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Enviroscan Ukrainian Institute of Speleology and Karstology

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Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That bedeckter karst is see covered karst.?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

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KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
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Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
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Your search for brine (Keyword) returned 57 results for the whole karstbase:
Showing 46 to 57 of 57
Potential environmental issues of C02 storage in deep saline aquifers: Geochemical results from the Frio-1 Brine Pilot test, Texas, USA, 2009,
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Kharaka Y. K. , Thordsena J. , Hovorkab S. D. , Nanceb H. S. , Colee D. R. , Phelps T. J. , Knauss K. G.

Sedimentary basins in general, and deep saline aquifers in particular, are being investigated as possible repositories for large volumes of anthropogenic C02 that must be sequestered to mitigate global wanning and related climate changes. To investigate the potential for the long-term storage of C02 in such aquifers, 1600 t of C02 were injected at 1500 m depth into a 24-m-thick "C" sandstone unit of the Frio Formation, a regional aquifer in the US Gulf Coast Fluid samples obtained before C02 injection from the injection well and an observation well 30 m updip showed a Na-ca-a type brine with ~93,000 mg/L IDS at saturation with CH.t at reservoir conditions; gas analyses showed that CH.t comprised ~95% of dissolved gas, but C02 was low at 0.3%. Following C02 breakthrough, 51 h after injection, samples showed sharp drops in pH (6.5-5.7), pronounced increases in alkalinity (100-3000 mgfL as HC03) and in Fe (30-1100 mgfL), a slug of very high DOC values, and significant shifts in the isotopic compositions of H20, DIC, and CH.t. These data, coupled with geochemical modeling, indicate corrosion of pipe and well casing as well as rapid dissolution of minerals, especially calcite and iron oxyhydroxides, both caused by lowered pH (initially ~3.0 at subsurface conditions) of the brine in contact with supercritical C~. These geochemical parameters, together with perfluorocarbon tracer gases (PFrs), were used to monitor migration of the injected C02 into the overlying Frio "B", composed of a 4-m-thick sandstone and separated from the "C" by ~ts m of shale and siltstone beds. Results obtained from the Frio "B" 6 months after injection gave chemical and isotopic markers that show significant ~ (2.9% compared with 0.3% C02 in dissolved gas) migration into the "B" sandstone. Results of samples collected 15 months after injection, however, are ambiguous, and can be interpreted to show no additional injected C02 in the "B" sandstone. The presence of injected C02 may indicate migration from "C" to "B" through the intervening beds or, more likely, a short-term leakage through the remedial cement around the casing of a 50-year old well. Results obtained to date from four shallow monitoring groundwater wells show no brine or C02 leakage through the Anahuac Formation, the regional cap rock.

Conceptual modelling of brine flow into aquifers adjacent to the Konarsiah salt diapir, Iran, 2010,
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Zarei Mehdi, Raeisi Ezzat

The Konarsiah salt diapir is located in the Simply Folded Zone of the Zagros Mountain, south Iran. Salt,extruding from two vents along a fault, spreads downslope as a salt glacier over the adjacent formations. Eight small permanent brine springs emerge from the Konarsiah salt body, with average total dissolved solids of 327.3 g/L. The diapir is in direct contact with several aquifers, namely, the karstic Eastern and Western Sarvak, karstic Eastern Asmari, Firouzabad, Konarsiah Plain and Shour. It is also surrounded by a number of impermeable formations. The springs and seepage sections emerging from the aquifers adjacent to the diapir are unexpectedly saline or brackish. Electrical conductivity, total dissolved solids, flow rate, temperature and major ion concentrations were measured monthly from September 2007 to August 2008 at 37 sampling sites, including springs, surface waters, boreholes and wells.
The study indicates that the source of salinity of the adjacent aquifers is halite dissolution of the diapir. Conceptual models of groundwater flow are proposed for the adjacent karst aquifers based on the geological setting, water budget, local base of erosion, isotope data and the profile of the water table. The share of the diapir brine in the Eastern Sarvak aquifer, the Western aquifers (Sarvak, Asmari and Shour) and Konarsiah Plain are 1.8 L/s, 0.8 L/s and 9.1 L/s, respectively. Most of this brine ultimately releases into the Firouzabad River and changes the TDS of this river from 9.21 g/L to 11.61 g/L.
To drain the brine flowing into the Eastern Sarvak aquifer and hence reduce the aquifer's salinity it might be feasible to construct a qanat (a man-made underground gallery transferring groundwater to the surface by gravity) at the aquifer's contact with the Konarsiah diapir. To exploit the fresh karst water of the Western Sarvak aquifer before it is contaminated by the Konarsiah brine, several wells could be constructed well away from the diapir.

