispersivity with observation scale). Such observations can easily be simulated by deterministic and/or black box models.
The structure of karst conduit networks, especially within the phreatic zone, plays an important role not only on the spatial distribution of the hydraulic heads in the conduits themselves, but in the LPV as well. Study of the network geometry is therefore useful for assessing the shape of the flow systems. We further suggest that any hydrogeological study aiming to assess the major characteristics of a flow system should start with a preliminary estimation of the conduit network geometry. Theories and examples presented show that the geometry of karst conduits mainly depends on boundary conditions and the permeability field at the initial stage of the karst genesis. The most significant boundary conditions are: the geometry of the impervious boundaries, infiltration and exfiltration conditions (spring). The initial permeability field is mainly determined by discontinuities (fractures and bedding planes). Today's knowledge allows us to approximate the geometry of a karst network by studying these parameters (impervious boundaries, infiltration, exfiltration, discontinuity field). Analogs and recently developed numerical models help to qualitatively evaluate the sensitivity of the geometry to these parameters. Within the near future, new numerical tools will be developed and will help more closely to address this difficult problem. This development will only be possible if speleological networks can be sufficiently explored and used to calibrate models. Images provided by speleologists to date are and will for a long time be the only data which can adequately portray the conduit networks in karst systems. This is helpful to hydrogeologists. The reason that we present the example of the Lake Thun karst system is that it illustrates the geometry of such conduits networks. Unfortunately, these networks are three-dimensional and their visualisation on paper (2 dimensions) is very restrictive, when compared to more effective 3-D views we can create with computers. As an alternative to deterministic models of speleogenesis, fractal and/or random walk models could be employed.

Initial Geologic Observations in Caves Bordering the Sibari Plain (Southern Italy), 1997, Galdenzi, S.
Geologic investigation of caves in the northern Calabria region of Italy has clarified their origin and irregular distribution. Caves and surface karst landforms are not widespread, despite the fact that the local limestones are widely exposed and surface drainage is poorly developed. The caves are located in small limestone hills and mountains around the Sibari Plain and are surrounded by low-permeability rocks. Among them is a significant shaft cave fed by a sinking stream that drains a non-karst recharge area. However, most of the caves are predominantly horizontal and have entrances at low altitudes at several levels. Their origin is due to the rising of thermal waters, which are mineralized after passing through the Neogene formations of the Sibari Plain. The caves can be considered relict hypogenic outflow caves. The main cave-forming process was probably the oxidation of H2S, favored by the mixing of thermal water and infiltrating fresh water. Oxidation of H2S has resulted in gypsum deposits within the caves.

Geological features, permeability and groutability characteristics of the Zimapan Dam Foundation, Hidalgo State, Mexico, 1997, Foyo A, Tomillo C, Maycotte Ji, Willis P,
The geology of the Zimapan Dam foundation has a significant influence on the permeability and groutability characteristics. The dam foundation is composed of a sequence of dolomitic limestones and dolomitic breccia of the late Jurassic period. Karst phenomena contribute the main structural features. In this paper the relationships between the karstic features and the permeability characteristics of the Zimapan Dam foundation have been evaluated. A modification of the low pressure test (Foyo and Cerda, 1990) for analyzing the permeability characteristics was carried out. This type of permeability test permits the determination of the critical pressure and the analysis of the differences between the critical manometric pressures and the real critical pressures induced during the test performance. Permeability and hydrofracture tests results were used in the foundation for the design of the grouting programme, and the karstic features of the formation were grouted using a special treatment process. The relationships between the permeability and the grouting results have been analyzed

