MWH Global

Enviroscan Ukrainian Institute of Speleology and Karstology

Community news

Speleology in Kazakhstan

Shakalov on 04 Jul, 2018
Hello everyone!   I pleased to invite you to the official site of Central Asian Karstic-Speleological commission ("Kaspeko")   There, we regularly publish reports about our expeditions, articles and reports on speleotopics, lecture course for instructors, photos etc. ...

New publications on hypogene speleogenesis

Klimchouk on 26 Mar, 2012
Dear Colleagues, This is to draw your attention to several recent publications added to KarstBase, relevant to hypogenic karst/speleogenesis: Corrosion of limestone tablets in sulfidic ground-water: measurements and speleogenetic implications Galdenzi,

The deepest terrestrial animal

Klimchouk on 23 Feb, 2012
A recent publication of Spanish researchers describes the biology of Krubera Cave, including the deepest terrestrial animal ever found: Jordana, Rafael; Baquero, Enrique; Reboleira, Sofía and Sendra, Alberto. ...

Caves - landscapes without light

akop on 05 Feb, 2012
Exhibition dedicated to caves is taking place in the Vienna Natural History Museum   The exhibition at the Natural History Museum presents the surprising variety of caves and cave formations such as stalactites and various crystals. ...

Did you know?

That interface is 1. the contact zone between two materials of different chemical or physical composition [22]. 2. the contact plane of two immiscible liquids [16].?

Checkout all 2699 terms in the KarstBase Glossary of Karst and Cave Terms

What is Karstbase?

Search KARSTBASE:

keyword
author

Browse Speleogenesis Issues:

KarstBase a bibliography database in karst and cave science.

Featured articles from Cave & Karst Science Journals
Chemistry and Karst, White, William B.
See all featured articles
Featured articles from other Geoscience Journals
Karst environment, Culver D.C.
Mushroom Speleothems: Stromatolites That Formed in the Absence of Phototrophs, Bontognali, Tomaso R.R.; D’Angeli Ilenia M.; Tisato, Nicola; Vasconcelos, Crisogono; Bernasconi, Stefano M.; Gonzales, Esteban R. G.; De Waele, Jo
Calculating flux to predict future cave radon concentrations, Rowberry, Matt; Marti, Xavi; Frontera, Carlos; Van De Wiel, Marco; Briestensky, Milos
Microbial mediation of complex subterranean mineral structures, Tirato, Nicola; Torriano, Stefano F.F;, Monteux, Sylvain; Sauro, Francesco; De Waele, Jo; Lavagna, Maria Luisa; D’Angeli, Ilenia Maria; Chailloux, Daniel; Renda, Michel; Eglinton, Timothy I.; Bontognali, Tomaso Renzo Rezio
Evidence of a plate-wide tectonic pressure pulse provided by extensometric monitoring in the Balkan Mountains (Bulgaria), Briestensky, Milos; Rowberry, Matt; Stemberk, Josef; Stefanov, Petar; Vozar, Jozef; Sebela, Stanka; Petro, Lubomir; Bella, Pavel; Gaal, Ludovit; Ormukov, Cholponbek;
See all featured articles from other geoscience journals

Search in KarstBase

Your search for carbonate (Keyword) returned 1215 results for the whole karstbase:
Showing 1201 to 1215 of 1215
The hydrogeology of high-mountain carbonate areas: an example of some Alpine systems in southern Piedmont (Italy), 2015,

The hydrogeological characteristics of some springs supplied by high-mountain carbonate rock aquifers, located in the south of Piedmont, in Italy, are presented in this work. The aquifers have different geological-structural conditions, including both deep and superficial karstification. Their catchment areas are located in a typical Alpine context at a high altitude of about 2000 m. These aquifers are ideal representations of the different hydrogeological situations that can be encountered in the high-altitude carbonate aquifers of the Mediterranean basin. It is first shown how the high-altitude zones present typical situations, in particular related to the climate, which control the infiltration processes to a great extent. Snowfall accumulates on the ground from November to April, often reaching remarkable thicknesses. The snow usually begins to melt in spring and continues to feed the aquifer for several months. This type of recharge is characterized by continuous daily variations caused by the typical thermal excursions. The hourly values are somewhat modest, but snowmelt lasts for a long time, beginning in the lower sectors and ending, after various months, in the higher areas. Abundant rainfall also occurs in the same period, and this contributes further to the aquifer supply. In the summer period, there is very little rainfall, but frequent storms. In autumn, abundant rainfall occurs and there are there fore short but relevant recharge events. It has been shown how the trend of the yearly flow of the high mountain springs is influenced to a great extent by the snowmelt processes and autumn rainfall. It has also been shown, by means of the annual hydrographs of the flow and the electric conductivity of the spring water, how the different examined aquifers are characterized by very different measured value trends, according to the characteristics of the aquifer.