Secondary halite deposits in the Iranian salt karst: general description and origin, 2011,
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Filippi Michal, Bruthans Jiř, , Palatinus Luk, Zare Mohammad, Asadi Naser

This paper summaries 12 years of documentation of secondary halite deposits in the Iranian salt karst.
A variety of secondary halite deposits was distinguished and classified into several groups, on the basis of the site and mechanism of their origin. Deposits formed: i) via crystallization in/on streams and pools, ii) from dripping, splashing and aerosol water, iii) from evaporation of seepage and capillary water, and iv) other types of deposits. The following examples of halite forms were distinguished in each of the above mentioned group: i) euhedral crystals, floating rafts (raft cones), thin brine surface crusts and films; ii) straw stalactites, macrocrystalline skeletal and hyaline deposits, aerosol deposits; iii) microcrystalline forms (crusts, stalactites and stalagmites, helictites); iv) macrocrystalline helictites, halite bottom fibres and spiders, crystals in fluvial sediments, euhedral halite crystals in rock salt, combined or transient forms and biologically induced deposits. The occurrence of particular forms depends strongly on the environment, especially on the type of brine occurrence (pool, drip, splashing brine, microscopic capillary brine, etc.), flow rate and its variation, atmospheric humidity, evaporation rate and, in some cases, on the air flow direction. Combined or transitional secondary deposits can be observed if the conditions changed during the deposition. Euhedral halite crystals originate solely below the brine surface of supersaturated streams and lakes. Macrocrystalline skeletal deposits occur at places with rich irregular dripping and splashing (i.e., waterfalls, places with strong dripping from the cave ceilings, etc.). Microcrystalline (fine grained) deposits are generated by evaporation of capillary brine at places where brine is not present in a macroscopically visible form. Straw stalactites form at places where dripping is concentrated in small spots and is frequent sufficient to assure that the tip of the stalactite will not be overgrown by halite precipitates. If the tip is blocked by halite precipitates, the brine remaining in the straw will seep through the walls and helictites start to grow in some places.
Macrocrystalline skeletal deposits and straw stalactites usually grow after a major rain event when dripping is strong, while microcrystalline speleothems are formed continuously during much longer periods and ultimately (usually) overgrow the other types of speleothems during dry periods. The rate of secondary halite deposition is much faster compared to the carbonate karst. Some forms increase more than 0.5 m during the first year after a strong rain event; however, the age of speleothems is difficult to estimate, as they are often combinations of segments of various ages and growth periods alternate with long intervals of inactivity.
Described forms may be considered in many cases as the analogues of forms found in the carbonate karst. As they are created in a short time period the conditions of their origin are often still visible or can be reconstructed. The described halite forms can thus be used for verification of the origin of various carbonate forms. Some of the described forms bear clear evidence of the paleo-water surface level (transition of the skeletal form to halite crystals and vice versa). Other kinds of deposits are potential indicators of the microclimate under which they developed (humidity close to the deliquescence relative humidity).

Geochemical/isotopic evolution of Pb-Zn deposits in the Central and Eastern Taurides, Turkey, 2011,
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Hanilci N. , Ozturk H.