Geology, geochemistry, and origin of the continental karst-hosted supergene manganese deposits in the western Rhodope massif, Macedonia, northern Greece, 1997, Nimfopoulos M. K. , Pattrick R. A. D. , Michailidis K. M. , Polya D. A. , Esson J. ,
Economic Mn-oxide ore deposits of commercial grade occur in the Rhodope massif near Kato Nevrokopi in the Drama region, Northern Greece. The Mn-oxide mineralization has developed by weathering of continental hypogene rhodochrosite-sulphide veins. The vein mineralization is confined by tectonic shear zones between marble and metapelites, extending laterally into the marble as tabular, pod or lenticular oreshoots (up to 50 m x 20 m x 5-10 m). Supergene oxidation of the hypogene mineralization led to the formation of in-situ residual Mn-oxide ore deposits, and secondary infills of Mn-oxide ore in embryonic and well developed karst cavities. Whole rock geochemical profiles across mineralized zones confirm the role of thrusts and faults as solution passageways and stress the importance of these structures in the development of hydrothermal and supergene mineralization at Kato Nevrokopi. Three zones an recognized in the insitu supergene veins: (A) a stable zone of oxidation, where immobile elements form (or substitute in) stable oxide mineral phases, and mobile elements are leached; (B) a transitional (active) zone in which element behavior is strongly influenced by seasonal fluctuations of the groundwater table and variations in pH-Eh conditions; and (C) a zone of permanent flooding, where variations in pH-Eh conditions are minimal. Zone (B) is considered as the source zone for the karst cavity mineralization. During weathering, meteoric waters, which were CO2-rich (P-CO2 similar to 10(-3.8) to 10(-1.4)) and oxygenated (fO(2) -10(-17) for malachite), percolated downward within the veins, causing breakdown and dissolution of sulfides and marble, and oxidation of rhodochrosite to Mn-oxides. Karat cavity formation was favored by the high permeability along thrust zones. Dissolved Mn2 was transported into karst cavities in reduced meteoric waters at the beginning of weathering (pH similar to 4-5), and as Mn(HCO3)(2) in slightly alkaline groundwaters during advanced weathering (pH similar to 6-8). Mn4? precipitation took place by fO(2) increase in ground waters, or pH increase by continuous hydrolysis and carbonate dissolution. In the well developed karst setting, some mobility of elements occurred during and after karst ore formation in the order Na>K>Mg>Sr>Mn>As>Zn>Ba>Al>Fe>Cu>Cd>Pb. (C) 1998 Canadian Institute of Mining, Metallurgy and Petrolem. Published by Elsevier Science Ltd. All rights reserved

Geochemical patterns in soils of the karst region, Croatia, 1997, Prohic E. , Hausberger G. , Davis J. C. ,
Soil samples were collected at 420 locations in a 5-km grid pattern in the Istria and Gorski Kotar areas of Croatia, and on the Croatian islands of Cres, Rab and Krk, in order to relate geochemical variation in the soils to underlying differences in geology, bedrock lithology, soil type, environment and natural versus anthropogenic influences. Specific objectives included assessment of possible agricultural and industrial sources of contamination, especially from airborne effluent emitted by a local power plant. The study also tested the adequacy of a fixed-depth soil sampling procedure developed for meager karstic soils. Although 40 geochemical variables were analyzed, only 15 elements and 5 radionuclides are common to all the sample locations. These elements can be divided into three groups: (1) those of mostly anthropogenic origin - Pb, V, Cu and Cr; (2) those of mixed origin - radionuclides and Zn; and (3) those of mostly geogene origin - Ba, Sr, Ti, Al, Na, Ca, Mg, Fe, Mn, Ni and Co. Variation in Pb shows a strong correlation with the pattern of road traffic in Istria. The distributions of Ca, Na and Mg in the flysch basins of southern Istria and Slovenia are clearly distinguishable from the distributions of these elements in the surrounding carbonate terrains, a consequence of differences in bedrock permeability, type of drainage and pH. The spatial pattern of Cs-137 from the Chernobyl nuclear power plant accident reflects almost exclusively the precipitation in Istria during the days immediately after the explosion. (C) 1997 Elsevier Science B.V

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