 


On the applicability of geomechanical models for carbonate rock masses interested by karst processes, 2015,

Rock mass classification and geomechanical models have a particular importance for carbonate rocks, due to their peculiar fabric, variability of the main features, and scarce availability of experimental data. Carbonates are particularly sensitive to syn-depositional and post-depositional diagenesis, including dissolution and karstification processes, cementation, recrystallisation, dolomitisation and replacement by other minerals. At the same time, as most of sedimentary rocks, they are typically stratified, laminated, folded, faulted and fractured. The strength and deformability of carbonate rock masses are, therefore, significantly affected by the discontinuities, as well as by their pattern and orientation with respect to the in situ stresses. Further, discontinuities generally cause a distribution of stresses in the rock mass remarkably different from those determined by the classical elastic or elasto-plastic theories for homogeneous continua. Goal of this work is the description of the difficulties in elaborating geomechanical models to depict the stress–strain behavior of karstified carbonate rock masses. Due to such difficulties, a high degree of uncertainty is also present in the selection of the most proper approach, the discontinuum one or the equivalent continuum, and in the numerical model to be used within a specific engineering application as well. The high uncertainty might cause wrong assessments as concerns the geological hazards, the design costs, and the most proper remediation works. Even though recent developments in the application of numerical modeling methods allow to simulate quite well several types of jointed rock masses, as concerns carbonate rock masses many problems in representing their complex geometry in the simulation models still remain, due to peculiarity of the structural elements, and the presence of karst features. In the common practice, the improper use of the geomechanical models comes from a superficial geological study, or from the lack of reliable geological and structural data that, as a consequence, bring to erroneous evaluations of the influence of the geological-structural features on the in situ stress state and the stress–strain rock mass behavior.


Sulphuric acid speleogenesis and landscape evolution: Montecchio cave, Albegna river valley (Southern Tuscany, Italy), 2015, Piccini Leonardo, De Waele Jo, Galli Ermanno, Polyak Victor J. , Bernasconi Stefano M. Asmerom Yemane

Montecchio cave (Grosseto province, Tuscany, Italy) opens at 320 m asl, in a small outcrop of Jurassic limestone (Calcare Massiccio Fm.), close to the Albegna river. This area is characterised by the presence of several thermal springs and the outcropping of travertine deposits at different altitudes. The Montecchio cave, with passage length development of over 1700 m, is characterised by the presence of several sub-horizontal passages and many medium- and small-scale morphologies indicative of sulphuric acid speleogenesis (SAS). The thermal aquifer is intercepted at a depth of about 100 m below the entrance: the water temperature exceeds 30 °C and sulphate content is over 1300 mg l−1. The cave hosts large gypsumdeposits from40 to 100mbelowthe entrance that are by-products of the reaction between sulphuric acid and the carbonate host rock. The lower part of the cave hosts over 1 m thick calcite cave raft deposits, which are evidence of long-standing, probably thermal, water in an evaporative environment related to significant air currents.

Sulphur isotopes of gypsum have negative δ34S values (from−28.3 to−24.2‰), typical of SAS. Calcite cave rafts and speleogenetic gypsumboth yield young U/Th ages varying from68.5 ka to 2 ka BP, indicating a rapid phase of dewatering followed by gypsum precipitation in aerate environment. This fastwater table lowering is related to a rapid incision of the nearby Albegna river, and was followed by a 20–30 m fluctuation of the thermal water table, as recorded in the calcite raft deposits and gypsum crusts.


Long-term erosion rate measurements in gypsum caves of Sorbas (SE Spain) by the Micro-Erosion Meter method, 2015, Sanna Laura, De Waele Jo, Calaforra José Maria, Forti Paolo

The present work deals with the results of long-term micro-erosion measurements in the most important gypsum cave of Spain, the Cueva del Agua (Sorbas, Almeria, SE Spain). Nineteen MEM stations were positioned in 1992 in a wide range of morphological and environmental settings (gypsum floors and walls, carbonate speleothems, dry conduits and vadose passages) inside and outside the cave, on gypsum and carbonate bedrocks and exposed to variable degree of humidity, different air flowand hydrodynamic conditions. Four different sets of stations have been investigated: (1) the main cave entrance (Las Viñicas spring); (2) the main river passage; (3) the abandoned Laboratory tunnel; and (4) the external gypsum surface. Data over a period of about 18 years are available. The average lowering rates vary from 0.014 to 0.016 mm yr−1 near the main entrance and in the Laboratory tunnel, to 0.022 mm −1 on gypsum floors and 0.028 mm yr−1 on carbonate flowstones. 