The Central and Eastern Taurides contain numerous carbonate-hosted Pb-Zn deposits, mainly in Devonian and Permian dolomitized reefal-stramatolitic limestones, and in massive Jurassic limestones. We present and compare new fluid inclusion and isotopic data from these ore deposits, and propose for the first time a Mississippi Valley-type (MVT) mode of origin for them. Fluid inclusion studies reveal that the ore fluids were highly saline (13-26% NaCl equiv.), chloride-rich (CaCl2) brines, and have average homogenization temperatures of 112°C, 174.5°C, and 211°C for the Celal Dag, Delikkaya, and Ayrakl deposits, respectively. Furthermore, the ?34S values of carbonate-hosted Pb-Zn deposits in the Central and Eastern Taurides vary between -5.4‰ and +13.70‰. This indicates a possible source of sulphur from both organic compounds and crustal materials. In contrast, stable sulphur isotope data (average ?34S -0.15‰) for the Cadrkaya deposit, which is related to a late Eocene-Oligocene (?) granodioritic intrusion, indicates a magmatic source. The lead isotope ratios of galena for all investigated deposits are heterogeneous. In particular, with the exception of the Sucat district, all deposits in the Eastern (Delikkaya, Ayrakl, Denizovas, Cadrkaya) and Central (Katranbasi, Kucuksu) Taurides have high radiogenic lead isotope values (206Pb/204Pb between 19.058 and 18.622; 207Pb/204Pb between 16.058 and 15.568; and 208Pb/204Pb between 39.869 and 38.748), typical of the upper continental crust and orogenic belts. Fluid inclusion, stable sulphur, and radiogenic lead isotope studies indicate that carbonate-hosted metal deposits in the Eastern (except for the Cadrkaya deposit) and the Central Taurides are similar to MVT Pb-Zn deposits described elsewhere. The primary MVT deposits are associated with the Late Cretaceous-Palaeocene closure of the Tethyan Ocean, and formed during the transition from an extensional to a compressional regime. Palaeogene nappes that typically limit the exposure of ore bodies indicate a pre-Palaeocene age of ore formation. Host rock lithology, ore mineralogy, fluid inclusion, and sulphur + lead isotope data indicate that the metals were most probably leached from a crustal source such as clastic rocks or a crystalline massif, and transported by chloride-rich hydrothermal solutions to the site of deposition. Localization of the ore deposits on autochthonous basement highs indicates long-term basinal fluid migration, characteristic of MVT depositional processes. The primary MVT ores were oxidized in the Miocene, resulting in deposition of Zn-carbonate and Pb-sulphate-carbonate during karstification. The ores underwent multiple cycles of oxidation and, in places, were re-deposited to form clastic deposits. Modified deposits resemble the 'wall-rock replacement' and the 'residual and karst fill' of non-sulphide zinc deposits and are predominantly composed of smithsonite

In defense of a fluctuating-interface, particle-accretion origin of folia, 2012,
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Davis Donald G.

Two recent papers have proposed radically different modes of origin for cave folia. Audra et al. (2009) propose subaqueous origin of carbonate folia via hypogenic CO2 bubble trapping, with concurrent condensation-corrosion and evaporative precipitation within individual folia gas pockets. Queen (2009) proposes that at least some folia are analogous to suboceanic tufa-tower “flanges” and may result from subaqueous freshwater mixing into a briny environment. The purpose of this paper is to show that neither of these mechanisms can be the fundamental process responsible for folia morphology in cave deposits, and that accretion from adherent particles at fluctuating interfaces is the only mechanism that has been shown to apply to folia of all compositions and in all cave environments where they are known to occur.

Electrical resistivity surveys of anthropogenic karst phenomena, southeastern New Mexico, 2012,
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Land L. , Veni G.

A small but significant number of sinkholes and other karst phenomena in southeastern New Mexico are of human origin and are often associated with solution mining of salt beds in the shallow subsurface. In 2008 two brine wells in a sparsely populated area of northern Eddy County, New Mexico, abruptly collapsed as a result of solution mining operations. The well operators had been injecting fresh water into underlying salt beds and pumping out brine for use as oil field drilling fluid. A third brine well within the city limits of Carlsbad, New Mexico, has been shut down to forestall possible sinkhole development in this more densely populated area. Electrical resistivity surveys conducted over the site of the brine well confirm the presence of a large, brine-filled cavity beneath the we0llhead. Laterally extensive zones of low resistivity beneath the well site represent either open cavities and conduits caused by solution mining or highly fractured and/or brecciated, brine-saturated intervals that may have formed by sagging and collapse into underlying cavities. The data also indicate that significant upward stoping has occurred into overlying strata.