The denudation data from the external gypsum stations are quite regular with a rate of 0.170 mm yr−1. The observations allowed the collecting of important information concerning the feeding of the karst aquifer not only by infiltrating rainwater, but under present climate conditions also by water condensation of moist air flow. This contribution to the overall karst processes in the Cueva del Agua basin represents over 20% of the total chemical dissolution of the karst area and more than 50% of the speleogenetically removed gypsum in the cave system, thus representing all but a secondary role in speleogenesis. Condensation–corrosion is most active along the medium walls, being slower at the roof and almost absent close to the floor. This creates typical corrosion morphologies such as cupola, while gypsum flowers develop where evaporation dominates. This approach also shows quantitatively the morphological implications of condensation–corrosion processes in gypsum karst systems in arid zones, responsible for an average surface lowering of 0.047 mm yr−1, while mechanical erosion produces a lowering of 0.123 mm yr−1.


International Conference on Groundwater in Karst, Programme and Abstracts, 2015, University of Birmingham, Birmingham, 2015,

Carbonate rocks present a particular challenge to hydrogeologists as the major groundwater flux is through an integrated network of dissolutionally enlarged channels that discharge via discrete springs. The channels span a very wide aperture range: the smallest are little more than micro-fractures or pathways through the rock matrix but at the other end of the spectrum (and commonly in the same rock mass) channels may grow to dimensions where they can be explored by humans and are called caves. Groundwater transmission through the smaller channels that are commonly intersected by boreholes is very slow and has often been analysed using equivalent porous media models although the limitations of such models are increasingly recognised. At the other end of the spectrum (and commonly in the same rock mass) flow through the larger conduits is analogous to ‘a surface stream with a roof’ and may be amenable to analysis by models devised for urban pipe networks. Regrettably, hydrogeologists have too often focussed on the extreme ends of the spectrum, with those carbonates possessing large and spectacular landforms regarded as “karst” whereas carbonates with little surface expression commonly, but incorrectly labelled as “non-karstic”. This can lead to failures in resource management. Britain is remarkable for the variety of carbonate rocks that crop out in a small geographical area. They range in age and type from Quaternary freshwater carbonates, through Cenozoic, Mesozoic and Paleozoic limestones and dolostones, to Proterozoic metacarbonates. All near surface British carbonates are soluble and groundwater is commonly discharged from them at springs fed by dissolutionally enlarged conduits, thereby meeting one internationally accepted definition of karst. Hence, it is very appropriate that Britain, and Birmingham as Britain's second largest city, hosts this International Conference on Groundwater in Karst. The meeting will consider the full range of carbonate groundwater systems and will also have an interdisciplinary approach to understanding karst in its fullest sense.


Turkish karst aquifers, 2015, Gunay G. , Guner N. , Tork K.

One third of Turkey’s surface is underlain by carbonate rocks that have been subdivided into four karst regions. The carbonate rock units are about 200 km wide along the Taurus Mountains that attain elevations of 2500 m. Karst features of western Turkey bordering the Aegean and Mediterranean seas demonstrate the tectonic, lithological and climatic controls on the occurrence, movement, and chemical characteristics of groundwater. In Turkey all karstic feature, such as lapies, caves, sinkholes, uvalas, poljes, ground river valleys developed in all karstic areas. Karstification is related not only to the thickness and to purity of limestone, climate and height but also to tectonic movements. Water resources of karst terrains of Turkey are relatively rich and as such are very important for the economic development of the country. High mountain chains, very often associated with the karst terrains, are responsible for some important and beneficial characteristics of these water resources. Four karst regions are: (1) Taurus karst region, (2) southeast Anatolia karst region, (3) central Anatolia karst region, and (4) northwest Anatolia and Thrace karst regions.


Basinscale conceptual groundwater flow model for an unconfined and confined thick carbonate region, 2015,

Application of the gravitydriven regional groundwater flow (GDRGF) concept to the hydrogeologically complex thick carbonate system of the Transdanubian Range (TR), Hungary, is justified based on the principle of hydraulic continuity. The GDRGF concept informs about basin hydraulics and groundwater as a geologic agent. It became obvious that the effect of heterogeneity and anisotropy on the flow pattern could be derived from hydraulic reactions of the aquifer system. The topography and heat as driving forces were examined by numerical simulations of flow and heat transport. Evaluation of groups of springs, in terms of related discharge phenomena and regional chloride distribution, reveals the dominance of topographydriven flow when considering flow and related chemical and temperature patterns. Moreover, heat accumulation beneath the confined part of the system also influences these patterns. The presence of cold, lukewarm and thermal springs and related wetlands, creeks, mineral precipitates, and epigenic and hypogenic caves validates the existence of GDRGF in the system. Vice versa, groups of springs reflect rock–water interaction and advective heat transport and inform about basin hydraulics. Based on these findings, a generalized conceptual GDRGF model is proposed for an unconfined and confined carbonate region. An interface was revealed close to the margin of the unconfined and confined carbonates, determined by the GDRGF and freshwater and basinal fluids involved. The application of this model provides a background to interpret manifestations of flowing groundwater in thick carbonates generally, including porosity enlargement and hydrocarbon and heat accumulation.


Hydrothermal speleogenesis in carbonates and metasomatic silicites induced by subvolcanic intrusions: a case study from the Štiavnické vrchy Mountains, Slovakia, 2015,

Several caves of hydrothermal origin in crystalline limestones and metasomatic silicites were investigated in the central zone of the Štiavnica stratovolcano, Štiavnické vrchy Mountains, central Slovakia. Evidence of hydrothermal origin includes irregular spherical cave morphology sculptured by ascending thermal water, occurrence of large calcite crystals and hydrothermal alteration of host rocks, including hydrothermal clays. The early phases of speleogenesis in the crystalline limestone near Sklené Teplice Spa were caused by post-magmatic dissolution linked either to the emplacement of subvolcanic granodiorite intrusions during Late Badenian time or to the spatially associated Late Sarmatian epithermal system. Speleogenesis in metasomatic silicites in the Šobov area is related to hydrothermal processes associated with the pre-caldera stage of the Štiavnica stratovolcano in Late Badenian. Both localities are remarkable examples of hydrothermal speleogenesis associated with Miocene volcanic and magmatic activity in the Western Carpathians


The current status of mapping karst areas and availability of public sinkhole-risk resources in karst terrains of the United States, 2015,

Subsidence from sinkhole collapse is a common occurrence in areas underlain by water-soluble rocks such as carbonate and evaporite rocks, typical of karst terrain. Almost all 50 States within the United States (excluding Delaware and Rhode Island) have karst areas, with sinkhole damage highest in Florida, Texas, Alabama, Missouri, Kentucky, Tennessee, and Pennsylvania. A conservative estimate of losses to all types of ground subsidence was $125 million per year in 1997. This estimate may now be low, as review of cost reports from the last 15 years indicates that the cost of karst collapses in the United States averages more than $300 million per year. Knowing when a catastrophic event will occur is not possible; however, understanding where such occurrences are likely is possible. The US Geological Survey has developed and main-tains national-scale maps of karst areas and areas prone to sinkhole formation. Several States provide additional resources for their citizens; Alabama, Colorado, Florida, Indiana, Iowa, Kentucky, Minnesota, Missouri, Ohio, and Pennsylvania maintain databases of sinkholes or karst features, with Florida, Kentucky, Missouri, and Ohio providing sinkhole reporting mechanisms for the public.


Superposed folding and associated fracturing influence hypogene karst development in Neoproterozoic carbonates, São Francisco Craton, Brazil, 2015,

Porosity and permeability along fractured zones in carbonates could be significantly enhanced by ascending fluid flow, resulting in hypogene karst development. This work presents a detailed structural analysis of the longest cave system in South America to investigate the relationship between patterns of karst conduits and regional deformation. Our study area encompasses the Toca da Boa Vista (TBV) and Toca da Barriguda (TBR) caves, which are ca. 107 km and 34 km long, respectively. This cave system occurs in Neoproterozoic carbonates of the Salitre Formation in the northern part of the São Francisco Craton, Brazil. The fold belts that are around and at the craton edges were deformed in a compressive setting during the Brasiliano orogeny between 750 and 540 Ma. Based on the integrated analysis of the folds and brittle deformation in the caves and in outcrops of the surrounding region, we show the following: (1) The caves occur in a tectonic transpressive corridor along a regional thrust belt; (2) major cave passages, at the middle storey of the system, considering both length and frequency, developed laterally along mainly (a) NE–SW to E–W and (b) N to S oriented anticline hinges; (3) conduitswere formed by dissolutional enlargement of subvertical joints,which present a high concentration along anticline hinges due to folding of competent grainstone layers; (4) the first folding event F1was previously documented in the region and corresponds with NW–SE- to N–S-trending compression, whereas the second event F2, documented for the first time in the present study, is related to E–Wcompression; and (5) both folding  еvents occurred during the Brasiliano orogeny. We conclude that fluid flow and related dissolution pathways have a close relationship with regional deformation events, thus enhancing our ability to predict karst patterns in layered carbonates.