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Florea Lee J.


This manuscript offers preliminary geochemical evidence that investigates the potential for hypogene speleogenesis in the Cumberland Plateau of southeastern Kentucky, U.S.A. The region was traditionally considered a classic example of epigenic karst, but new insights have uncovered tantalizing observations that suggest alternatives to simple carbonic acid speleogenesis. Such first-order observations have included natural petroleum seeps at the surface and in caves, occasional cave morphologies consistent with action of hypogene fluids, and prolific gypsum within cave passages. To this point, geochemical data from caves and springs verify carbonic acid as the primary dissolutional agent; however, these same analyses cannot rule out sulfuric acid as a secondary source of dissolution. In this paper, Principal Component Analysis of ionic data reveals two components that coordinate with parameters associated with “karst water” and shallow brine. In contrast, molar ratios of Ca+ and Mg+ as compared to HCO3 - and SO4 2- closely follow the reaction pathway stipulated by the carbonate equilibria reactions. Despite these data, the role, if any, of hypogene speleogenesis in the karst of the Cumberland Plateau remains inconclusive. It is very likely that carbonic acid dominates speleogenesis; however, contributions from sulfuric acid may influence our understanding of “inception” and carbon flux within these aquifers.

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Land, Lewis

A significant minority of sinkholes in the greater Permian Basin region of west Texas and southeastern New Mexico are of human origin. These anthropogenic sinkholes are often associated with historic oil field activity, or with solution mining of Permian salt beds in the shallow subsurface. The well-known Wink Sinks in Winkler Co., Texas formed in 1980 and 2002 within the giant Hendrick oil field. The Wink Sinks were probably the result of subsurface dissolution of salt caused by fresh water leakage in improperly cased abandoned oil wells. In 2008 two catastrophic sinkhole events occurred a few months apart in northern Eddy Co., New Mexico, and a third formed a few months later in 2009 near Denver City, Texas. All three sinkholes were the result of solution mining operations for brine production from Upper Permian salt beds. The Eddy Co. sinkholes formed within the giant Empire oil and gas field, several kilometers from populated areas. In the aftermath of these events, another brine well operation was identified within the city limits of Carlsbad, New Mexico as having a similar geologic setting and pumping history. That well has been abandoned and geotechnical monitoring of the site has been continuous since 2008. Although there is no indication of imminent collapse, geophysical surveys have identified a substantial void in Permian salt beds beneath the brine well extending north and south beneath residential areas, a major highway intersection, a railroad, and an irrigation canal

Isotopes of Carbon in a Karst Aquifer of the Cumberland Plateau of Kentucky, USA, 2013,
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Florea Lee J.

In this study, the concentration and isotopic composition of dissolved organic carbon (DOC) and dissolved inorganic carbon (DIC) are measured in the karst groundwater of the Otter Creek watershed of the Cumberland Plateau of Kentucky, USA. Comparisons among these data and with the geochemistry of carbonate and gypsum equilibrium reactions reveal that DOC concentration is inversely related to discharge, multiple reaction pathways provide DIC with isotopic enrichment that may be directly related to mineral saturation, and oxidation of reduced sulfur is possible for dissolution. DOC is derived from C3 vegetation with an average δ13C DOC of ‒27‰. DIC in groundwater is derived from both pedogenic CO2  and HCO3 - from dissolved carbonate. At input sites to the karst aquifers DIC concentrations are expectedly low, less than 1 mmol/L, in waters that are undersaturated with respect to calcite. At the output of these karst aquifers DIC concentrations reach 3 mmol/L in waters that are at or above calcite saturation. Values of δ13C DIC range between ‒6.3 and ‒12.4‰ with CO2 degassing and calcite precipitation at some sites obfuscating a simple relationship between δ13C DIC, discharge, and mineral saturation. In addition, concentrations of DIC in sulfur seeps within the watershed range between 2–7 mmol/L with δ13C DIC values in some samples skewed more toward the anticipated value of carbonate bedrock than would be expected from reactions with carbonic acid alone. This suggests that the oxidation of reduced sulfur from shallow oilfield brines liberates bedrock DIC through reactions with sulfuric acid.