Hypogenic origin, geologic controls and functional organization of a giant cave system in Precambrian carbonates, Brazil, 2015,

This study is focused on speleogenesis of the Toca da Boa Vista (TBV) and Toca da Barriguda (TBR), the longest caves in South America occurring in the Neoproterozoic Salitre Formation in the São Francisco Craton, NE Brazil. We employ a multidisciplinary approach integrating detailed speleomorphogenetic, lithostratigraphic and geological structure studies in order to reveal the origin of the caves, their functional organization and geologic controls on their development. The caves developed in deep-seated confined conditions by rising flow. The overall fields of passages of TBV and TBR caves represent a speleogenetically exploited large NE–SW-trending fracture corridor associated with a major thrust. This corridor vertically extends across the Salitre Formation allowing the rise of deep fluids. In the overall ascending flow system, the formation of the cave pattern was controlled by a system of sub-parallel anticlines and troughs with NNE–SSWdominant orientation, and by vertical and lateral heterogeneities in fracture distribution. Three cave-stratigraphic stories reflect the actual hydrostratigraphy during the main phase of speleogenesis. Cavities at different stories are distinct inmorphology and functioning. The gross tree-dimensional pattern of the system is effectively organized to conduct rising flow in deep-seated confined conditions. Cavities in the lower story developed as recharge components to the system. A laterally extensive conduit network in the middle story formed because the vertical flow from numerous recharge points has been redirected laterally along the highly conductive unit, occurring below the major seal - a scarcely fractured unit. Rift-like and shaft-like conduits in the upper story developed along fracturecontrolled outflow paths, breaching the integrity of the major seal, and served as outlets for the cave system. The cave system represents a series of vertically organized, functionally largely independent clusters of cavities developed within individual ascending flow cells. Lateral integration of clusters occurred due to hydrodynamic interaction between the flow cells in course of speleogenetic evolution and change of boundary conditions. The main speleogenetic phase, during which the gross cave pattern has been established and the caves acquired most of their volume, was likely related to rise of deep fluids at about 520 Ma or associated with rifting and the Pangea break-up in Triassic–Cretaceous. This study highlights the importance of speleogenetic studies for interpreting porosity and permeability features in carbonate reservoirs.


Sulfuric acid speleogenesis (SAS) close to the water table: Examples from southern France, Austria, and Sicily, 2015,

Caves formed by rising sulfuric waters have been described from all over the world in a wide variety of climate  settings, from arid regions to mid-latitude and alpine areas. H2S is generally formed at depth by reduction of  sulfates in the presence of hydrocarbons and is transported in solution through the deep aquifers. In tectonically  disturbed areas major fractures eventually allow these H2S-bearing fluids to rise to the surface where oxidation  processes can become active producing sulfuric acid. This extremely strong acid reacts with the carbonate  bedrock creating caves, some of which are among the largest and most spectacular in the world. Production of  sulfuric acid mostly occurs at or close to the water table but also in subaerial conditions in moisture films and  droplets in the cave environment. These caves are generated at or immediately above the water table, where  condensation–corrosion processes are dominant, creating a set of characteristic meso- and micromorphologies.  Due to their close connection to the base level, these caves can also precisely record past hydrological and  geomorphological settings. Certain authigenic cave minerals, produced during the sulfuric acid speleogenesis  (SAS) phase, allow determination of the exact timing of speleogenesis. This paper deals with the morphological,  geochemical and mineralogical description of four very typical sulfuric acid water table caves in Europe: the  Grotte du Chat in the southern French Alps, the Acqua Fitusa Cave in Sicily (Italy), and the Bad Deutsch Altenburg  and Kraushöhle caves in Austria


Hidden sinkholes and karst cavities in the travertine plateau of a highly-populated geothermal seismic territory (Tivoli, central Italy), 2015,

Sinkholes and other karst structures in settled carbonate lands can be a significant source of hazard for humans and human works. Acque Albule, the study area of this work, is a Plio-Pleistocene basin near Rome, central Italy, superficially filled by a large and thick deposit of late Pleistocene thermogene travertine. Human activities blanket large portions of the flat territory covering most evidence from geological surface processes and potentially inducing scientists and public officials to underestimate some natural hazards including those connected with sinkholes. To contribute to the proper assessment of these hazards, a geomorphologic study of the basin was performed using digital elevation models (DEMs), recent aerial photographs, and field surveys. Historical material such as old aerial photographs and past geomorphologic studies both pre-dating the most part of quarrying and village building was also used together with memories of the elderly population. This preliminary study pointed out the presence of numerous potentially active sinkholes that are at present largely masked by either quarrying or overbuilding. Where this first study pointed out the apparent absence of sinkholes in areas characterized by high density of buildings, a detailed subsurface study was performed using properly-calibrated electrical resistivity tomography (ERT) and dynamic penetration measurements (DPSH), together with some borehole logs made available from the local municipality. This second study highlighted the presence of sinkholes and caves that are, this time, substantially hidden to the resolution of standard methods and materials such as aerial photographs, DEMs, and field surveys. Active sinkhole subsidence in the Acque Albule Basin may explain, at least in part, the frequent damages that affect numerous buildings in the area. The main conclusion from this study is that the mitigation of sinkhole hazard in highly populated areas has to pass through a thorough search of (hidden) sinkholes that can be masked by the Anthropocenic molding and blanketing of the territory. For these purposes, data from historical (pre-Anthropocene) documents as well as, where possible, subsurface investigations are fundamental.


Basin-scale conceptual groundwater flow model for an unconfined and confined thick carbonate region, 2015,

Application of the gravity-driven regional  groundwater flow (GDRGF) concept to the  hydrogeologically complex thick carbonate system of the  Transdanubian Range (TR), Hungary, is justified based on  the principle of hydraulic continuity. The GDRGF concept  informs about basin hydraulics and groundwater as a  geologic agent. It became obvious that the effect of  heterogeneity and anisotropy on the flow pattern could be  derived from hydraulic reactions of the aquifer system.  The topography and heat as driving forces were examined  by numerical simulations of flow and heat transport.  Evaluation of groups of springs, in terms of related  discharge phenomena and regional chloride distribution,  reveals the dominance of topography-driven flow when  considering flow and related chemical and temperature  patterns. Moreover, heat accumulation beneath the confined  part of the system also influences these patterns. The  presence of cold, lukewarm and thermal springs and  related wetlands, creeks, mineral precipitates, and epigenic  and hypogenic caves validates the existence of GDRGF in  the system. Vice versa, groups of springs reflect rock–  water interaction and advective heat transport and inform  about basin hydraulics. Based on these findings, a  generalized conceptual GDRGF model is proposed for  an unconfined and confined carbonate region. An interface  was revealed close to the margin of the unconfined and  confined carbonates, determined by the GDRGF and  freshwater and basinal fluids involved. The application  of this model provides a background to interpret manifestations  of flowing groundwater in thick carbonates  generally, including porosity enlargement and hydrocarbon  and heat accumulation.


Chemistry and Karst, 2015, White, William B.

The processes of initiation and development of characteris­tic surface karst landforms and underground caves are nearly all chemical processes. This paper reviews the advances in understanding of karst chemistry over the past 60 years. The equilibrium chemistry of carbonate and sulfate dissolution and deposition is well established with accurate values for the necessary constants. The equations for bulk kinetics are known well enough for accurate modeling of speleogenetic processes but much is being learned about atomic scale mechanisms. The chemistry of karst waters, expressed as parameters such as total dissolved carbonates, saturation index, and equilibrium carbon dioxide pressure are useful tools for probing the internal char­acteristics of karst aquifers. Continuous records of chemical parameters (chemographs) taken from springs and other karst waters mapped onto discharge hydrographs reveal details of the internal flow system. The chemistry of speleothem deposi­tion is well understood at the level of bulk processes but much has been learned of the surface chemistry on an atomic scale by use of the atomic force microscope. Least well understood is the chemistry of hypogenetic karst. The main chemical reac­tions are known but equilibrium modeling could be improved and reaction kinetics are largely unknown.


Results 1201 to 1215 of 1215
You probably didn't submit anything to search for