Permeability evolution due to dissolution and precipitation of carbonates using reactive transport modeling in pore networks, 2013,
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A reactive transport model was developed to simulate reaction of carbonates within a pore network for the high-pressure CO2-acidified conditions relevant to geological carbon sequestration. The pore network was based on a synthetic oolithic dolostone. Simulation results produced insights that can inform continuum-scale models regarding reactioninduced changes in permeability and porosity. As expected, permeability increased extensively with dissolution caused by high concentrations of carbonic acid, but neither pH nor calcite saturation state alone was a good predictor of the effects, as may sometimes be the case. Complex temporal evolutions of interstitial brine chemistry and network structure led to the counterintuitive finding that a far-from-equilibrium solution produced less permeability change than a nearer-to-equilibrium solution at the same pH. This was explained by the pH buffering that increased carbonate ion concentration and inhibited further reaction. Simulations of different flow conditions produced a nonunique set of permeability-porosity relationships. Diffusive-dominated systems caused dissolution to be localized near the inlet, leading to substantial porosity change but relatively small permeability change. For the same extent of porosity change caused from advective transport, the domain changed uniformly, leading to a large permeability change. Regarding precipitation, permeability changes happen much slower compared to dissolution-induced changes and small amounts of precipitation, even if located only near the inlet, can lead to large changes in permeability. Exponent values for a power law that relates changes in permeability and porosity ranged from 2 to 10, but a value of 6 held constant when conditions led to uniform changes throughout the domain

Karstification of Dolomitic Hills at south of Coimbra (western-central Portugal) - Depositional facies and stratigraphic controls of the (palaeo)karst affecting the Coimbra Group (Lower Jurassic), 2014,
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Dimuccio, Luca Antonio

An evolutionary model is proposed to explain the spatio-temporal distribution of karstification affecting the Lower Jurassic shallow-marine carbonate succession (Coimbra Group) of the Lusitanian Basin, cropping out in the Coimbra-Penela region (western-central Portugal), in a specific morphostructural setting (Dolomitic Hills). Indeed, in the Coimbra Group, despite the local lateral and vertical distributions of dolomitic character and the presence of few thick sandy-argillaceous/shale and marly interbeds, some (meso)karstification was identified, including several microkarstification features. All types of karst forms are commonly filled by autochthonous and/or allochthonous post-Jurassic siliciclastics, implying a palaeokarstic nature.

The main aim of this work is to infer the interplay between depositional facies, diagenesis, syn- and postdepositional discontinuities and the spatio-temporal distribution of palaeokarst. Here, the palaeokarst concept is not limited to the definition of a landform and/or possibly to an associated deposit (both resulting from one or more processes/mechanisms), but is considered as part of the local and regional geological record.

Detailed field information from 21 stratigraphic sections (among several dozens of other observations) and from structural-geology and geomorphological surveys, was mapped and recorded on graphic logs showing the lithological succession, including sedimentological, palaeontological and structural data. Facies determination was based on field observations of textures and sedimentary structures and laboratory petrographic analysis of thin-sections. The karst and palaeokarst forms (both superficial and underground) were classified and judged on the basis of present-day geographic location, morphology, associated discontinuities, stratigraphic position and degree of burial by post-Jurassic siliciclastics that allowed to distinguish a exposed karst (denuded or completely exhumed) than a palaeokarst (covered or partially buried).

A formal lithostratigrafic framework was proposed for the local ca. 110-m-thick combined successions of Coimbra Group, ranging in age from the early Sinemurian to the early Pliensbachian and recorded in two distinct subunits: the Coimbra formation, essentially dolomitic; and the overlying S. Miguel formation, essentially dolomitic-limestone and marly-limestone.

The 15 identified facies were subsequently grouped into 4 genetically related facies associations indicative of sedimentation within supra/intertidal, shallow partially restricted subtidal-lagoonal, shoal and more open-marine (sub)environments - in the context of depositional systems of a tidal flat and a very shallow, inner part of a low-gradient, carbonate ramp. In some cases, thick bedded breccia bodies (tempestites/sismites) are associated to synsedimentary deformation structures (slumps, sliding to the W to NW), showing the important activity of N–S and NNE–SSW faults, during the Sinemurian. All these deposits are arranged into metre-scale, mostly shallowing-upward cycles, in some cases truncated by subaerial exposure events. However, no evidence of mature pedogenetic alteration, or the development of distinct soil horizons, was observed. These facts reflect very short-term subaerial exposure intervals (intermittent/ephemeral), in a semiarid palaeoclimatic setting but with an increase in the humidity conditions during the eogenetic stage of the Coimbra Group, which may have promoted the development of micropalaeokarstic dissolution (eogenetic karst).

Two types of dolomitization are recognized: one (a) syndepositional (or early diagenetic), massive-stratiform, of “penesaline type”, possibly resulting from refluxing brines (shallow-subtidal), with a primary dolomite related to the evaporation of seawater, under semiarid conditions (supra/intertidal) and the concurrent action of microbial activity; another (b) later, localized, common during diagenesis (sometimes with dedolomitization), particularly where fluids followed discontinuities such as joints, faults, bedding planes and, in some cases, pre-existing palaeokarstic features.

The very specific stratigraphic position of the (palaeo)karst features is understood as a consequence of high facies/microfacies heterogeneities and contrasts in porosity (both depositional and its early diagenetic modifications), providing efficient hydraulic circulation through the development of meso- and macropermeability contributed by syn- and postdepositional discontinuities such as bedding planes, joints and faults. These hydraulic connections significantly influenced and controlled the earliest karst-forming processes (inception), as well as the degree of subsequent karstification during the mesogenetic/telogenetic stages of the Coimbra Group. Multiple and complex karstification (polyphase and polygenic) were recognized, including 8 main phases, to local scale, integrated in 4 periods, to regional scale: Jurassic, Lower Cretaceous, pre-Pliocene and Pliocene-Quaternary. Each phase of karstification comprise a specific type of (palaeo)karst (eogenetic, subjacent, denuded, mantled-buried and exhumed).

Finally, geological, geomorphological and hydrogeological characteristics allowed to describe the local aquifer. The elaborated map of intrinsic vulnerability shows a karst/fissured and partially buried aquifer (palaeokarst) with high to very high susceptibility to the contamination.

Influence of the f low rate on dissolution and precipitation features during percolation of CO 2 - rich sulfate solutions through fractured limestone samples , 2015,
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Calcited issolution and  gypsum precipitation is expected to occur  when injecting CO2  in  a limestone reservoir with sulfate - rich resident brine. If the reservoir is fractured, These reactions will take place mainly in the fractures, which serve as preferential paths for fluid  flow. As a consequence, the geometry of the fractures will vary leading to changes  in their hydraulic and transport properties. In this study, a set of percolation  experiments  which  consisted of injecting CO 2 - rich solutions through fractured  limestone  cores were performed under P  =  150 bar and  T  =  60  ºC .  Flow rate s ranging from 0.2 to 60 mL/ h and sulfate - rich and sulfate - free solutions  were used. Variation in fracture volume induced by calcite dissolution and  gypsum precipitation was measured by X - ray computed microtomography  (XCMT) and aqueous chemistry. An increase in flow rate led to  an increase in  volume of dissolved limestone per unit of  time , which indicated that the calcite dissolution rate in the fracture  was transport  controlled. Moreover, the dissolution pattern varied from face dissolution to wormhole formation  and uniform dissolution by increasing the flow rate (i.e.,  Pefrom 1 to 346 ). Fracture permeability always increased and depended on the type of dissolution pattern.

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